Your search resulted in 30 documents. Displaying 25 entries per page.
Potentialities of protein borates as low-toxic, long-term wood preservatives - Preliminary trials
1999 - IRG/WP 99-30212
Boron compounds are efficient wood preservatives, as well as safe for the mammals and environmentally acceptable. Their natural solubility allows them to treat almost any wood species, but is also the cause of their high depletion from treated timber in outside exposure. In order to reduce this leachability, potentialities of proteinic polymer networks retaining boron within the wood have been inv...
M-F Thévenon, A Pizzi, J P Haluk
A new ground-contact wide-spectrum organic wood preservative: DNBP
1986 - IRG/WP 3358
A new organic wood preservative, which 25 years field tests have proved to be of efficiency and effectiveness comparable to CCA wood preservatives for ground-contact applications, is presented. Physical and chemical tests, supporting the long term field test results as well as indicating the characteristics of this preservative, are also presented....
W E Conradie, A Pizzi
Biological effectiveness of ground-contact wood preservatives as determined by field exposure stake tests
1984 - IRG/WP 3297
Field exposure tests conducted on stakes treated with different creosotes, mixtures of creosote and waxy oil as well as different CCA wood preservatives over a period of 25 years, gave the following results: The CCA preservatives provided excellent biological protection to treated stakes, especially against fungal attack. The CCA Type I, currently approved for use under South African conditions is...
W E Conradie, A Pizzi
CCA Chemistry
1983 - IRG/WP 3268
A Pizzi
Polyflavonoid tannins - From a cause of CCA soft-rot failure to the "missing link" between lignin and microdistribution theories
1986 - IRG/WP 3359
Polyflavonoid tannins are proven to be fast-reacting with CCA solutions and hence, to be strong competitors of the structural wood constituents for fixation of CCA preservatives. The consequence of this effect is that even relatively small amounts of tannin cause severe undertreatment of the structural wood constituents which in turn badly affects the long term durability of CCA-treated timber. Th...
A Pizzi, W E Conradie, M Bariska
Sludge formation in timber treatment with CCA preservatives. Origin and elimination
1984 - IRG/WP 3276
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, are repor...
A Pizzi, W E Conradie, A Jansen
Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability.
Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk
Practical consequences of the clarification of the chemical mechanism of CCA fixation to wood
1983 - IRG/WP 3220
Practical consequences derived from the chemical investigation of the mechanism of fixation of CCA to the wood constituents are discussed. Among these, formulas for the calculation of the time of hexavalent chrome fixation are presented. Furthermore, three parameters are shown to be important to the long-term effectiveness of CCA-treated timber: (i) the temperature of treatment, (ii) the initial p...
A Pizzi
Low-toxicity DNBP wood preservatives
1987 - IRG/WP 3408
Low and very low toxicity single compound preservatives of both excellent insecticidal and fungicidal activity for interior, extrior and ground-contact applications are presented. These are ester derivatives of alkyl dinitrophenols, in particular of 2-sec-butyl-4,6-dinitrophenol (DNBP) and 2-sec-octyl-4,6-dinitrophenol. These esters, of much lower toxicity than DNBP impart to the treated timber co...
A Pizzi, W E Conradie, A Jansen, R Vosloo
Copper linoleate: A new low toxcity wide spectrum, heavy duty wood preservative
1995 - IRG/WP 95-30082
Copper linoleate, a "fixed" copper soap has been developed and evaluated in South Africa over a 30-year period. The initial product, an organic solvent based preservative has been tested in pine poles against termites and fungi. Results indiate that the product has performed well against existing heavy duty wood preservatives such as CCA and creosote in long term field trials (30 years). The paper...
D Conradie, P Turner, W E Conradie, A J Pendlebury, T Pizzi
Durability of heat-treated wood
1999 - IRG/WP 99-40145
Heat-treated wood from the French process were laboratory tested against decay using agar block test and a modified soil block test. Water absorption, bending strength, lignin content and acid number were also determined to evaluate the effect of heat treatment. Heat treated samples exhibit a higher lignin content and a lower acid number compared to untreated control indicating the degradation of ...
D P Kamdem, A Pizzi, R Guyonnet, A Jermannaud
Water-borne DNBP wood preservatives - Preparation and performance
1987 - IRG/WP 3407
Three waterborne wide-spectrum ground-contact DNBP (2-sec-butyl-4,6-dinitrophenol) wood preservative formulations and their performance are presented. Two are double-treatment formulations in which insolubilization and precipitation of the preservative is attained by salt formation or by formation of a water insoluble Cu/NH3/DNBP complex of formula [DNBP]2 [Cu(NH3)2]2 the clarified structure of wh...
W E Conradie, A Pizzi
Wood preservation in Southern Africa
1984 - IRG/WP 3320
This report deals with the status of wood preservation in the countries of Southern Africa, namely Botswana, Lesotho, Mozambique, Namibia, South Africa, Swaziland and Zimbabwe. It includes some data on the timber production from the forests of these countries, as well as detailing the state of the timber products industries in South Africa which is the dominant country in the field in the sub-cont...
A Pizzi, W E Conradie, R Cockcroft
Three-year field trials of polymeric formulations which provide a new basis for the invention and design of non-toxic wide-spectrum wood preservatives
1994 - IRG/WP 94-40029
Three types of non-toxic polymeric formulations invented using a new approach to wood preservation were challenged with termites and fungi in three-year ground-contact field trials in the sub-tropical climate of Natal. These formulations were copper soaps of carboxylic acid groups of unsaturated fatty acids of waxes and edible vegetable oils; of resin acids of rosin, and, of synthetic unsaturated ...
A A W Baecker, A Pizzi
Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon
Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel
Synthesis of boric acid ammonium oleate salt for wood preservation: Leachability and termite resistance test
2007 - IRG/WP 07-30435
A new chemical compound coupling boric acid and oleic acid through a joint of ammonium salt has been produced and its synthesis followed and validated by Fourier Transformed Infra Red (FTIR). This compound named ammonium borate oleate (BAO) combining biocidal properties of boron and water repellence of fatty acids has then been studied as a wood preservative.
Synthesis of BAO involved different...
F Lyon, A Pizzi, Y Imamura, M F Thevenon, S N Kartal, J Gril
Development of boron/linseed oil combined treatment as a low-toxic wood protection. Evaluation of boron fixation and resistance to termites according to Japanese and European standards
2007 - IRG/WP 07-30448
Combinations of boric acid as a first step of treatment and linseed oil as a second step have been performed in order to enhance boron retention to leaching and wood resistance to termites. Classic leaching and termites resistance standards are inappropriate to evaluate this combination which can be considered as both a wood core preservation treatment and a coating.
Japanese Industrial Standard...
F Lyon, M-F Thevenon, Y Imamura, J Gril, A Pizzi
Utilizing Cypress to improve the decay and termite resistance of OSB panels
2008 - IRG/WP 08-10658
OSB panels were manufactured with mixture of pine and cypress heartwood and lignin and tannin based resins in order to propose an eco-friendly wood composite. The resistance of OSB panels was tested against Reticulitermes santonensis according to the EN 118 and EN 117 standards and field tests methods. OSB made from cypress showed more resistance against the tested termite, the resistance decrease...
N Amusant, O Arnould, A Depres, R H Mansouris, T Pizzi, C Baudassé
Wood preservation by a mixed anhydride treatment: Using simple models of polymeric wood compounds
2008 - IRG/WP 08-30457
Treatment of wood by a mixed aceto/oleic (or other fatty acid residue) anhydride promoted as a safe and environment friendly wood preservation system has been examined quantitatively by liquid phase 13C NMR and solid phase MAS-DEC (proton decoupling) 13C NMR through all its different stages to determine which reactions occur with simple model compounds of the polymeric constituents of wood. The p...
F Lyon, M-F Thevenon, A Pizzi, G Tondi, A Despres, J Gril, S Rigolet
Fungal decay resistance and durability of wood products made from borax-impregnated wood and bonded with corn starch and tannin adhesive
2009 - IRG/WP 09-30494
At present, the production of wood composites mainly relies on the petrochemical-based and formaldehyde-based adhesives such as phenol formaldehyde (PF) resins and urea formaldehyde (UF) resins, which are non-renewable and therefore ultimately limited in supply. This paper concerns the decay resistance of wood products bonded with a new, environment-friendly adhesive derived from abundant and rene...
A Moubarik, A Pizzi, A Allal, F Charrier, B Charrier
Resistance to decay fungi of ammonium borate oleate treated wood
2009 - IRG/WP 09-30505
Ammonium borate oleate molecule (ABO) produced from reaction between boric acid, ammonia and oleic acid was tested as wood preservative treatment against brown and white rot fungi according to European standards. This compound was prepared according to a previous study which has proved existence of synthesis reaction and effectiveness against termites (Lyon et al. 2007b). Four solutions of ABO in ...
F Lyon, M-F Thevenon, A Pizzi, J Gril
Fungal decay resistance and mechanical properties of plywood panels made from maritime pine (Pinus pinaster) and bonded with cornstarch-quebracho tannin-phenol formaldehyde adhesive
2010 - IRG/WP 10-40490
The aim of this work is to demonstrate the performances of cornstarch-quebracho tannin-based resins designed as adhesive in the plywood production. In this way, the cornstarch and quebracho tannin was introduced in the classic adhesive formulation in order to supply a part of phenol-formaldehyde (PF). In order to evaluate the mechanical performances of optimal cornstarch-quebracho tannin-PF, plywo...
F Charrier, A Moubarik, A Allal, A Pizzi, B Charrier
Tannin resin-boron for outdoor wood protection and fire retardancy
2011 - IRG/WP 11-30567
Boron in the form of boric acid is well known for its efficacy against wood destroying organisms, as well as for its high leachability from treated wood when in outside exposure. Moreover, due to the European directive 2008/58/EC, boric acid is only authorized at low levels. In order to keep considering boric acid as an interesting active ingredient for wood protection, the issue is now to fix it ...
M-F Thévenon, G Tondi, N Leménager, S Wieland, A Pizzi
Biological and mechanical performances of particleboard panels made from maritime pine (Pinus pinaster) and glued with cornstarch-mimosa tannin-urea formaldehyde adhesive
2011 - IRG/WP 11-40542
The objective of this work was to demonstrate the utility of cornstarch-mimosa tannin-based resins designed for application as an adhesive in the particleboard production. Bond qualities of cornstarch-mimosa tannin- urea formaldehyde (UF) (10:4:86, weight ratios) resins and commercial UF resin were assessed by using an automatic bonding evaluation system, prior to production of particleboard panel...
A Moubarik, F Charrier, A Pizzi, A Allal, B Charrier