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Tannin resin-boron associations: Leaching and biological resistance
2012 - IRG/WP 12-30587
The easy leaching of boron in wood preservation formulations has allowed to use this fungicide only for short term applications. The recently discovered adduct with flavonoids allows boron to resist longer periods of time within wood and consequently extend its life. Two different leaching treatments were compared and the fungal and termite decay was examined. The biological tests have shown extre...
G Tondi, S Wieland, N Lemenager, A Petutschnigg, A Pizzi, M-F Thevenon


Thermal durability and biodegradation of tannin lignin adhesives
2014 - IRG/WP 14-40657
Mimosa tannins and lignosulfonates were used in wood adhesives formulation to substitute resins based on formaldehyde. Mimosa tannins were mixed with either glyoxalated sodium lignosulfonates or glyoxalated ammonium lignosulfonates. The ratios of mimosa tannins and sodium lignosulfonates varied from 20% tannins to 60% tannins. The thermal durability of the adhesives were analysed by thermogravimet...
L Chupin, B Charrier, A Pizzi, F Charrier


Environmentally Friendly Wood Modification based on Tannin-Furfuryl alcohol - Effect on stabilisation, mechanical properties and decay durability
2022 - IRG/WP 22-40929
Furfurylation is a well-known wood modification technology. This paper studied the effect of tannin addition on the wood furfurylation. Three kinds of dicarboxylic acids, adipic acid, succinic acid, and tartaric acid, as well as glyoxal as a comparing agent, were used to catalyse the polymerisation of furanic or tannin-furanic solutions during wood modification. Impregnation of furanic or tannin-f...
M Mubarok, E Azadeh, F O Akong, S Dumarçay, A Pizzi, C Charbonnier-Gérardin, P Gérardin


Novel bio-based tannin/furfurylic alcohol thermosets: application to wood preservation
2022 - IRG/WP 22-40959
This project is integrated within the overall context of sustainable development and targets the valorization the wood industry by-products such as polyphenolic extractives, and in particular tannins. The objective targets the use of the same polymer used for production of tannin-furanic foams, but here for wood preservation to avoid the utilization of biocides. The aims is to the design of copoly...
C Gérardin-Charbonnier, E Azadeh, A Pizzi, P Gerardin


Optimization of furfurylic alcohol/tannin ratio to improve the performance of biosourced thermoset resins for wood protection
2023 - IRG/WP 23-40994
This study concerns the chemical modification of wood with different ratios of tannin and furfuryl alcohol (FA) in the presence of maleic acid as catalyst. Tannins were used not only as cross-linking agents, but also as co-monomers to improve wood durability, while reducing the amount of FA used. Different aqueous formulations were prepared containing decreasing amount of FA (from 45.45% to 0%) an...
E Azadeh, A Pizzi, P Gérardin, C Gérardin-Charbonnier


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