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Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


Chemical composition of extractives of different wood compartments of Pinus merkusii and their potential implication in wood durability
2015 - IRG/WP 15-10841
Amounts and nature of extractives differ strongly according to the compartment of wood and to the nature of the wood species. Previous studies reported that knotwood of several European Pinus sp. contains extractives contents much higher than stemwood consisting mainly of lignans which may find valuable applications in cosmetic, nutraceutic or pharmaceutic sectors. Different explanations have been...
A Wijayanto, S Dumarçay, R Kartika Sari, W Syafii, P Gérardin, C Gérardin-Charbonnier


Glutathione transferases and wood extracts
2015 - IRG/WP 15-10845
Wood rotting fungi have developed an efficient detoxification system allowing them to be well adapted to their way of life, these fungi generating and encountering potential toxic compounds during wood degradation. Belonging to this detoxification network, glutathione transferases are particularly extended in these fungi and their presence could reflect the chemical environments encountered by the...
A Deroy, F Saiag, Z Kebbi-Benkeder, N Touahri, M Morel-Rouhier, F Colin, S Dumarcay, P Gérardin,


A review of the analytical methods used in determining the decay resistance of heat treated wood
2015 - IRG/WP 15-40690
Heat treatment as a wood process is increasingly used because of its non-biocide behaviour and its low environmental impact. This sort of treatment is based on biopolymer chemical degradation by heat transfer. This process improves mainly the dimensional stability and the decay resistance of wood. Wood becomes darker after this type of treatment and thus gives it an aesthetic appearance. These i...
K Candelier, M-F Thévenon, A Pétrissans, S Dumarçay, P Gérardin, M Pétrissans


Effect of natural variability of European Oak wood on heat treatment process and potential implication on wood durability
2015 - IRG/WP 15-40693
Environmental pressures appeared in France and in most European countries during the last decade has led to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative method during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important...
J Hamada, A Pétrissans, F Mothe, M Pétrissans, P Gérardin


Exudate production: a detoxification strategy of wood decaying fungi
2016 - IRG/WP 16-10868
Even often observed, the exudate production in fungi remains mainly unstudied. During growth on oak wood, the white-rot fungus Trametes versicolor produces droplets of a red-brown liquid, this phenomenom being observed with nine studied strains. One of these strains secretes a similar exudate on rich medium even in the absence of wood. This secretion seems to be linked to the formation of special...
A Deroy, J G Berrin, S Dumarçay, P Gérardin, A Kohler, D Navarro, C Rose, R Sormani, M Morel-Rouhier, E Gelhaye


Resistance of heat treated Ash wood under steam pressure: rot fungi, soil micro-organisms and termites
2016 - IRG/WP 16-40724
Thermal modification processes have been developed to increase the biological durability and dimensional stability of wood. The aim of this paper was to study the influence of ThermoWood® treatment intensity on wood decay resistance improvement against soil-inhabiting micro-organisms, brown/white rots and termite’s exposures. All of the tests were carried out in the laboratory with two differen...
K Candelier, S Hannouz, M-F Thévenon, D Guibal, P Gérardin, M Pétrissans, R Collet


How intraspecific radial variability of the European Oak’s may influence mild pyrolysis process and durability of the material
2016 - IRG/WP 16-40725
Last decades wood is promoted as building material. Unprotected wood exposed to outdoor conditions undergoes a variety of degradation induced essentially by fungi attacks. Heat treatment of wood by mild pyrolysis (180°C T 240°C under inert atmosphere) is a preservation process with a weak environmental impact, and therefore, is viewed as an interesting alternative to the chemical impregnation me...
J Hamada, A Pétrissans, F Mothe, M Pétrissans, P Gérardin


Incorporation of raw boron minerals to protect particleboard against decay and mold fungi, termites and insects
2016 - IRG/WP 16-40729
This paper evaluated the biological performance of particleboards incorporated with the raw boron minerals ulexite and colemanite against decay, mold fungi, termites and insect larvae in comparison with that of particleboards with zinc borate, or boric acid plus a borax mixture. The results showed that ulexite and colemanite were highly effective against the decay fungi and termite attack in labor...
S N Kartal, E Terzi, P Gerardin, C M Ibanez, T Yoshimura


Enhancing wood properties through bio-based and non-biocidal co-polyesters
2016 - IRG/WP 16-40740
The commonly used wood preservation treatments are nowadays facing huge environmental issues, as well as increasing public concern. As regards those concerns, legislation tends to regulate the use of biocidal preservation chemicals. Thus, it does appear crucial to provide alternatives to the use of biocides to allow different outdoor uses of wood such as for, posts, decking, and cladding or even ...
C L’Hostis, M-F Thévenon, E Fredon, P Gérardin


Optimising wood chemical modification with lactic acid oligomers by screening of processing conditions and chemical additives
2016 - IRG/WP 16-40741
Oligomer systems based on lactic acid (OLA), were impregnated in wood and polymerised in-situ by heat treatment to improve the properties of the treated wood especially regarding anti-swelling efficiency (ASE), hygroscopicity, water leaching resistance and durability. This article relates the optimisation of the heat treatment conditions and the consideration of selected chemicals for improvement ...
C Grosse, M-F Thévenon, M Noël, P Gérardin


The impact of catalyst on the properties of furfurylated beech wood
2016 - IRG/WP 16-40748
European beech (Fagus sylvatica L.) is a major tree species of European forest that is underexploited because of its low dimensional stability and durability. Similarly to what has been developed with radiata pine, furfurylation might be the answer to optimize the utilization of local beech wood. Beech wood furfurylation process was studied using five different catalysts: maleic anhydride, maleic ...
P S Sejati, A Imbert, C Gérardin, S Dumarçay, E Fredon, E Masson, D Nandika, T Priadi, P Gérardin


Evaluation of Commercially Available Polyurethane Resin to Develop Non-biocidal Wood Preservation Treatments
2016 - IRG/WP 16-40751
Evaluation of commercially available polyurethane (PU1 and PU2 and polyisocyanate (PNCO) to develop non-biocidal wood preservation treatments have been conducted. A simple method by vacuum impregnation of these resins into beech wood (Fagus sylvatica L) and pine wood (Pinus sylvestris L.) samples followed by varied curing process at ambient temperature, 103oC, and 200oC have been performed. Based ...
M Mubarok, Y Sudo Hadi, J Suryana, I W Darmawan, F Simon, S Dumarcay, C Gérardin, P Gérardin


Improvement of wood properties by impregnation with liquefied spruce bark based resins
2016 - IRG/WP 16-40761
In this paper, biobased phenolic thermosetting resins are designed to be used as wood stabilization treatment. The originality of the study stands in substituting part of phenol by spruce (picea abies) bark: this is achieved by a liquefaction process in phenol in the presence of sulfuric acid as catalyst. Next, thermosetting resins are synthetized from liquefied bark by condensation on formaldehy...
X Duret, E Fredon, E Masson, P Gérardin


Interactions between fungal glutathione transferases and wood extractives
2017 - IRG/WP 17-10894
The interactions between extractives from several tree species of French Guyana and glutathione transferases (GST) from the white-rot Trametes versicolor have been studied. These interactions have been monitored using a thermal shift assay. It appears from these experiments that TvGSTO2S interacts strongly with acetonic extract of Bagassa guianensis and in particular with oxyresveratrol. In agreem...
T Perrot, F Saiag, N Amusant, S Dumarçay, P Gérardin, M Morel-Rouhier, R SormaniI, E Gelhaye


Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


Interactions between wood polyphenols and detoxification enzymes of the white rot Trametes versicolor
2018 - IRG/WP 18-10906
Wood decay fungi have complex detoxification systems that enable them to cope with secondary metabolites produced by plants. Although the number of genes encoding for glutathione transferases (GSTs) is especially expanded in lignolytic fungi, little is known about their physiological target molecules. In this study, by combining thermal shift assay and affinity crystallography we highlighted inter...
M Schwartz, T Perrot, E Aubert, S Dumarçay, F Favier, P Gérardin, M Morel-Rouhier, G Mulliert, F Saiag, C Didierjean, E Gelhaye


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Improvement of short rotation teak wood properties through thermal modification
2018 - IRG/WP 18-40842
Teak (Tectona grandis L.f) is one of the most popular tropical timber species. Nowadays, the source of long rotation teak is limited in the availability. Many wood processing industries use short rotation teak, which has lower quality especially in durability and dimensional stability. Heat treatment is an eco-friendly method improving dimensional stability and durability of wood. The objectives o...
L A Pratiwi, I W Darmawan, B George, A Merlin, C Gérardin, S Dumarçay, T Priadi, P Gérardin


Natural durability of four Tunisian Eucalyptus wood species and their respective compositions in extractives
2019 - IRG/WP 19-10942
In the 50’s, Tunisia government introduced more than 11 Eucalyptus wood species. Eucalyptus species were planted in Tunisia in different arboreta throughout the country for close observation and adaptation to climate and soil. These fast-growing wood species were mainly used as fire wood, for the production of mine wood and to fight against the erosion. These tree species were adapted themselve...
S Ben Ayed, M T Elaieb, S Dumarçay, B De Freitas Homen De Faria, M-F Thévenon, P Gerardin, K Candelier


Coula edulis baill an unknown wood species as an alternative to the main durable wood species used in Gabon
2019 - IRG/WP 19-10945
The Congo Basin hosts an exceptional biodiversity of trees, flora and fauna. However, the immense natural heritage of the forests in this area is increasingly threatened by many anthropogenic factors, due to selective exploitation of certain wood species. In Gabon, whose ecosystem is representative of this area, the forest represents nearly 80% of the national territory. Only a minority of wood sp...
C S A Bopenga Bopenga, S Dumarçay, P Edou Engonga, P Gerardin


Chemical composition, antitermite and antifungal activity of Dacryodes edulis oleoresin
2019 - IRG/WP 19-20653
Damages to wood structures and other cellulosic materials caused by wood destroying insects and fungi are estimated to several billions of dollars each year in the world. Among these, termites are considered as one of the most economically important pests for wooden structures. In the past, several wood protection chemicals like CCA, creosote, lindane or pentachlorophenol have been used. However, ...
W F Bedounguindzi, K Candelier, P E Engonga, Se Dumarcay, M-F Thevenon, P Gerardin


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Improvement of wood decay and termite durability resulting from combined treatments based on borax/phenol-formaldehyde impregnation followed by thermal modification
2019 - IRG/WP 19-40871
This study determined the factors influencing the boron content after leaching of pine blocks impregnated with aqueous solution of phenol-formaldehyde (PF) resin with or without borax and subjected to heat treatment by response surface methodology. An experimental design permits to analyze the effects of heat treatment temperature (150, 185 and 220°C), curing time (5, 12, 5 and 20 hours), resin c...
S Salman, M-F Thevenon, A Petrissans, S Dumarcay, P Gerardin


Promoting Commercially Available Epoxy Resins for Non-biocidal Wood Preservation
2019 - IRG/WP 19-40877
Commercially available epoxy and polyamine resins were evaluated with the aim of developing new non-biocidal wood preservation treatments. A simple method allowing the impregnation of wood by vacuum double impregnation followed by a curing process was developed for two reference species, beech Fagus sylvatica and Scots pine Pinus sylvestris. The tested products were evaluated for their ability to ...
P Poveda, M Mubarok, S Dumarcay, M Montibus, I Le Bayon, M Kutnik, P Gerardin, F Simon


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