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Effectiveness and synergistic effects between copper and polymer betaine
1996 - IRG/WP 96-30097
Different formulations of "Copper Amine" and Polymer Betaine were studied. During laboratory tests a synergism between both active ingredients against soft rot and dry rot has been found. The efficacy against soft rot according to the "BAM method" and the European Standard ENV 807 depends only on the amount of copper. Long term tests in a fungus cellar for determining the relative protective effec...
H Härtner, V Barth


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB. ...
H Härtner, S Schmitt, Futong Cui, H M Barnes


The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


Suitability of cotton strip testing as a screening method for the development of wood preservative formulations
2003 - IRG/WP 03-20270
This paper outlines a simple and rapid test method for screening the efficacy of wood preservative formulations against microbiological attack using cotton strips. The method was evaluated against soft rot and was found to provide reliable information on the protection of lignocellulosic material against microbiological attack. The assessment is based on visual interpretation of decay and on a sim...
H Leithoff, I Stephan, H Härtner


A new type of biocide suitable for use in different fields of wood preservation
1993 - IRG/WP 93-30014
A new type of polymeric biocides was developed containing quaternary ammonium and boron ester groups as active structure elements, to overcome the disadvantages of AAC's in wood preservation use and to utilise their good performance due to a broad efficacy against fungi on the other hand. The new biocides called polymeric betains have been tested in laboratory and field tests and especial...
V Barth, H Härtner


The role of chromium in wood preservatives - The situation and new results concerning biological efficacy
2006 - IRG/WP 06-30397
A heavy discussion about the status of chromium-containing compounds in wood preservatives has ensued in the European Union since the Biocidal Product Directive 98/8/EG has come into force.The origin of this discussion is the fact that according to the Biocidal Product Directive chromium trioxide and sodium dichromate have been identified as active ingredients and therefore the placement of wood p...
P Jüngel, H Härtner, E Melcher


Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes