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Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Preparation of Calibration Standards for the Analysis of Pentachlorophenol in Treated Wood by X-ray Fluorescence
2016 - IRG/WP 16-20591
The primary purpose of this project was to develop a method for preparing calibration standards that can be used by the wood treating industry to calibrate X-ray fluorescence instrumentation. Calibration standards of penta/P9-oil in southern yellow pine that cover the retention range of 0.2 to 0.9 pcf (0.6 to 1.9 %) were successfully prepared. A detailed procedure for mixing penta in treating sol...
L L Ingram Jr, H M Barnes, R Shmulsky, D Jeremic


Elimination of alternative explanations for the effect of iron on treated wood
1993 - IRG/WP 93-30006
Amounts of iron which had previously been found in stakes removed from ground contact reduced decay of untreated wood by four brown-rot fungi. This suggested that the effect of iron may be on the preservative. Analysis of the leachates from CCA- and ACA-treated wood blocks first exposed to rusting iron, then to a brown-rot fungus, showed that the increased decay found in the laboratory for wood ex...
P I Morris, J K Ingram, D L Gent


A Soil Bed Test of the Effect of CCA Penetration on the Performance of Hem-fir Plywood
2004 - IRG/WP 04-30332
An accelerated decay test was set up to compare the performance of CCA-treated Western hemlock/amabilis fir plywood treated to meet the preserved wood foundation (PWF) retention standard with various patterns of preservative penetration. Short lengths of treated plywood and comparable untreated material were installed in a soil bed. After eleven years of exposure, the CCA treatments were all sou...
P I Morris, J K Ingram


An investigation of organotin compounds in treated wood using Mössbauer spectroscopy
1983 - IRG/WP 3249
The influence of sample preparation on the 119mSn Mössbauer spectrum of tributyltin chloride in ponderosa pine was investigated. Initial studies with sawdust and compressed discs concluded that the latter were clearly superior. Further studies showed that compressed discs prepared from 0.4 g of treated wood and 0.1 g of cellulose were robust and gave excellent Mössbauer spectra. The possibility ...
J N R Ruddick, J K Ingram


Serviceability of copper naphthenate-treated poles
2000 - IRG/WP 00-30214
Copper naphthenate-treated poles in service were inspected for deterioration, penetration, retention, and serviceability. The study to date has included poles in all hazard zones in the United States. Poles installed by 12 different utilities and eight different treating companies are included in the survey. Both southern pine and Douglas-fir poles and distribution and transmission poles are inclu...
H M Barnes, M H Freeman, J A Brient, C N Kerr Jr


Modification of wood by graft treatment
2003 - IRG/WP 03-40257
New water-repellent systems for wood are needed to improve the weathering characteristics. This study found that treatment of wood with chemical grafting systems imparted substantial water repellency. Different direct oxidative grafting systems were examined. Specifically, KMnO4, Fe(NH4)(SO4)2·12H2O, Fe2(SO4)3·5H2O, and (NH4)2Ce(NO3)6 were used as initiators and styrene as the monomer. All the...
M M Morshed, D D Nicholas, C Pittman Jr, T Schultz


Accidental mold/termite testing of high density fiberboard (HDF) treated with borates and N’N-naphthaloylhydroxylamine (NHA)
2003 - IRG/WP 03-10462
High density fibreboard (HDF) was made from beech and pine furnish (50:50) and treated with boric acid (0.1-3%), borax (0.1-3%) or N'-N-(1,8-naphthalyl) hydroxylamine (NHA) (0.1-1%) prior to gluing with urea formaldehyde (UF) resin in order to determine resistance to Eastern subterranean termites (Reticulitermes flavipes Kollar), the most economically important termite species in North Am...
S N Kartal, H H Burdsall Jr, F Green III


Soft Rot Determines Service Life of L-joints with Low Borate Loading
2008 - IRG/WP 08-30470
As part of a research program on the potential use of borates by the Canadian wood products industry, Forintek set up an L-joint test of untreated and borate-diffusion treated hem-fir (western hemlock and amabilis fir) in 1990. The treated material had a low initial retention of only 0.2% boric acid equivalent and analysis after 5 years revealed no detectable borate close to the tenon. Nev...
P I Morris, J Wang, J K Ingram


Field Tests of naturally Durable North American Wood Species
2008 - IRG/WP 08-10675
There has been little field test performance data published on North American naturally durable species in general, and no published data on second growth material in particular. Yellow cedar (Callitropsis nootkatensis), western red cedar (Thuja plicata), eastern white cedar (Thuja occidentalis), and three wood species reputed to be moderately durable were installed in ground-contact (stakes) an...
P E Laks, P I Morris, G M Larkin, J K Ingram


Effectiveness of MOQ® OX 50 (CCB-Oxide) wood preservative – Part 2: Field tests
2008 - IRG/WP 08-30483
MOQ® OX 50 is a chromated copper borate preservative known around the world as CCB. In Brazil, this product is the only CCB-oxide type preservative with fungicide and insecticide properties registered at the Brazilian Institute for the Environment and Renewable Resources (IBAMA) that complies with the requirements of the Brazilian and European markets for preserved wood. For over five decades, s...
A Gandolfi Jr, C Salvela, D R Macedo, J M Vidal


Selection of Wood-Rotting Basidiomycetes for Inoculation of an Accelerated Soil Bed Test
2014 - IRG/WP 14-20543
There is a need for a test method that guarantees exposure of treated wood to soil and preservative-tolerant wood-rotting basidiomycetes as standard field tests do not do this reliably. The ability of a range of selected wood-rotting basidiomycetes to grow through unsterile forest soil was investigated in a Mason jar test assembly. None of the white-rot fungi in test grew through this soil. Fou...
P I Morris, A Uzunovic, J Ingram


Borate Redistribution in Glulam in an Above Ground Field Test
2014 - IRG/WP 14-30652
Researchers have refocused on the use of boratesin the wood protection industry in the last two decades due to their broad spectrum effectiveness against fungi and insects, and favourable environmental characteristics. This study was designed to determine borate distribution in a limited number of samples from a large field test of composites protected by a combination of coating and borate treatm...
P I Morris, A Temiz, J Ingram


New Method for Pretreatment of Railroad Crossties
2014 - IRG/WP 14-40675
Creosote has been successfully utilized for nearly 150 years for the protection of railroad crossties (sleepers) in the USA and remains today as the most widely used wood preservative for this application. One of the few shortcomings of creosote as a preservative is its inability to penetrate many of the refractory hardwood species which make up the majority of crossties in the USA. Lack of full...
A S Ross, R W Clawson Jr


Buffered Amine Oxide Treatment Systems for Ammonical Copper Wood Preservatives
2014 - IRG/WP 14-40685
Wood is the most versatile, practical and sustainable building material in the world. In modern countries, wood is a well-managed renewable resource that has a small carbon footprint. Wood does suffer from a lack of durability against invasive organisms such as insects and fungi. Steel, aluminum and composites have emerged as viable alternative building materials. These sectors market the defi...
R W Clawson Jr


Field Performance of Old-Growth and Second-Growth Western Red Cedar Fence Posts with and without Barrier Wraps
2015 - IRG/WP 15-10838
Many authors have suggested natural durability may be lower in second-growth western redcedar than in old-growth. One potential means of offsetting a decline in durability is use of physical barriers to separate the wood from soil. In the present work we compared the durability of old-growth and second-growth western red cedar posts, with and without barrier wraps, in a field test. After ten year...
P I Morris, J K Ingram, R Stirling


Buffered Amine Oxide Treatment Systems for Imparting Water Based Azoles/Insecticides in Douglas Fir and Eucalyptus
2015 - IRG/WP 15-40707
In today’s world, wood remains the most versatile, practical and sustainable building material. In contemporary countries, wood is a well-managed renewable resource that has a remarkably small carbon footprint compared to those of steel, aluminium, composites, and concrete. These alternative materials have continued to emerge as viable building materials given the durability issues of untreate...
R W Clawson Jr


Experimental Measurements of Fire Retardants on Plywood at Fire Test
2015 - IRG/WP 15-40709
The use and development of wood composite materials increased in the past few years. However, in Brazil there are some restrictions on these products regarding their use, since it could be considered a potential risk at a fire situation. Thus, becomes evident the need for researches aiming to fit these in safety standards. This study aims to evaluate the efficiency of two new fire retardant produc...
G C A Martins, L A Marcolin, J M Vidal, C Calil Jr


Above-ground performance of a buffered amine oxide treatment system against Mastotermes darwiniensis
2016 - IRG/WP 16-10855
Above-ground H2 field tests against Mastotermes darwiniensis were conducted in far north Queensland to assess the efficacy of buffered amine oxide treatments in the softwoods Pinus sylvestris and P. radiata, and the hardwoods Eucalyptus regnans and E. diversicolor. Untreated hardwoods and slash pine bait wood (P. elliottii) were severely attacked or destroyed, while untreated P. sylvestris was mod...
L J Cookson, R W Clawson Jr


A Treatability Study of Western Wood Species with Water Based Azoles and Insecticides Using Buffered Amine Oxides
2016 - IRG/WP 16-40766
The use of Western U.S. Wood Species remains small in today’s global wood product market when compared to the use of other commercially available softwoods. One reason that other fiber sources, those that may be less naturally durable or exhibit slightly inferior mechanical properties, are utilized is ease of treatment. In an attempt to ensure adequate penetration in commercially important an...
R W Clawson Jr, C N Cheeks, K A Cutler


Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris