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Leaching of inorganic wood preservatives – Investigating the relationship between leachability, dissociation characteristics and long-term leaching potential
2003 - IRG/WP 03-50199
Estimation of the leaching properties of preservative components is greatly affected by the leaching test method applied since not all methods equally consider the physical components responsible for leaching. These include: wetting of the wood and penetration of water (affected by dimensions, amount of end grain, permeability, duration and nature of water exposure); solution of preservative comp...
L Waldron, Y T Ung, P A Cooper


Testing a diffusion and reaction model for the leaching of CCA components from unfixed CCA-treated wood
2002 - IRG/WP 02-50193
A previously described physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is applied to the leaching of CCA components from unfixed wood. Using this model and laboratory leaching experiments with small wood samples immersed in water, the diffusion coefficients and reaction rate constant of Cr6+, total Cr, Cu and As in unfixed CCA-treated...
L Waldron, P A Cooper


Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung


A diffusion and reaction model for the leaching of Cr-VI from unfixed CCA-treated wood
2001 - IRG/WP 01-50169
A physical model applicable to the leaching of any substance undergoing a first-order fixation reaction with wood is presented. Using this model and a laboratory leaching experiment with small wood samples immersed in water, the radial and tangential diffusion coefficients and the reaction rate constants of Cr-VI in unfixed CCA-treated red pine (Pinus resinosa Ait.) are measured. Reaction rate con...
L Waldron, P A Cooper


Kinetics of the dissociation of Cr, Cu, and As in fixed CCA-treated wood
2001 - IRG/WP 01-50168
The results of an experiment showing the kinetics of the dissociation of CCA compo-nents in water within treated wood samples are presented. Dry red pine (Pinus resinosa Ait.) samples were simultaneously vacuum-treated with water, then expressed to re-move the water at successive time intervals. The expressate was then analyzed for Cr, Cu, and As concentration by inductively coupled plasma (ICP). ...
L Waldron, P A Cooper