Your search resulted in 66 documents. Displaying 25 entries per page.
An investigation of organotin compounds in treated wood using Mössbauer spectroscopy
1983 - IRG/WP 3249
The influence of sample preparation on the 119mSn Mössbauer spectrum of tributyltin chloride in ponderosa pine was investigated. Initial studies with sawdust and compressed discs concluded that the latter were clearly superior. Further studies showed that compressed discs prepared from 0.4 g of treated wood and 0.1 g of cellulose were robust and gave excellent Mössbauer spectra. The possibility ...
J N R Ruddick, J K Ingram
An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner
Performance of non-incised CCA-treated hem-fir decking
1993 - IRG/WP 93-40004
The question of what preservative penetration will provide an acceptable service life for treated wood in residential above-ground applications is topical in North American standards committees. Non-incised CCA-treated nominal 2 x 4 inch² hem-fir decking with penetrations close to the proposed CSA O80 2 decking standard of 80% over 5 mm, has remained without decay after 10 years exposure in south...
P I Morris, J N R Ruddick
The possible role of mobile CCA components in preventing spore germination in checked surfaces, in treated wood exposed above ground
2001 - IRG/WP 01-30263
Untreated check surfaces are often exposed in CCA-treated lumber of refractory species used above ground since, during weathering, some checks develop beyond the preservative penetrated zone. However, decay is seldom observed in these checks even after many years of exposure. It is hypothesized that minor amounts of mobile CCA preservative components redistribute during weathering into checks, and...
S Choi, J N R Ruddick, P I Morris
The fungal degradation of quaternary ammonium compounds in wood
1998 - IRG/WP 98-10263
This work focuses on the biodegradation of didecyldimethylammonium chloride (DDAC) by the mould fungus Gliocladium roseum within a woody matrix. Three sawdust types, distinguished by their treatment and amount of DDAC retained, were inoculated with the fungus and their DDAC loss was measured over 11 weeks. The rates of degradation varied depending on the sawdust; however, a significant loss of DDA...
J W Dubois, J N R Ruddick
The influence of copper (II) chemicals on the weathering of treated wood. Part 1: ACQ treatment of wood on its weathering
1994 - IRG/WP 94-30040
Wood weathering can be accelerated by alkylammonium compound (AAC) treatment, and slowed by ammoniacal copper quat (ACQ) treatment. This study aims at investigating the influence of ACQ treatment of wood, especially the present of copper (II), on its weathering. ACQ, CCA and DDAC treated microtomed sections of southern yellow pine earlywood were prepared and naturally weathered for five periods, t...
Ruiying Liu, J N R Ruddick, L Jin
Fumigant movement in Canadian wood species
1984 - IRG/WP 3296
Pole sections prepared from seven Canadian wood species (Thuja plicata, Thuja occidentalis, Pinus contorta, Pinus resinosa, Pinus banksiana, Pseudotsuga menziesii, southern yellow pine) were fumigated with chloropicrin, methylisothiocyanate and Vapam and the rates of fumigant penetration determined. All three fumigants were applied directly into holes bored radially into the pole sections. Analysi...
J N R Ruddick
Field testing of alkylammonium wood preservatives
1983 - IRG/WP 3248
The field test performance of five alkylammonium wood preservatives is described. The relative effectiveness of three unmodified formulations was determined by calculation of a Performance Index. Of the three, didecyldimethylammonium chloride was found to be superior to octyldecyldimethylammonium chloride, and both were more effective than alkyltrimethylammonium chloride. However, none were consid...
J N R Ruddick
A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick
X-ray photoelectron spectroscopic analysis of CCA treated wood
1992 - IRG/WP 92-3700
Ponderosa pine and Douglas-fir wood sections were treated with CCA preservative. To elucidate the mechanism of fixation of the CCA, the wood surface was analyzed by X-ray photoelectron spectroscopy (XPS). CCA treatment increased C1 (carbon bonded to carbon and/or hydrogen) and decreased C2 (carbon bonded to one oxygen) in XPS C1s spectra, both in unextracted and pre-extracted sections. This sugges...
J N R Ruddick, K Yamamoto, P C Wong, K A R Mitchell
Application of a novel strength evaluation technique during screening of wood preservatives
1986 - IRG/WP 2262
The effectiveness of CCA and ACA in treated aspen mini stakes tested using a novel bag procedure, with unsterile soil fortified with Chaetomium globosum and Ceratocystis albida, is reported. Good agreement between toxic limits determined using the standard weight loss procedure, and those determined by the strength technique were found, with some indication that the strength loss method is more se...
J N R Ruddick
Application of energy dispersive X-ray fluorescence spectrometry to the quantitative analysis of organotin preservative solutions and treated wood
1978 - IRG/WP 3125
One technique frequently used for the quantitative analysis of material containing inorganic compounds is energy dispersive X-ray fluorescence spectrometry. It has been shown previously that this technique can be readily used to determine the retentions of chromated copper arsenate and ammoniacal copper arsenate treated wood. This paper reports the results of a preliminary study to determine wheth...
J N R Ruddick
Incomplete fixation of chromium in the pre-treated wood with a solution of copper and arsenic compounds
1995 - IRG/WP 95-50052
Ponderosa pine wood thin sections were treated with a combination of chromium, copper, and arsenic chemicals. The wood sections was analyzed by electron spin resonance spectrometry (ESR) and X-ray photoelectron spectrometry (XPS) to elucidate the mechanism of fixation of the chromated-copper preservatives. The wood subjected to the two-step treatment with copper and arsenic followed by chromium ex...
J N R Ruddick, K Yamamoto, F G Herring, P C Wong, K A R Mitchell
Evaluating the potential of amine chemicals for use as wood protecting agents. Part 1: Investigation of cation components of quaternary ammonium compounds
1994 - IRG/WP 94-30049
Quaternary ammonium compounds (quats) have shown a great potential as more environmentally acceptable wood preservatives. In order to identify chemicals possessing the wood protecting potential, an evaluation was carried out of a range of commercially available 'quats', using a modified soil block test. Ponderosa pine sapwood blocks were treated with selected 'quat&a...
Hang Tang, J N R Ruddick
A review of incising as a means of improving treatment of sawnwood
1994 - IRG/WP 94-40019
The use of incising, perforation of the wood surface, is increased because of the need to treat refractory wood species. This paper reviews the development of incising and shows how the required incising patterns can be determined and specified. Most of the development has been in the area of toothed-roller incisors because of their rapid throughput. Needle, Laser, drill and water jet incisors hav...
P I Morris, J J Morrell, J N R Ruddick
Aspects of the fungal degradation of quaternary ammonium compounds in liquid culture
1997 - IRG/WP 97-30160
Didecyldimethylammonium chloride (DDAC) is a quaternary ammonium compound (QAC) that has found use as an anti-sapstain preservative for the transportation of softwood lumber from Canada to overseas markets. However, its use is limited by the knowledge that certain mould fungi seem capable of degrading it. The aim of this research was to gain knowledge about the fungal degradation of DDAC. The effe...
J W Dubois, J N R Ruddick
Leachability of didecyldimethylammonium chloride (a quaternary ammonium compound) from four wood species
1982 - IRG/WP 3204
Sapwood blocks prepared from red pine, ponderosa pine, southern yellow pine and hem-fir (a commercial mixture of western hemlock and amabilis fir) were treated with didecyldimethylammonium chloride, (an alkylammonium compound, AAC). After oven drying the blocks were vacuum impregnated with distilled water and subjected to a static leach cycle for 48 hours. The leachate was analyzed and the amount ...
J N R Ruddick, A R H Sam
Kerfing reduces checking in ACA-treated western white spruce poles
1988 - IRG/WP 3477
Western white spruce poles, pressure treated with pentachlorophenol and ammoniacal copper arsenate (ACA) were installed in the Westham Island test site. The pentachlorophenol treated poles were unkerfed, while both unkerfed and kerfed ACA poles were placed in test. The checking and kerf width and depth were recorded at the time of installation. After ten years of weathering the checking characteri...
J N R Ruddick
Bioremediation of surfactant contaminated waste
1996 - IRG/WP 96-50070
The objective of this work was to determine the potential of fungi as agents for the bioremediation of wastes (particularly wood and soil) contaminated with quaternary ammonium compounds (QACs). Until now only bacteria have been investigated for this purpose. Tolerant strains of Gliocladium roseum and Verticillium bulbillosum were studied for their ability to degrade the following QACs: didecyldim...
J L Bürgel, J Dubois, J N R Ruddick
The Copper Tolerance of Mycelium vs. Spores for Two Brown Rot Fungi
2002 - IRG/WP 02-10422
The copper tolerance of two brown rot fungi, Gloeophyllum sepiarium and Oligoporus placentus, has been tested using both mycelia and basidiospores as inoculum sources. Mycelial growth of O. placentus on agar medium was shown to be much more tolerant to copper (as copper sulfate) than that of G. sepiarium. However, there was no difference in copper tolerance of basidiospores between the two specie...
S Choi, J N R Ruddick, P I Morris
Determination of the amine to copper ratio remaining in wood after leaching
2002 - IRG/WP 02-30285
The effectiveness of the protection and the environmental impact of the treated wood are two of the most important aspects that need to be understood for all preservatives. Both are particularly influenced by the loss of biocidal components from treated wood. For amine copper preservatives, copper fixation determines the leaching resistance of the copper and amine compounds formed in wood. Previou...
N Lucas, J N R Ruddick
The effect of storage and subculturing on in vitro fruit body formation and spore production in Gloeophyllum sepiarium and Oligoporus placentus
2001 - IRG/WP 01-20232
Spores are widely assumed to be the main mode of infection of wood in conditions conducive to decay above ground. In order to supply spores on demand as an experimental material, fruiting body and basidiospore production in vitro by Gloeophyllum sepiarium and Oligoporus placentus have been examined. The optimum medium, time to spore production, and duration of fruiting as well as fruiting body sha...
S Choi, J N R Ruddick, P I Morris
Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick
Isolation and identification of non-decay fungi affecting the performance of alkylammonium compounds
1993 - IRG/WP 93-10020
The isolation of DDAC tolerant fungi was carried out on lumber treated with a range of antisapstain chemicals containing DDAC as one of their active ingredients. The tolerant fungi were selected by using malt media spiked with DDAC (100 and 2500 ppm). Isolations were tentatively identified into a range of fungi commonly found associated with wood deterioration (i.e. Penicillium sp. and Trichoderma...
A K Doyle, J N R Ruddick
The influence of staining fungi on the decay resistance of wood treated with alkylammonium compounds
1984 - IRG/WP 3308
Although found to be very effective in laboratory tests, alkylammonium compounds (AAC's) have failed to perform as well in field stake tests. Examination of leachability showed that this was not the cause. The present study investigated the possibility that staining fungi, (which have been observed to rapidly infect the field stakes), degrade the AAC wood preservative. Soil-blocks were tr...
J N R Ruddick