IRG Documents Database and Compendium


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Laboratory decay test of Burmese in and kanyin treated with three wood preservatives
1982 - IRG/WP 3210
Laboratory decay tests were performed on samples of In (Dipterocarpus tuberculatus Roxb.) and Kanyin (Dipterocarpus alatus Roxb. and Dipterocarpus turbinatus Gaertn f.) pressure treated with three wood preservatives - copper arsenic additive (CAA - a variation of ammoniacal copper arsenate), Arquad C-33 (a waterborne quaternary ammonium formulation), and tributyltin acetate (TBTA) dissolved in eth...
J N R Ruddick, R S Smith, A Byrne


Studies of the distribution and degradation of tributyltin naphthenate in double-vacuum treated wood
1983 - IRG/WP 3230
The effects of forced solvent evaporation by kilning redwood (Pinus sylvestris) that has been double-vacuum treated with tributyltin naphthenate (TBTN) have been investigated. Contrary to previous studies reported, it has been shown that forced evaporation can have a considerable influence on the losses of the fungicide. It has been found that, whether the solvent is allowed to evaporate slowly or...
J Jermer, M-L Edlund, W Hintze, S V Ohlsson


Stability and performance of tributyltin compounds
1984 - IRG/WP 3275
Based on the critical examinations of the disputable permanence of tributyltin compounds in wood, this paper deals with a number of examinations of the relative evaporation, thermal stability and oxidation stability of some TBT-compounds. While thermal and oxidative stability is high for all TBT-species, the relative evaporation at elevated temperature is highly variable, and lowest for the TBT-es...
F Imsgard, B Jensen, H A B Landsiedel, H Plum


An investigation of organotin compounds in treated wood using Mössbauer spectroscopy
1983 - IRG/WP 3249
The influence of sample preparation on the 119mSn Mössbauer spectrum of tributyltin chloride in ponderosa pine was investigated. Initial studies with sawdust and compressed discs concluded that the latter were clearly superior. Further studies showed that compressed discs prepared from 0.4 g of treated wood and 0.1 g of cellulose were robust and gave excellent Mössbauer spectra. The possibility ...
J N R Ruddick, J K Ingram


The compatability of tributyltin fungicides and synthetic pyrethroid insecticides as wood preservatives
1987 - IRG/WP 3414
The stability of three synthetic pyrethroids, cypermethrin, deltamethrin and permethrin, to selected tributyltin compounds, Bu3SnX {where X = OSnBu3, Cl, 02CC6H5, O2C (Naphthenyl), OSO2Et}, (Bu3SnO)3PO and {NBu4} {Bu3SnCl2}, in toluene solution was investigated by infra-red spectroscopy over a six month period. It was found that only (Bu3Sn)2O reacted with the pyrethroids and that their order of r...
S J Blunden, R Hill


Giftwirkung einiger organischer Zinn-Verbindungen auf Eilarven von Hylotrupes bajulus (L.). [Toxic efficacy of some organic tin compounds against egg larvae of Hylotrupes bajulus (L.)]
1978 - IRG/WP 2120
The toxic values of 12 organic tin compounds towards newly hatched larvae of Hylotrupes bajulus were determined after 4- and 12-week test periods in comparison with bis-tri-n-butyltin oxide (TBTO). Tri-n-butyltin benzoate as well as the 2-, 3- and 4-methyl benzoate of tributyltin oxide were equally effective as TBTO and the latter two were somewhat more effective after a 12-week test period. Almos...
G Becker


Tributyltin compounds in wood preservation: Health and safety aspects
1986 - IRG/WP 3396
The toxicity of organotin compounds of the general formula RnSnX(4-n) depends strongly on the type of organic substituent R and on the degree of substitution n. The residues X, not bound through a tin-carbon bond, are however of much smaller influence. Furthermore, there is evidence that hydrolysis of tributyltin esters will occur under environmental as well as under physiological conditions to TB...
H Schweinfurth, P Günzel, H A B Landsiedel, R Lang, R Reimann, C Schöbel, F Siegmund


The effectiveness of three tributyltin compounds in beech against soft rot fungi using a soil-bed technique: A preliminary report
1986 - IRG/WP 3390
The effectiveness, towards soft rot fungi, of bis (tributyltin) oxide, tributyltin ethanesulphonate (TBTES) and benzyltributylammonium tributyldichlorostannate in both leached and unleached beech stakes is compared to that of a CCA preservative (Tanalith CT 106), using a soilbed technique. In addition, the effect of test solvent (water or toluene) on the performance of TBTES is evaluated. Total ti...
R Hill, A H Chapman, B Patel, A Samuel, J K Carey


Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland


A laboratory evaluation of tributyltin ethanesulphonate as an aqueous fungicide in wood preservation
1983 - IRG/WP 3229
Toxic limit data, using both leached and unleached wood test blocks, are reported for aqueous solutions of tributyltin ethanesulphonate against four Basidiomycete fungi, Poria placenta, Gloeophyllum trabeum, Coriolus versicolor and Coniophora puteana. An in situ study of the tributyltin compound in Scots pine and ponderosa pine sapwood has been carried out, using the technique of 119mSn Mössbauer...
R Hill, P J Smith, J N R Ruddick, K W Sweatman


Preliminary observations on tributyltin treated Scots pine sapwood using 119Sn (Mössbauer and NMR) spectroscopic techniques
1984 - IRG/WP 3312
119mSn Mössbauer data are presented for bis(tributyltin) oxide, tributyltin ethanesulphonate, bis(tributyltin) carbonate and tris(tributyltin) phosphate, both in the pure form and in Scots pine sapwood. The structures proposed for these compounds, in the solid state, are supported by 119Sn nuclear magnetic resonance spectroscopy.
R Hill


A field evaluation of modified and unmodified alkylammonium compounds
1987 - IRG/WP 3436
Laboratory soil block studies of alkylammonium compounds (AAC's) at Forintek and other research establishments have shown that they can prevent decay by standard wood-destroying fungi. Their performance in field tests, however, has been disappointing. Following investigation of possible causes for this poor field performance, stakes treated with modified AAC's were installed at W...
J N R Ruddick


Co-operative studies on determining toxic values against wood-destroying Basidiomycetes: Progress report to May 1989
1989 - IRG/WP 2339
This document reports progress on the co-operative study between nine laboratories set up following the proposals contained in Document IRG/WP/2316. Results have been received from two laboratories. Toxic values data have been established successfully using the test fungus Coniophora puteana but problems have been encountered with the other test fungi....
A F Bravery, J K Carey


Chemical compounds from Eperua falcata and Eperua grandiflora heartwood and their biological activities against wood destroying fungus (Coriolus versicolor)
2005 - IRG/WP 05-30373
The chemistry analysis of the compounds present in dichloromethane and ethanolic fraction as well as bioassays enables to understand the durability differences of Eperua falcata and Eperua grandiflora. The principal distinction between these two species is the acidic subfraction of diterpenoic extract, which is antifungic in Eperua falcata when tested in in-vitro conditions. This study also enable...
N Amusant, C Moretti, B Richard, E Prost, J M Nuzillard, M-F Thévenon


Observations on the colonization of freshly-felled timber treated with prophylactic chemicals by mould and sapstain fungi
1989 - IRG/WP 1394
Field tests using freshly felled pine sapwood were set up to determine the effectiveness of a range of antisapstain compounds and to study the problems of colonization by mould and sapstain fungi. Differences were recorded both in the overall performance of the compounds and also their selectivity in controlling specific fungal types. These results were found to be useful in gaining a better under...
G R Williams, D A Lewis


Preliminary results of investigations on screening test of chemical compounds suitable for the preservation of lignocellulosic materials against biodeterioration
1976 - IRG/WP 262
This paper investigates the possibilities of reducing the time needed for the determination of the effectiveness of chemical compounds from the point of view of their eventual application to lignocellulosic materials for preservation against decay and soft-rot....
K Lutomski, S S Neyman


La rôle de l'expert dans l'évaluation toxicologique
1990 - IRG/WP 3589
C Boudene


Results of co-operative studies on determining toxic values against wood-destroying Basidiomycetes. Preliminary report to Sub-group members
1986 - IRG/WP 2271
A F Bravery, J K Carey


Dimensional stabilization of wood with dimethylol compounds
1987 - IRG/WP 3412
This study showed that a substantial degree of dimensional stability can be imparted to wood by crosslinking with low concentrations of dimethyloldihydroxyethyleneurea. It was demonstrated that by selecting the right catalyst system the cure temperature can be reduced to the point that strength loss of the treated wood is minimized....
D D Nicholas, A D Williams


Fluorine compounds for wood preservation
1971 - IRG/WP 304
Fluoride compounds have gained a considerable importance in wood preservation, especially in Germany and some other countries of Europe. They are used as single compounde or in mixtures of different compounds. In the International Research Group on Wood Preservation which continues the activities of a former OECD-Group, it was moved to prepare a survey on fluorides in wood preservation together wi...
G Becker


Accelerated ageing of preservatives in treated wood
1988 - IRG/WP 3476
New preservatives are tested in the laboratory and often in field tests before they are used commercially. Some preservatives, however, tested in the laboratory do not show the expected stability when used in service. The differences between laboratory tests and practical use can never be completely eliminated but must be minimized as far as possible by relevant testing methods. Studies of the eff...
M-L Edlund, B Henningsson, B Jensen, C-E Sundman


The 1999-2000 annual report for the IRG - Wood Preservation in Egypt
2000 - IRG/WP 00-40188
The wood destroying insects in Egypt are belonging to several families of Coleoptera, Lepidoptera and Isoptera. Imported woods are treated by The Agricultural Quarantine or the authorized companies. The materials used for protection as pre-treatment are the same of the treatment. They are Bromide methyl, copper or fluoride salts, organo-phosphorus compounds, pyrethroides, creosote or creosodial. A...
S I M Moein


Testing of alkylammonium compounds
1981 - IRG/WP 2152
Following laboratory soil block tests which showed that Bardac 20 possessed a fungicidal threshold similar to that of chromated copper arsenate, treated ponderosa pine sapwood stakes were installed in a field test site near Vancouver, Canada. Two years after installation all the stakes show signs of fungal degradation. Seven stakes have been removed from the test due to total loss of strength afte...
J N R Ruddick


Fungicidal and termiticidal effectiveness of alkylammonium compounds
1983 - IRG/WP 3232
This paper is related to effectiveness of several AAC's against wood decay fungi and termites by Japanese standardized test methods....
K Tsunoda, K Nishimoto


Some thoughts on the future strategy for eradicating Serpula lacrymans from a building
1989 - IRG/WP 1405
We now have a clear view of the mechanism of translocation of nutrients in the mycelium of Serpula lacrymans which is one of the physiological processes underlying the remarkable capacity of this fungus to spread through a building. Here the elements of the mechanism of translocation are dissected out to suggest avenues which might be followed in the search for new ways for eradicating the fungus ...
D H Jennings


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