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Microscopic FT-IR depth profiling study of photo-induced degradation in wood
2001 - IRG/WP 01-20229
FT-IR microspectroscopy was used to monitor the changes in the chemical composition at various depths from the photo-irradiated surface of sugi (Cryptomeria japonica D. Don) sapwood. The radially cut wood face was exposed to artificial solar radiation from a xenon light source at 375 Wm-2 (in a 300 - 700 nm spectral range) for up to 600 h. The IR depth profiling spectra showed that the artificial ...
Y Kataoka, M Kiguchi.


Copper nanoparticles in southern pine wood treated with a micronised preservative: Can nanoparticles penetrate the cell walls of tracheids and ray parenchyma?
2010 - IRG/WP 10-30547
This study tests the hypothesis that copper nanoparticles can penetrate the cell walls of southern pine wood treated with a micronised preservative. We examined the nanodistribution of particles in tracheid and ray parenchyma cell walls using state-of-the-art HR (High Resolution)-TEM and HR-STEM (Scanning Transmission Electron Microscope)-EDX. These devices are capable of atomic-scale resolution. ...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Copper Nanoparticles in Southern Pine Wood Treated with a Micronised Preservative: Nanodistribution of Copper in the Pit Membrane and Border of an Earlywood Bordered Pit
2011 - IRG/WP 11-30566
Copper nanoparticles can penetrate the cell walls of unlignified parenchyma cells in southern pine wood treated with a micronised wood preservative, but they are excluded from lignified tracheid walls. This paper extends these observations to include the cell wall layers of the bordered pit. Focused ion beam and ion milling were used to make an ultra-thin section of the cell wall layers of an earl...
H Matsunaga, Y Kataoka, M Kiguchi, P Evans


Use of Variable Pressure Scanning Electron Microscopy for in situ Observation of Degradation of Wood Surfaces during Artificial Weathering
2012 - IRG/WP 12-20489
Variable pressure scanning electron microscopy (VPSEM) is capable of observing electrically non-conductive materials like wood without the need to render the surface conductive by applying a coating of gold, platinum or carbon. Hence, there is the possibility that VPSEM could be used to non-destructively follow the structural changes occurring at wood surfaces during weathering, because specimens ...
F Hatae, Y Kataoka, M Kiguchi, H Matsunaga, J Matsumura


Accessibility of Wood Cell Walls to Well-defined Platinum Nanoparticles
2012 - IRG/WP 12-20494
Copper nanoparticles are found in the walls of parenchyma cells in southern pine sapwood treated with a micronised wood preservative, but they are absent from tracheid walls. Hence, we hypothesized that small nanoparticles can penetrate the walls of unlignified parenchyma cells, but are excluded from lignified tracheid walls. This paper tests this hypothesis by treating pine sapwood with an aqueou...
H Matsunaga, Y Kataoka, M Kiguchi, P D Evans