Adsorption of ACQ and CuMEA Wood Preservatives in Red pine

IRG/WP 05-30374

C Tascioglu, P A Cooper, Y T Ung

The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions without DDAC were also evaluated for comparison. After the treatments, samples were conditioned without drying either at 22° C for seven weeks or at 50° C for one week. At different times after treatment, expressate from the specimen blocks was analyzed for copper, DDAC and MEA. Copper and MEA adsorption by the wood cell walls followed similar trends. The equilibrium copper adsorption ranged from 44% at high ACQ retentions to about 95% for the lowest retention while the values in the CuMEA system were slightly higher for the higher retentions, ranging from about 54% to 93%. This suggests that DDAC may compete with CuMEA for reaction sites at high ACQ concentrations. Adsorption of DDAC into the wood cell wall matrix was rapid; at all solution concentrations, more than 80% of DDAC was adsorbed by red pine sapwood within minutes after treatment.

Keywords: ACQ, copper amine, DDAC, MEA, quaternary ammonium compound, stabilization

Conference: 05-04-24/28 Bangalore, India

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