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Tropical In-Ground Durability of Structural Sarawak Hardwoods Impregnated to High Retention with CCA-salts, CCA-oxide and FCAP after 20 Years Exposure
2005 - IRG/WP 05-30384
Statistical analysis (ANOVA) was conducted on durability (termite and decay combined) rating data collected over 20 years exposure period of over 140 species of Sarawak timbers with altogether 30,000 stake specimens, at the Forest Department’s Sibu “graveyard” stake test sites from 1977. About 20 replicated stakes were pressure-treated to refusal with 10% g/ml concentration of up to 3 CCA-sa...
Wang Choon Ling, A H H Wong


Preservatives stains as exterior wood finishes
1977 - IRG/WP 389
For many years wood preservatives and paints have been used as the only treatment for exposed wood surfaces. Because of the inherent color of the preservatives, such as creosote, the wood surface was stained as well as protected from attack by micro-organisms. Paints protect surfaces from weathering, but recently, with an increased interest in maintaining the more natural appearance of exterior wo...
D W French


Treatment of wood by diffusion of salts
1976 - IRG/WP 368
A brief survey is given on the treatment of wood by diffusion of salts. The compounds used for this process, mainly boron and fluorine compounds, are mentioned and the factors influencing diffusion described. The main pre-condition is a high moisture content of the wood of above 40%. Fields of application are fresh roundwood, remedial treatment of poles and sleepers, preservation of posts and espe...
G Becker


Amine copper reaction with wood components: acidity versus copper adsorption
1997 - IRG/WP 97-30161
The bonding sites for copper in wood from CCA, as well as ammoniacal/amine based systems, has long been a topic of investigation. Both phenolic and carboxylic functional groups have been discussed as potential bonding sites for copper. However, no consensus on the adsorption mechanism has been realized. Thus, the selective adsorption of copper in southern yellow pine from ethanolamine-copper solut...
S M Thomason, E A Pasek


The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield


Interaction of copper-amine complexes with wood: Influence of copper source, amine ligands and amine to copper molar ratio on copper retention and leaching
1999 - IRG/WP 99-30203
The absorption and leachability of copper in copper amine (Cu-EA) treated wood are influenced by the formulation and the composition of copper amine treating solutions. The sources of copper used, Cu(OH)2, CuCO3, CuSO4 and Cu(NO3)2, in the copper amine complex formulation affect the leachability of copper. Data show that copper amine from CuSO4 and Cu(NO3)2 treated wood has less copper loss during...
Jun Zhang, D P Kamdem


The future for chromium in wood preservation
1985 - IRG/WP 3332
Most water-borne preservatives contain CrVI compounds, originally to reduce corrosion although now also to improve toxicant fixation. Chromium contributes to preservation and this is recognised in, for example, New Zealand and USA where chromium contents are included in calculations of overall preservative activity of CCA formulations, but chromium may also have anti-stain and joinery (millwork) p...
B A Richardson, T R G Cox


Inhibition of the biodegradation of coniferous and broadleaved wood by new imidazolium salts
2003 - IRG/WP 03-30320
Studies were carried out on fungicidal values of fourteen potential wood preservatives – modified quaternary heteroaromatic compounds using the screening agar-block. The vacuum treated blocks (22mm x 17mm x 12mm) of Scots pine (Pinus sylvestris L.), spruce (Picea excelsa L.), beech (Fagus silvatica L.) and birch (Betula verrucosa Ehrh.) with testing compounds were exposed to Coniophota puteana a...
J Zabielska-Matejuk, J Pernak, W Wieczorek


Effects of the delay in the beginning of treatment on absorption and distribution of water-soluble salts in posts treated by sap-replacement method
1992 - IRG/WP 92-3719
One of the most important matters in green wood treatments, such as sap-replacement method, is knowing the longest time available for beginning treatment without losing efficacy. In this paper, the influence of this factor on absorptions and distribution of the preservative into the wood is analized. Tree start-up times were first chosen: 3-6 hours, 48 h and 120 h after being cut down. The treatme...
M V Baonza Merino


Amine Oxides for Use in Wood Protection: I. A Formulation Adjuvant and Performance Enhancer for Wood
2007 - IRG/WP 07-30425
Amine oxides have great potential for use in the area of wood protection. This paper highlights the advantages of using amine oxides as a formulation adjuvant and performance enhancer for different azoles. It was found that azoles are readily soluble in aqueous amine oxide solutions and form soluble concentrates. These azole/amine oxide concentrates have excellent storage stability and can be dilu...
Xiao Jiang, L Walker


Amine Oxides for Use in Wood Protection: II: Water Repellent Agents for Wood
2007 - IRG/WP 07-30426
Wood treated with cetyl and stearyl amine oxides was evaluated to determine its long term water repellency. Comparative water uptake data, generated during two years of outdoor exposure, illustrated that Lonza’s products, Barlox® 18S (N-octadecyl-N, N-dimethylamine oxide) and Barlox® 16S (N-hexadecyl-N, N-dimethylamine oxide), were effective water repellent agents, imparting lasting water res...
Xiao Jiang, L Walker


Amine Oxides for Use in Wood Protection: III. Penetration Aids for Wood
2008 - IRG/WP 08-30461
This paper highlights the advantages of using amine oxides as penetration aids for quaternary ammonium compounds (quats) and azoles in the area of wood protection. It was found that the use of amine oxide effectively enhanced the penetration and distribution of quats and azoles. For both southern yellow pine (SYP) and Douglas fir wood samples, the addition of cocodimethylamine oxide (Barlox® 12) ...
Xiao Jiang


Effect of steam on fixation of Cu-amine preservative treated wood
2008 - IRG/WP 08-50251
The rates of copper fixation in copper amine preservative treated wood were investigated with different fixation conditions (20° with drying and 50° without drying) and post-steaming. We also measured the degree of leaching for other biocide components (azoles, quatz, and Cu-HDO). Treatments conditioned at 20° with drying required 50 days or more to fix in woods. While copper was stabilized i...
Sung-Mo Kang, In-Yong Hwang, Suk-Kuwon Kim


Biological efficacy of micronized copper systems
2008 - IRG/WP 08-30485
Soil block, fungal cellar and field stake test data will be presented for micronized copper systems. The copper portion of the formulations is present as a fine dispersion of "micro" particulates while the co-biocide is present as either a soluble quat or an azole containing emulsion. This testing generally used the amine based counterpart as the control preservative system and the micronized fo...
C R McIntyre, M H Freeman


Laboratory Studies on Copper Availability in Wood Treated with Soluble Amine Copper and Micronized Copper Systems
2008 - IRG/WP 08-30489
A laboratory method has been employed to investigate the level of soluble copper in wood treated with various copper-based preservative systems, such as micronized copper (particulate copper) and amine copper solutions. This report describes the methodology and preliminary results on determination of the soluble copper in the treating solutions and the treated wood by these systems, as well as th...
L Jin, P Walcheski, A Preston


Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper


Copper preservative systems: A rapid investigation into effects of co-biocides and used treating solutions
2010 - IRG/WP 10-30541
The efficacy of various micronized and amine copper preservative systems was evaluated using soil block testing with the copper tolerant brown rot fungi, Postia placenta. The American Wood Protection Association E22 protocol was used to compare the relative efficacy of preservatives by monitoring compressive strength losses of the systems in southern pine wood. As information, the weight losses ...
T F Shupe, K Ragon, Q Wu, M H Freeman, C R McIntyre


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Studies on Effect of pH on Copper Availability in Copper-Based Preservatives
2010 - IRG/WP 10-30549
Laboratory methods have been employed to investigate the pH effect on the copper solubility of basic copper carbonate. The pH was controlled using two different approaches. One was with the adjustment of pH of the solutions by acid or base using sulfuric acid or sodium hydroxide until the solution equilibriums were obtained for each defined pH. A second approach was to control pH with buffer sol...
L Jin, P Walcheski, A F Preston


Influence of Copper Preservative Type on Earlywood and Latewood Distribution of Copper in Treated Wood
2010 - IRG/WP 10-40507
Some of the new water based copper containing wood preservative systems use particulate “micronized” copper as the primary biocide instead of the more traditional soluble amine copper based systems. Studies were conducted to investigate how this difference in the type of copper system might impact both initial and post drying distribution of the preservatives in wood. Of specific interest wa...
A Zahora


Standardized Field Trials with Micronized Copper
2011 - IRG/WP 11-30564
In 2008, an extensive review of all available data from standardized tests of micronized copper systems was published and there has been considerable work since then. This paper discusses over 20 field stake trials underway in well-known sites such as Gainesville, FL, Hilo, HI and the Dorman and Saucier sites in MS as well as tests from Australia and New Zealand. In addition, 4 ground proximity ...
C R McIntyre, M H Freeman


Further Studies on the Distribution of Copper in Treated Wood Using an XRF Microscope Technique
2011 - IRG/WP 11-40549
There are two distinct forms of copper in aqueous copper based wood preservative systems that are currently used in the United States for treatment of southern pine lumber. These are systems using either soluble copper (typically amine based) or the more recent particulate or “micronized” copper as the primary biocide. Studies reported last year showed that there were distinct differences in...
A Zahora


Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products. In this study the efficacy of wood treated with micronized copper, zinc oxide and their mixture was compared to that of wood treated with soluble amine copper oxide with subterranean termites in a laboratory test. All of the formulations tested were effective in controlling wood degradation by the termites...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani


State of progress of utilisation of supramolecular gels for formulations of water-soluble wood preservation salts
2013 - IRG/WP 13-30630
This article is a compilation of the work done so far concerning the utilization of supramolecular hydrogels, built on low-molecular-weight amphiphilic molecules and containing boron salts conferring fungicidal properties. Mixing boron with thermoreversible hydrogels allows the formation of a supra molecular network incorporating boron and important amount of water upon gelification of the solutio...
F Obounou Akong, P Gérardin, M-F Thévenon, C Gérardin-Charbonnier


Effect of Nano and Micronized Particles as Wood Preservatives for Termite Control
2013 - IRG/WP 13-30620
Subterranean termites are a major factor in the biodegradation of wood constructor products. In this study the efficacy of wood treated with micronized copper, zinc oxide and their mixture was compared to that of wood treated with soluble amine copper oxide with subterranean termites in a laboratory test. All of the formulations tested were effective in controlling wood degradation by the term...
M Akhtari, D Nicholas, A Rowlen, M Arefkhani


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