IRG Documents Database and Compendium


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Long term marine performance of ACZA treated Hem fir in Krishnapatnam harbour, east coast of India
2006 - IRG/WP 06-30409
The performance of Hem fir (Tsuga heterophylla) and Southern pine (Pinus sp.) treated with ammoniacal copper zinc arsenate (ACZA) and copper dimethyldithio carbamate (CDDC) at two retention levels of each preservative was assessed in tropical marine waters at Krishnapatnam harbour on the east coast of India. Panels treated with ACZA of lower loadings (23.1 Kg/m3) had failed in 38 months while the ...
B Tarakanadha, K S Rao, J J Morrell


Copper borate for the protection of engineered wood products
2006 - IRG/WP 06-40334
Copper borate was evaluated for use in protecting oriented strand board (OSB) from mould, decay, and termites. Aspen OSB bonded with either phenolic or isocyanate resin was treated with several formulations of copper borate at various loadings from 0.26 to 4 percent by weight. These panels were then tested to determine the impact of the preservative on mechanical properties as well as resistance ...
R Smart, W Wall


Laboratory evaluation of borate amine: Copper derivatives in wood for fungal decay
2010 - IRG/WP 10-30543
The aims of this study were to evaluate borate: amine: copper derivatives in wood for fungal decay protection as well as the permanence of copper and boron in wood. Wood treated with each of four derivatives of borate:amine:copper prevented fungal decay. Disodium tetraborate ecahydrate (Borax):amine:copper derivatives with retentions of 0.61 to 0.63% after water leaching prevented decay by Gloeo...
G Chen


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Mold Control for Treated Lumber in Block-Stack Storage Conditions
2012 - IRG/WP 12-30588
The mold development and control for freshly treated and block-stacked wood have been evaluated using a green house mold testing method. The results for the mold resistance of several commonly used water boron preservative treatment systems, such as ACQ, Copper Azole, and borates with and without inclusion of mold inhibitors are presented. The data suggest that the different preservative treatme...
L Jin, P Walcheski, A Preston


Termite resistance of copper-based preservative supplemented aspen strandboards
2012 - IRG/WP 12-30594
Termite resistance of aspen strandboards treated with various copper-based preservative systems was evaluated in field exposure tests. Five copper-based chemicals or zinc borate were blended into aspen furnish at three retention levels prior to pressing. Tebuconazole or 4,5-dichloro-2-N-octyl-4-isothiazolin-3-one (DCOI) were added as co-biocides to selected copper-based treatments. Sections from...
J J Morrell, C Vidrine, A Preston, L Jin


Incidence of soft rot attack on preservative treated Douglas-fir poles: a preliminary survey
2014 - IRG/WP 14-10818
Occurrence of soft rot decay in Douglas-fir poles treated with ammoniacal copper zinc arsenate (ACZA) or pentachlorophenol in oil was studied. Soft rot was less prevalent in poles treated with penta, but some soft rot was found in approximately 20 % of poles examined. Soft rot was more common in poles treated with ACZA, and, when present, was found in almost 20% of the cells examined. The potenti...
P Torres Andrade, J J Morrell


Ammoniacal Copper Zinc Arsenate Preservative Treated Wood Ties Their Performance in Testing and Track
2014 - IRG/WP 14-30636
While not a new preservative system, Ammoniacal Copper Zinc Arsenate (ACZA), had not previously been used to protect crossties. Its performance in treating difficult or refractory species of wood has been documented through its wide range of uses approved in AWPA. The establishment of appropriate testing for railroad material use was put in place and includes laboratory, field as well as commercia...
T Carey


Cost effective extension of service life of bridge tie (sleepers) - Effectively applying borate during Boulton conditioning and treatment with copper naphthenate
2014 - IRG/WP 14-30637
Current longevity of creosote treated wooden bridge ties in the South Eastern US is about 15 to 25 years, which is well below of the average service life of 33-50 years of railroad ties. Such short service life increases costs associated with maintenance of railroads including bridge down time for tie replacement as well as the cost for the new ties themselves. Because of this, many railroads are...
J D Lloyd, T Chambers, J-W Kim


Borate Redistribution in Glulam in an Above Ground Field Test
2014 - IRG/WP 14-30652
Researchers have refocused on the use of boratesin the wood protection industry in the last two decades due to their broad spectrum effectiveness against fungi and insects, and favourable environmental characteristics. This study was designed to determine borate distribution in a limited number of samples from a large field test of composites protected by a combination of coating and borate treatm...
P I Morris, A Temiz, J Ingram


Ammoniacal zinc borate as solid wood preservative
2014 - IRG/WP 14-30659
Zinc borate, well-known for its fungicidal, insecticidal and flame resistant properties, is widely used in manufacture of lignocellulose particle board. This form of borate is the least water soluble form available providing advantages as well as disadvantages for use as a wood preservative. This form does not leach from wood under conditions of high humidity, but it is also very difficult to appl...
C Ibáñez, C Mantero, A Ibarra, M Rabinovich


Borate and Copper Naphthenate Dual Treatment of Bridge Timbers-Borate movement over time
2017 - IRG/WP 17-40795
Preservative treated wooden bridge ties in the South Eastern USA have a service life of about 15 to 20 years, which falls well below the average service life of 40 years of railroad cross ties (sleepers). It has been shown that cross tie life is significantly extended using borate dual treatment and this is now commercialized in bridge timbers using borate inserts. In previous research, it was dem...
J-W Kim, J D Lloyd


Dual Borate and Copper Naphthenate Treatment of Bridge Timbers:- Potential Performance Enhancements and Cost Savings
2017 - IRG/WP 17-40797
Dual treatment technology combining diffusible preservatives with oil borne preservatives, widely used for crossties in the USA, has now also been commercialized with bridge ties/timbers. In order to understand the implications of these changes, the historic service life of creosote treated bridge timbers in northern and southeastern USA were considered as well as field test data for both creosote...
J Lloyd, C Brischke, R Bennett, A Taylor


Boron dual-treatments for Douglas-fir utility poles: Tracking boron migration over time
2019 - IRG/WP 19-30739
The potential for using boron pressure-treatment prior to over-treatment with conventional, heavy-duty wood preservatives to limit internal decay in-service was investigated in two field tests on Douglas-fir utility poles. Pole sections were pressure-treated with disodium octaborate tetrahydrate (DOT) and then over-treated with either pentachlorophenol or copper naphthenate in oil. Alternatively, ...
J Cappellazzi, M J Konkler, J J Morrell


Economic and Alternative Preservative Research with an Overview of its Impact on the Dynamics of Wood Tie Markets and Railroads
2019 - IRG/WP 19-30751
This presentation will discuss the Railway Tie Association’s (RTA) efforts in economic research for the North American wood tie industry, along with decades-long research into improving wood preservation processes and its resulting economic impact for railroads. Ongoing research is continuing to expand the knowledge-base by comparing existing standard creosote (C) and borate-creosote (B-C) dual...
J C Gauntt


Effect of damage to polyurea coatings on metal losses from ammoniacal copper zinc arsenate treated Douglas-fir pile sections
2019 - IRG/WP 19-40867
Metal-based preservatives remain the most widely used treatments for protecting wood in soil or water contact. While these treatments are highly effective, one drawback is a tendency for small amounts of metal to migrate into the surrounding environment. The greatest risk in this regard is copper because many organisms are highly sensitive to this metal. While post treatment practices can reduce ...
M J Konkler, J J Morrell


Comparative response of Reticulitermes flavipes and Coptotermes formosanus to borate soil treatments
1991 - IRG/WP 1486
Eastern (Reticulitermes flavipes [Kollarl]) and Formosan (Coptotermes formosanus Shiraki) subterranean termite workers (Isoptera: Rhinotermitidae) were exposed to borate-treated sand in an indirect exposure tunneling assay in the laboratory. In the ten day assay period, both termite species readily penetrated sand containing 5000, 10000, or 15000 ppm (wt. of compound / wt. of sand) disodium octabo...
J K Grace


Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi ha...
D Vesentini, D J Dickinson, R J Murphy


Marine testing of selected waterborne preservatives
1987 - IRG/WP 4137
In 1978 a marine test was established at West Vancouver, B C. to determine the performance of selected waterborne preservatives. The preservatives in test were chromated-copper-arsenate (CCA-C), ammoniacal copper arsenate (ACA), a modified formulation of ACA which contained a higher copper content (modified ACA), ammoniacal copper zinc arsenate (ACZA) and ammoniacal zinc arsenate (AZA). The wood s...
J N R Ruddick


Types of decay observed in CCA-treated pine posts in horticultural situations in New Zealand
1984 - IRG/WP 1226
The few reported failures of 11-12-year-old horticultural posts in New Zealand in 1982 were caused by brown-rot. A subsequent survey of CCA-treated posts in all the major horticultural areas has revealed decay of many posts. A microscopic examination of these posts has shown decay by brown-rot, white-rot, soft-rot and bacteria. Several types of bacterial decay have been observed....
J A Drysdale, M E Hedley


An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper-chrome-arsenic preservative
1981 - IRG/WP 3150
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. We have evaluated the influence of steaming on treatability with a waterborne CCA preservative....
C R Coggins


Field Testing of Copper Carboxylate Preservatives
2003 - IRG/WP 03-30322
This paper details our ongoing experience with field testing of copper naphthenate and other copper carboxylate preservative systems. Results from field stake tests at an AWPA Hazard Zone 4 test site are presented. In general, copper carboxylates made with ‘synthetics’ yielded results equivalent to or only slightly lower than systems with straight nap acids or nap acids amended with syntheti...
H M Barnes, M G Sanders, T L Amburgey


Influence of different fixation and ageing procedures on the leaching behaviour of copper from selected wood preservatives in laboratory trials
2003 - IRG/WP 03-20264
The paper focuses on the role of different parameters, such as fixation, sample size, wood species, and leaching in internationally standardized ageing procedures for wood preservatives from Europe, Japan and the United States. The leaching protocols used were EN 84, JIS K 1571 and AWPA E11 protocols. The wood species were Scots pine, Sugi and Southern Yellow Pine respectively. Three types of com...
J Habicht, D Häntzschel, J Wittenzellner


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Third update and first report
1996 - IRG/WP 96-10174
At the 24th annual meeting of IRG in Orlando, USA, in May 1993 an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives, copper-chrome-arsenic (CCA) and copper naphthenate (Cu-Na) against the subterran...
J R J French


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