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Evaluation of a solid remedial wood preservative containing boron and fluorine
1993 - IRG/WP 93-30022
The fungicidal and termiticidal effectiveness of a new rod form of diffusible remedial wood preservative, containing disodium octaborate tetrahydrate/sodium fluoride and marketed as Polesaver Rod, was evaluated in laboratory tests against three species of basidiomycete fungi (Coniophora olivacea, Pycnoporus coccineus, Perenniporia tephropora) and two species of subterranean termites (Coptotermes a...
K J McCarthy, J W Creffield, L J Cookson, H Greaves


Effect of borate on uptake and efficacy of an anti-sapstain treatment
2005 - IRG/WP 05-30380
The potential for using borates to enhance uptake and efficacy of propiconazole-based anti-sapstain chemicals was assessed on ponderosa pine sapwood wafers. Borates had no consistent effect on either net solution absorption or propiconazole distribution in the wood. Even small amounts of borate, however, markedly improved the performance of propiconazole against fungal discoloration. These resul...
Jianju Luo, Hua Chen, J J Morrell


Preliminary evaluation of borate baits and dusts for eastern subterranean termite control
1990 - IRG/WP 1433
Borates are of potential use in the development of baiting systems for subterranean termite control. In the 15-day laboratory assays reported here, the oral toxicity of disodium octaborate tetrahydrate to Reticulitermes flavipes (Kollar) was evaluated under choice and no-choice conditions. These assays suggest a range of 2500 to 5000 ppm to be applicable in developing baits, and that concentration...
J K Grace, A Abdallay, J M Sisson


Leachability of borate-modified oriented strandboard: A comparison of zinc and calcium borate
2002 - IRG/WP 02-40232
The leachability of boron in zinc and calcium borate-modified oriented strandboard (OSB) was investigated in this study. The leaching experiments were conducted by exposing edge-sealed OSB samples under running water for 8, 24, 72, and 216 hours. The results were compared with those from the unleached controls. Boron leaching of the modified OSB occurred upon the initial water exposure, and the le...
S Lee, Q Wu


Ten year field test with a copper-borate ground line treatment for poles
1993 - IRG/WP 93-30017
A wood preservative paste consisting of borax and copper naphthenate has been tested to determine its efficiency in protecting wood from decay fungi and insects. The paste was applied to polyethylene-backed wraps that were fastened to the below-ground portions of unseasoned southern pine pole stubs. After 4 years of exposure in Mississippi, the untreated control stubs were completely deteriorated....
T L Amburgey, M H Freeman


A Preliminary Report on the Properties of Engineered Wood Composite Panels Treated with Copper Naphthenate
2005 - IRG/WP 05-40294
This paper reports on our preliminary investigation of the properties of randomly oriented strandboard which had waterborne or powdered copper naphthenate (CuN) incorporated into the board during manufacture. When compared to zinc borate-treated controls (ZnB), the mechanical properties of strandboard (MOR, MOE, work-to-maximum load, internal bond strength) were not adversely affected by treatmen...
J W Kirkpatrick, H M Barnes


Leaching results of shower test on L-joints with boric acid, bifluoride and TBTO rods
1995 - IRG/WP 95-50051
As part of the EC-project "Improvement of a local preservation process for wood products with reduced environmental impact", TNO has performed a leaching test on L-joints treated with pills with boric acid (Defence corner), bifluorides (Woodpil 55) and TBTO (Woodcap). The L-joints were exposed in an adapted shower test during 10 days, using 70 liters of water per day. The experiment is designed to...
P Esser, M J Boonstra, W L D Suitela, A J Pendlebury


Albumin borate: A new non-toxic, wide-spectrum, long-term wood preservative
1998 - IRG/WP 98-30167
Boron, widely recognized for its broad range of activity towards both fungi and insects and for its low mammalian toxicity, can not provide long term protection to treated timber due to its high leachability. Boron, in the form of boric acid, can be partially fixed to timber by the formation of an association with egg albumin, which is insolubilized by heat-induced coagulation. Chemical investiga...
M-F Thévenon, A Pizzi, J-P Haluk


Treatment of wood-based panel products with volatile borate
1990 - IRG/WP 3616
The paper presents recent developments in the use of volatile borate esters for the preservative treatment of wood based board materials. Several advances on previous reports are discussed. In laboratory studies, treatment times of approximately ten minutes at 20°C on boards at equilibrium moisture content provided full penetration and retentions of 1% wt/wt boric acid. Biological tests have been...
P Turner, R J Murphy, D J Dickinson


The efficacy of remedial treatments for controlling fungal decay in window millwork used in the United States
1987 - IRG/WP 3432
Conventional window millwork was subjected to basidiomycete decay by inoculation and sampled for active growth of the decay fungus before and eight months after remedial preservative treatment with fused disodium octaborate rods (IMPEL) at boric acid levels of 1.5 and 4.0 kg/m³ or liquid bifluoride injections (IMPROSOL) at 1 kg/m³. The elimination of decay fungus after remedial treatment was nea...
M G Dietz, E L Schmidt


Preservative treatments of window components with a water-based borate formulation
2000 - IRG/WP 00-40171
Factory finished window joinery components were treated with an aqueous borate preservative in order to investigate penetration and retention levels, associated drying times; and the potential impact of using a water-based treatment on finished items. It was found that by using borates applied by light double vacuum schedules, it was possible to meet standards for penetration and retention, to air...
J Jermer, J D Lloyd


Wood protection by surface treatment of two borate preservatives, TIM-BOR® and BORA-CARE®, for the formosan subterranean termite and eastern subterrean termite
1993 - IRG/WP 93-10044
TIM-BOR® (disodium octaborate tetrahydrate: DOT, Na2B8O134H2O) and BORA-CARE® (40% DOT in ethylene glycol) are two borate products marketed for treating wood in use by brushing or spraying onto the wood surface. The active ingredients presumably diffuse into wood by the 10-15% existing wood moisture. Few data, however, are available to demonstrate the diffusion rate. Su & Scheffrahn (1991) s...
M Toroko, N-Y Su


Laboratory evaluation of borate formulations as wood preservatves to control the subterranean termite coptotermes acinaciformis (isoptera: Rhinotermitidae) in Australia
2001 - IRG/WP 01-30266
The termiticidal efficacy of Borocol (sodium octaborate tetrahydrate), boric acid, bore-ester-7 and tri- methyl borate was evaluated in laboratory bioassays against Coptotermes acinaciformis (Froggatt). Seasoned sapwood blocks of Pinus radiata D. Don, and Eucalyptus regnans (F. Muell) were impregnated with the various borate compounds. There were marked differences in mass loss and mortality rate ...
B M Ahmed, J R J French, P Vinden


Decay and mold resistance of borate modified oriented strandboard
2003 - IRG/WP 03-40260
Decay and mold resistance of zinc borate (ZB) and calcium borate (CB) modified oriented strandboard (OSB) from southern mixed hardwoods and yellow pine was investigated in this study. Tests were done with brown rot, Gloeophyllum trabeum, and white-rot, Trametes versicolar, fungi for 8 and 12 weeks, respectively. Wood species and fungus type had significant influence on the decay resistance. Decay...
Q Wu, S Lee, J P Jones


Durability of Wood Plastic Composites Relative to Natural Weathering and Preservative Treatment With Zinc Borate
2005 - IRG/WP 05-40316
Wood-Plastic Composites (WPCs) used for decking have experienced dramatic increases in North America, averaging 25% growth per annum since 1998. A key factor contributing to this growth has been the successfully communicated message that they are "virtually maintenance free". The common perception being that the wood fiber is completely encapsulated by the thermoplastic resin, minimizing the pot...
M E Mankowski, F M Ascherl, M J Manning


Evaluating the natural durability of native and tropical wood species against Reticulitermes flavip
2004 - IRG/WP 04-10539
Environmental pressures to eliminate arsenate from wood preservatives has resulted in voluntary removal of CCA for residential applications in the United States. A new generation of copper organic preservatives has been formulated to replace CCA for decking and in-ground applications but there is no guarantee that these preservatives represent a permanent solution to all related problems. There...
R A Arango, F Green III, K Hintz, R B Miller


A suggestion for the improvement of the chemical protection of wooden poles
1987 - IRG/WP 3445
Insufficient drying of white poles in Sweden causes inadequate penetration of the impregnation compounds, CCA salts and creosote, in a varying proportion of the treated poles, and with pretreatment decay present, sooner or later, internal fungal attack in the ground-line zone of the standing poles is the result. The application of a diffusing fungicide in the ground-line zone in connection with th...
H Friis-Hansen


Performance of boron and fluoride based rods as remedial treatments in Douglas-fir poles
1995 - IRG/WP 95-30070
Boron and fluoride are widely used for remedial internal treatments, but their use in North America has been limited. Recently, however, interest in these chemicals has increased as the result of concerns about the risks of fumigant usage. The performance of boron or a boron/fluoride combination was assessed in Douglas-fir poles over 1 to 3 year periods. Both chemical formulations diffused well th...
J J Morrell, P F Schneider


The effect of different concentrations of polesaver rods on the survival of selected decay fungi in liquid culture
1998 - IRG/WP 98-30166
An in-vitro method was developed to determine the effect of solutions of Polesaver Rods on the survival of selected decay fungi. Polesaver Rods are a diffusing preservative treatment containing fluorine and boron designed for the internal remedial treatment of power poles. Two white-rot fungi, Perenniporia tephropora and Trametes versicolor, and two brown-rot fungi, Polyporus verecundus and Gloeo...
M A Powell, T Deldot, C McEvoy


Long-term efficacy of wood dip-treated with multicomponent biocides
2005 - IRG/WP 05-30379
Biocides designed for prevention of indoor mold growth on wood-based materials need to provide long-term protection under conditions of high humidity. Specimens of kiln-dried southern pine and unseasoned southern pine, aspen, and Douglas-fir were dip-treated with borate-dimethylcocoamine (DMCA) supplemented with voriconazole, thiabendazole, or thujaplicin and evaluated at 4-week intervals for inhi...
C A Clausen, V W Yang


Comparison of the effects of borate, germanate and tellurate on fungal growth and wood decay
1992 - IRG/WP 92-1533
The tetra-hydroxy borate ion is known to undergo complexation with polyols and has been shown to inhibit dehydrogenase enzymes in this way. It has been previously suggested that this complexation is responsible for the inhibition of fungal growth and the protection of boron treated timber. Other ions that have the ability to complex with polyols have also been shown to inhibit dehydrogenase activi...
J D Lloyd, D J Dickinson


Chemical evaluation of borate treated pine sapwood attacked by the subterranean termite Coptotermes acinaciformis
1993 - IRG/WP 93-20003
Sapwood of hoop (Araucaria cunninghamii Ait. ex D. Don) and slash (Pinus elliottii Englem.) pines were treated by Vacuum Pressure Impregnation (VPI) to provide test specimens. The concentration of boron was defined by chemical analyses of the timber, in the zone of primary attack by the termite being bioassayed. A common method of definition of preservative retention, weight uptake of preservative...
A R Moffat, B C Peters


Remedial ground-line treatment of CCA poles in service. A final report after 60 months' testing
1989 - IRG/WP 3534
Remedial treatment of CCA treated utility poles of Pinus sylvestris with incipient decay was carried out in 1983 and the results of chemical and microbiological analyses 6 months after treatment were reported in Document No: IRG/WP/3388 while microbiological studies 12 and 28 months after treatment as well as chemical analyses of poles treated with boron rods or boric acid paste 28 months after tr...
B Henningsson, H Friis-Hansen, A Käärik, M-L Edlund


Field performance of novel antisapstain formulations
1997 - IRG/WP 97-30125
The effectiveness as antisapstain formulations of combinations of oxine copper (Cu-8), carbendazim, hexaconazole, cyproconazole, flusilazole, didecyldimethyl ammonium chloride (DDAC), an alkanolamine borate (SB), benzalkonium chloride (BAC), 2-n-octylisothiazolin -3-one (isothiazoline) and p-chlorophenyl-3-iodopropagilformal (CPIPF) was determined for freshly sawn, block-stacked radiata pine in th...
D R Eden, R N Wakeling, C M Chittenden, J G Van der Waals


The effect of glycol additives on diffusion of boron through Douglas-fir
2000 - IRG/WP 00-30235
Boron is highly effective against a variety of fungi and insects and is able to diffuse with moisture through wood. Diffusion decreases sharply at lower moisture contents, a characteristic that limits the potential use of this material as a remedial treatment for arresting internal decay. One approach to improvi ng boron diffusion is the simultaneous addition of glycol, which is presumed to enhanc...
C M Freitag, R Rhatigan, J J Morrell


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