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The formation of organotin carboxylates in bis(tributyltin) oxide - treated Pinus sylvestris sapwood
1990 - IRG/WP 3618
Tributyltin compounds have been successfully used for many years as wood preservatives, although their chemical nature in timber have not been fully elucidated. This study by 119Sn and 13C NMR spectroscopy has shown that, on impregnation into Pinus sylvestris sapwood, bis(tributyltin) oxide, (Bu3Sn)2O, is rapidly converted to tributyltin carboxylates, Bu3SnOCO·R, via reaction with components of t...
S J Blunden, R Hill


Measurement of VOC emissions from curative treated wood: A new emission test chamber
2001 - IRG/WP 01-50166-13
A poor indoor air quality (IAQ) is now recognized as a potential factor affecting occupants health. There are three basic strategies to improve IAQ: source control, improvement of the ventilation and use of air cleaners. Usually, the most efficient way to improve IAQ is to eliminate the different pollutant sources or to reduce their emissions. In order to precisely measure emissions from building ...
F Maupetit, O Ramalho, C Yrieix


Budget for 2013 (forecast June 3103)
2013 - IRG/WP 13-60345
IRG Secretariat


Budget for 2014
2013 - IRG/WP 13-60346
IRG Secretariat


Reporting minutes of the Plenary Meeting 2013
2013 - IRG/WP 13-60355
IRG Secretariat


IRGWP Strategy development 2012-2013
2013 - IRG/WP 13-60356
J Norton


Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens


The effect of selective additives and conditions on the decomposition of Basamid in Douglas fir heartwood
1992 - IRG/WP 92-3698
Basamid is a solid, powdered chemical used as an agricultural soil fumigant. Decomposition of Basamid isothiocyanate, hydrogen sulfide, methyl amine, and formaldehyde. Basamid has some potential as a wood fumigant, but it decomposes too slowly to be effective. Various additives and conditions were tested for their ability to enhance Basamid decomposition in Douglas-fir heartwood. Higher MC&apo...
P G Forsyth, J J Morrell


The distribution of introduced acetyl groups and a linseed oil model substance in wood examined by microautoradiography and ESEM
2000 - IRG/WP 00-40169
Microautoradiography, a photographic method that shows the localization of substances labelled with radioactive isotope, and Environmental Scanning Electron Microscopy (ESEM) were combined to enhance sensitivity, resolution and reliability for examination of the distribution of introduced substances in wood. The preparation of microautoradiographs is less complicated when investigated with ESEM an...
M Rosenqvist


Distribution of cellulases in the body of Coptotermes formosanus and the probability that the termite uses glucose as an energy and carbon sources
1997 - IRG/WP 97-10202
We assayed extracts of the digestive system and of the whole body of Coptotermes formosanus to determine where the various cellulases, glucose, and related substances were concentrated and to detect pyruvate dehydrogenase activity in the hindgut-removed body in order to verify its full cellulolytic system. About 20%, 18% and 36% of the total exo-1,4-ß-glucanase activity of C. formosanus were dete...
S Itakura, H Tanaka, A Enoki


Bending properties of TCMTB-treated Southern pine sapwood using supercritical carbon dioxide impregnation process
1997 - IRG/WP 97-40080
The effects of elevated pressure and treatment with thiocyanomethylthiobenzothiazole (TCMTB) on the bending properties of Southern pine sapwood were evaluated at pressures ranging from 1,800 to 3,600 psi. All bending properties were affected to some extent by supercritical fluid treatment. Modulus of elasticity and work to maximum load were not significantly affected by pressure levels. Modulus of...
Gyu-Hyeok Kim, S Kumar, E S Demessie, K L Levien, J J Morrell


The chemical nature of bis(tributyltin) oxide in Pinus sylvestris sapwood
1989 - IRG/WP 3508
Tributyltin compounds have been used for many years as wood preservatives. This study has provided, for the first time, an explanation for the previously reported dealkylation and/or volatilisation of the tributyltin species in, and from, Scots pine (Pinus sylvestris) sapwood. Thus, 119 Sn nuclear magnetic resonance studies have shown that, on impregnation into this timber, bis(tributyltin) oxide ...
S J Blunden, R Hill


Wood extractives as carbon sources for staining fungi in the sapwood of lodgepole pine and trembling aspen
1995 - IRG/WP 95-10098
Wood discoloration by sapstaining fungi reduces lumber value. In Canada, the most commonly recorded sapstaining fungi belong to the genera Ophiostoma. This work evaluated the effect that Ophiostoma piceae, Ophiostoma ainoae, and Ophiostoma piliferum used the lipids present in the sapwood of lodgepole pine (Pinus contorta Dougl.) and trembling aspen (Populus tremuloides Michx.). Wood lipids, common...
Yong Gao, C Breuil


Distinguishing isolates of Aureobasidium on the basis of their ability to utilise lignin breakdown products as a sole carbon source
1996 - IRG/WP 96-10151
Wild isolates of Aureobasidium were obtained by dilution plating from a ca 20 year old painted pine window frame. Four isolates were obtained from the paint/wood interface region and four isolated from regions deep in the wood. The isolates were then used to inoculate liquid cultures containing ferulic acid, a lignin breakdown product, present as the sole carbon source. Ability of the isolates to ...
M W Schoeman, D J Dickinson


Accelerated laboratory testing of preservatives on 13 North American wood species
1999 - IRG/WP 99-30201
The ability of selected water and solvent based biocides to protect wood against fungal attack was evaluated on 13 North American wood species using 7 decay fungi in a modified soil block test. Most preservatives were capable of providing protection at their recommended above ground and soil contact use levels. Many decay fungi caused substantial weight losses on blocks treated with chlorothalonil...
J J Morrell, C M Freitag


Analysis of D-glucose metabolism of wood decay fungi using 13C-NMR and 13C-labeled substrates
2003 - IRG/WP 03-10475
D-Glucose metabolism is thought to be important during wood decay by fungi, not only for anabolic and catabolic purposes of central metabolism, but also as a potential source of peroxide required by extracellular peroxidases. There has been some confusion in the literature as to whether this peroxide-generating activity is of the glucose 1-oxidase or pyranose 2-oxidase (glucose 2-oxidase) type wi...
T H de Koker, M D Mozuch, P J Kersten


Termite Field Tests of Various Timber Species Treated with permethrin using supercritical carbon dioxide
2005 - IRG/WP 05-10560
Termite field tests were conducted on permethrin-treated Eucalyptus obliqua heartwood, Pinus radiata sapwood and P. radiata LVL. The permethrin was impregnated using either supercritical carbon dioxide (scCO2) or light organic solvent preservative (LOSP) systems. Comparative permethrin retentions were most accurately achieved in P. radiata sapwood, where no difference between impregnation systems ...
A Qader, L J Cookson, J W Creffield, D Scown


Utilization of nitrogenous substance by Serpula lacrymans
1989 - IRG/WP 1397
When Serpula lacrymans degrades wood, the fungus is considered to have to assimilate nitrogen, which is not abundant in the wood, from the third material. The strands/mycelium has grown into the soil under the floor of the wooden house damaged by the dry rot fungus. The authors analyzed the soil samples collected from the ground under the floors of the dryrotted houses. The samples which were coll...
S Doi, I Togashi


Cellular and fractural failure after supercritical fluid impregnation of four wood species
2004 - IRG/WP 04-10503
Supercritical fluids (SCFs) have been investigated for delivering biocides into sawn wood. Pressure differentials during treatment may exceed the compressive or tensile strength perpendicular to grain, creating a potential for transverse deformations that exceed elastic strain limits. Wood treated by SCF processing with CO2, a potential biocide carrier, was inspected macroscopically and microscopi...
M E Anderson, R J Leichti, J J Morrell


Remediation of a large CCA-impregnation plant
1998 - IRG/WP 98-50101-13
During 1949-85 the Swedish Telecom ran a plant for pressure impregnation of poles in Hjältevad, 80 km east of Jönköping in the southern part of Sweden. About one million poles were treated with CCA-preservaties. Leaks and accidential spills have contaminated soil and groundwater within the 5 ha large site. The total amount of released arsenic, the main pollutant, is estimated to 6-7 metric tons...
P Englöv


Applicability of supercritical carbon dioxide to the preservative treatment of wood-based composites
2001 - IRG/WP 01-40199
Treatability of five structural-use wood-based composites (medium density fiberboard, hardwood plywood, softwood plywood, particleboard and oriented strand board) was evaluated when supercritical (SC) carbon dioxide (CO2) was used as a carrier solvent. Treatments were conducted at three temperature 32 levels (25, 35 and 45°C) and two pressure levels [80 kgf/cm2 (7,845 kPa) and 120 kgf/cm2 (11,768...
M Muin, A Adachi, K Tsunoda


Solid state NMR study on pine wood degraded by brown rot fungus Gloeophyllum trabeum
1994 - IRG/WP 94-10067
Blocks of Pinus koraiensis wood were degraded by Gloeophyllum trabeum and examined by solid-state 13C NMR spectroscopy. Chemical compositions were estimated from relative signal aras. There was no evidence for preferential degradation of the noncrystalline cellulose which accounted for about 4% by weight of the wood. Loss of partly ordered cellulose on crystal surfaces exceeded the loss of crystal...
Yoon Soo Kim, R Newman


Preservative treatment of wood-based composites with a mixture formulation of IPBC-silafluofen using supercritical carbon dioxide as a carrier gas
2003 - IRG/WP 03-40251
Wood-based composites treated with a mixture formulation of a fungicide, 3-iodo-2-propynyl butylcarbamate (IPBC) and a termiticide, silafluofen using supercritical carbon dioxide (SC-CO2) as a carrier solvent were tested for their resistance to decay and termite attack in the laboratory. The treatment solution was prepared by mixing both biocides (IPBC 10 + silafluofen 1) with a co-solvent, ethano...
K Tsunoda, M Muin


NMR T1 relaxation time as a non-destructive method for the study of decay in wood
1992 - IRG/WP 92-2406
The NMR spectroscopic technique of measuring the T1 spin-lattice relaxation times has been investigated for its potential in the detection of microbial decay in wood. The T1 NMR analyses were carried out on samples of Scots pine and European beech that had been exposed to decay and non-decay fungi representing each of the important groups colonising wood. Decay in the test material was also assess...
P W McCormack, A E G Cass, R J Murphy


Extracellular mucilage (ECM) in wood decay basidiomycetes
2002 - IRG/WP 02-10439
The ability of wood decay basidiomycetes to produce extracellular mucilage (ECM) and its relationship with total biomass production is being investigated. Growth and ECM production by the brown-rot fungus Gloeophyllum trabeum (FPRL 108 N) and the white-rot fungus Coriolus versicolor (CTB 863 A) was assessed in liquid culture under different conditions and in the presence of the fungicide cyprocona...
D Vesentini, D J Dickinson, R J Murphy


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