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Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi ha...
D Vesentini, D J Dickinson, R J Murphy


Influence of different fixation and ageing procedures on the leaching behaviour of copper from selected wood preservatives in laboratory trials
2003 - IRG/WP 03-20264
The paper focuses on the role of different parameters, such as fixation, sample size, wood species, and leaching in internationally standardized ageing procedures for wood preservatives from Europe, Japan and the United States. The leaching protocols used were EN 84, JIS K 1571 and AWPA E11 protocols. The wood species were Scots pine, Sugi and Southern Yellow Pine respectively. Three types of com...
J Habicht, D Häntzschel, J Wittenzellner


Performance of treated fence posts after 6 years in five test plots in the State of Sao Paulo - Brazil
1976 - IRG/WP 376
Fence posts treated with creosote, pentachlorophenol and creosote/ pentachlorophenol mixtures showed good performance after 6 years of exposure in five test plots located in the State of Sao Paulo - Brazil. Good results were also achieved with copper sulphate/sodium arsenate and copper sulphate/potassium dichromate mixtures. Fungi and termites were the main destroying agents found attacking the po...
M S Cavalcante


Pinus and Eucalyptus fenceposts treated with creosote and solvex tar by hot and cold open-tank process
1987 - IRG/WP 3455
A comparative study of the behaviour of two different wood preservatives, creosote and solvex-tar, was made, using two wood species, Pinus pinaster Ait and Eucalyptus globulus Labill, by the hot and cold open-tank process. Results showed that the creosote behaved better in relation with the uniformity of its distribution in wood. On the other hand, better results were obtained on Pinus for both pr...
M V Baonza Merino


Fire resistance of preservative treated fence posts
1994 - IRG/WP 94-30033
Pine fence posts were pressure treated separately with CCA-C, CCA-wax, CCA-oil and creosote. Treated posts and untreated controls were planted in the ground in a randomised block design, weathered for six months and then subjected to a controlled burning test using two fuel loads. Creosote treatment increased the time that posts were alight whereas CCA treatment had no such effect. However, CCA tr...
P D Evans, P J Beutel, C F Donnelly, R B Cunningham


Evaluation of new creosote formulations after extended exposures in fungal cellar tests and field plot tests
2000 - IRG/WP 00-30228
Although creosote, or coal tar creosote, has been the choice of preservative treatment for the railroad industry since the 1920s, exuding or "bleeding" on the surface of creosote-treated products has been one incentive for further enhancements in creosote production and utility (Crawford et al., 2000). To minimize this exuding problem, laboratories such as Koppers Industries Inc., USA, and Commonw...
D M Crawford, P K Lebow, R C De Groot


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Third update and first report
1996 - IRG/WP 96-10174
At the 24th annual meeting of IRG in Orlando, USA, in May 1993 an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives, copper-chrome-arsenic (CCA) and copper naphthenate (Cu-Na) against the subterran...
J R J French


Types of decay observed in CCA-treated pine posts in horticultural situations in New Zealand
1984 - IRG/WP 1226
The few reported failures of 11-12-year-old horticultural posts in New Zealand in 1982 were caused by brown-rot. A subsequent survey of CCA-treated posts in all the major horticultural areas has revealed decay of many posts. A microscopic examination of these posts has shown decay by brown-rot, white-rot, soft-rot and bacteria. Several types of bacterial decay have been observed....
J A Drysdale, M E Hedley


A case study on quality control on telephone poles as a cost saving tool in Tanzania
1987 - IRG/WP 3418
A sample of 28 CCA treated Eucalyptus poles from a lot of 2,000 poles awaiting delivery to the field, was studied to reveal the quality of treatment. Results showed a product of very poor quality. Average figures for penetration and retention were 8.4 mm and 2.2 kg/m³; these results are 66% and 91% below the required standards, respectively. Consequences of such results are estimated to amount to...
K K Murira


Results of chemical analyses in the field of wood preservation in the Bundesanstalt für Materialprüfung
1973 - IRG/WP 321
The results of qualitative and quantitative chemical analyses of wood preservatives are often the basis for evaluating the various works in the field of wood preservation. In the past 10 to 15 years a number of such works was carried out in the Bundesanstalt fur Materialprüfung, Berlin-Dahlem, dealing with the identification and effectiveness of wood preservatives and with methods of wood preserv...
H J Petrowitz


Fungicidal activity of some organic solvents, copper carboxylates and their complexes with 2-aminoethanol
1997 - IRG/WP 97-30136
We evaluated the activity of eight organic solvents against wood - rotting fungus Trametes versicolor in order to choose the most appropriate one for rapid screening tests of some copper(II) carboxylates and their adducts with 2-aminoethanol. Their activity against the selected fungus was classified in the following order: chloroform > N,N-dimethylformamide > acetonitrile > methanol > ...
M Petric, F Pohleven


Possible regulatory status of treated wood waste and implications
1998 - IRG/WP 98-50101-07
In relation to the European Community or the French regulations, treated wood waste can get two different regulatory status: <<recycled product or fuel>> or <<waste>>. Then, into the waste status, two categories are possible for these residues: <<domestic waste and assimilated>> or <<hazardous waste>>. These different status and categories are import...
G Deroubaix


Results of stake tests on wood preservatives (Progress report to 1974)
1975 - IRG/WP 361
A number of field stake trials on preservative-treated wood have been carried out at Princes Risborough Laboratory from 1928 to the present day, and many of the tests still continue. This paper presents in detail the results obtained to date, covering about 15 000 individual test stakes exposed over the period....
D F Purslow


Extending the useful life of creosoted electricity distribution poles in service
1993 - IRG/WP 93-50001-16
Creosoted transmission poles have provided good service over many decades in a whole range of environments. The use of save biocides for secondary treatments has the potential to extend the life of such poles. These techniques, together with a full understanding of the modes of failure, make it possible to establish new strategies to further improve the environmental benefits of treated wooden pol...
D J Dickinson, B Calver


Termite resistance of pine wood treated with chromated copper arsenates
1997 - IRG/WP 97-30128
Two four-week, no-choice laboratory tests were performed with CCA-treated southern yellow pine and radiata pine against Formosan subterranean termites, Coptotermes formosanus. CCA retentions as low as 0.05 kg/m3 (0.03 pcf) provided protection from all but light termite attack (rating of 9 on a 10-point visual scale). Similar and consistent light attack on wafers containing retentions as high as 6....
J K Grace


Problems of fixation of CCA-preservatives in palm-wood
1985 - IRG/WP 3338
Palm-wood may be used for posts and poles where it needs proper treatment for long time use. Based on observations by W. Killmann on low CCA-fixation in palm-wood, samples of Jubaea-palm grown in a Greenhouse at Hamburg, have been treated in two different series with a 4% solution of CCA-type B. After 1-16 weeks of storage the blocks were split into sticks of 1-2 mm² and leached. In all series 50...
H Willeitner, K Brandt


A new concept of oxalic acid biosynthesis in physiology of copper-tolerant brown-rot fungi
2001 - IRG/WP 01-10394
Recently, a wide variety of roles of oxalic acid (oxalate) in wood decay systems have been receiving much attention. Copper tolerance of wood-rotting basidiomycetes has been believed to be due to the detoxification of copper wood preservatives by oxalate produced by these fungi. However, biochemical mechanism of oxalate biosynthesis in relation to physiology of wood-rotting fungi has not been eluc...
E Munir, T Hattori, M Shimada


Copper naphthenate performance: A new way to look at old data
2000 - IRG/WP 00-30215
Although copper naphthenate has over a 50-year test history, it is still considered as a "new" preservative in the United States when it is used for utility poles. It has also been extensively used in remedial treatments for poles and has considerable retail or over-the-counter sales. The test history includes a number of different tests and a rationale for evaluating this data and comparing the p...
C R McIntyre


An investigation of the effects of pre-steaming on the treatment of sawn spruce timber with Celcure A, a copper-chrome-arsenic preservative
1981 - IRG/WP 3150
Difficulties in the treatment of spruce using standard vacuum/pressure techniques with both water-borne and organic solvent preservatives are well known. We have evaluated the influence of steaming on treatability with a waterborne CCA preservative....
C R Coggins


Field Testing of Copper Carboxylate Preservatives
2003 - IRG/WP 03-30322
This paper details our ongoing experience with field testing of copper naphthenate and other copper carboxylate preservative systems. Results from field stake tests at an AWPA Hazard Zone 4 test site are presented. In general, copper carboxylates made with ‘synthetics’ yielded results equivalent to or only slightly lower than systems with straight nap acids or nap acids amended with syntheti...
H M Barnes, M G Sanders, T L Amburgey


Creosoted radiata pine by non-pressure methods
1988 - IRG/WP 3486
Posts of Pinus radiata have been impregnated with creosote by immersion for 1, 3, and 7 days, and by hot-and-cold open tank with hot bath temperatures at 40°C and 60°C. On the basis of the retention rates obtained, suitable procedures are described for wood elements that are going to be in ground contact, and an analysis is made of the way in which the variables tested affect the results....
M V Baonza Merino, C De Arana Moncada


The leaching of copper, chrome and arsenate from CCA-impregnated poles stored for ten years in running water
1978 - IRG/WP 3122
There is no evidence to indicate that the chromium and copper components are leached from the outermost 5 mm of sapwood in poles impregnated with Boliden K33 and Tanalith C and stored in running water for ten years. The arsenic component, however, seems to be leached out during the first few months to an extent of about 20% of the initial amount. The leaching time is dependent on the preservative ...
F G Evans


Inspection results of preservative treated stakes, maximum 33 years in field
1992 - IRG/WP 92-3690
Since in 1958, we have undertaken field experiments in Japan. For these field experiments, we used sapwoods of Japanese cedar called Sugi (Cryptomeria japonica) because of majority of plantation forest soft wood species in Japan. For some preservatives, we added sapwood of Japanese beech called Buna (Fagus crenata), a main Japanese hard wood species. Dimensions of these specimens were 30 x 30 x 60...
K Suzuki, K Yamamoto, M Inoue, S Matsuoka


The biostatic effect of copper on decay of fire retardant-treated mining timber
1991 - IRG/WP 1507
Blocks of Eucalyptus grandis were treated with 20kg/m³ ammonium sulphate as fire retardant and challenged with Coriolus versicolor. Replicates were soil buried. A second set of blocks was treated with retardant and copper at 6.6 kg/m³ (ie 1% w/w), and challenged similarly. After 8 weeks weight losses produced by Coriolus versicolor in untreated, retardant treated and copper supplemented blocks w...
G D Shelver, E A Shelver, A A W Baecker


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