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Screening of the technical performance and aquatic toxicity of N-methylolacrylamide treated wood
2000 - IRG/WP 00-40166
In the course of the last decades chemical modification of wood species, with a limited natural durability, has been subjected to intensive research. As a possible alternative and supplementary treatment of non-durable wood in a range of applications it remains one of the major topics in the wood preservation world. Different modification systems have been scaled-up and are now in an industrialisi...
V Rijckaert, S De Geyter, J Van Acker, M Stevens


Effect of fungal degradation on the chemical composition of acetylated beech wood
2003 - IRG/WP 03-40267
This study investigated the impact of fungal attack on the chemical composition of acetylated wood. Beech wood acetylated to different degrees was exposed to decay by the white-rot fungus Trametes versicolor under solid-state fermentation conditions. Laboratory soil-bed assays were also conducted to study the degradation of acetylated wood by soft rot fungi and other soil-inhabiting microorganisms...
H Militz, Dong-won Son, L Gómez-Hernández, R Sierra-Alvarez


The effects of chemical modification on the biological properties of alder and spruce particleboards
2007 - IRG/WP 07-40363
This study is evaluated by measuring the weight loss, and the ability of white and brown-rot fungi to attack unmodified and modified particleboards manufactured using spruce (Picea orientalis (L.) Link.) and alder (Alnus glutinosa) chips. The chips were reacted with acetic, succinic, maleic and phthalic anhydride at constant temperature for 3 hours then, hot pressed at 150 °C by using phenol for...
Ü C Yildiz, E Dizman, S Yildiz, A Temiz, M Aslan, E D Gezer


Chemical modification of Scots Pine Sawdust by mixed anhydrides
2008 - IRG/WP 08-40439
By making react mixtures containing acetic-fatty anhydrides on Scots pine sawdust (SPS) without any solvent or catalyst; we synthesized mixed acetic-fatty esters of SPS. Such mixtures were synthesized by reaction between a carboxylic acid and acetic anhydride. These mixtures were obtained after reaction of acetic anhydride and a fatty acid that yields at equilibrium a mixture of five compounds: ac...
J Peydecastaing, E Borredon, S El Kasmi


Effect of different ASAs (alkenyl succinic anhydrides) on the treatment of biological protection of wood in use class 4
2008 - IRG/WP 08-40440
The alkenyl suscinic anhydrides (ASAs) used in this work are adducts resulting from the maleinization reaction of fatty acid alkyl esters. Various products with different alkyl groups were synthesized from rapeseed (Brassica napus) oil esters, rich in oleic acid. The liquids obtained showed a viscosity similar to that of vegetable oils and a brown color. When applied into wood, a thermal treatment...
C Vaca-Garcia, O Pignolet


Modification of Wood by a Water-Repellent Compound Used in the Textile Industry: Boron Release and Termite Resistance
2009 - IRG/WP 09-40447
In the study, wood specimens were treated with disodium octoborate tetrahydrate (DOT) and a commercial water and oil repellent compound, FORGUARD M®, a weak cationic emulsion containing dipropylene glycol monomethylether, water and solids in its formulation and used in the textile industry. There were two different processes for preservative treatments: double and single treatments. The leaching ...
S N Kartal, E Terzi, B Erilkun, Y Imamura


Multilayer hot-press drying and chemical modifying of poplar wood with urea-formaldehyde prepolymer
2011 - IRG/WP 10-40539
The objective of this study was to determine the technology of chemical modifying and multilayer hot-press drying on poplar wood. The chemicals were impregnated into cell lumen space by pulse-dipping machine to improve the dimension stability and mechanical property of timber. The timbers were compressed and dried by the multilayer hot-press drying to increase the density of timber. Results indica...
Guofeng Wu, Yifei Jiang, Sheng Yao, Junwen


Study of UV resistance and natural weathering of coatings on chemically modified wood
2013 - IRG/WP 13-40629
In this study, UV resistance and weathering performance of rubberwood (Hevea brasiliensis) and radiata pine (Pinus radiata) modified with benzoyl chloride and acetic anhydride was studied. Performance of polyurethane based wood coatings on modified wood was also evaluated. Unmodified and chemically modified specimens were exposed to accelerated and natural weathering. Modified and unmodified woo...
K K Pandey, K Srinivas


Characterization of wood modification prepared by in situ polymerization with pre-polymer and the mechanism of modification
2013 - IRG/WP 13-40633
Chemical modification of wood is a potential way to obtain high quality wood. In this study, the fast-growing poplar was impregnated with modifier using a pulse-dipping machine by in situ polymerization. Fungal decay analysis, mechanical properties and dimension stability of the natural and modified woods were investigated. The wood samples were also characterized by X-ray diffraction (XRD) Therma...
Qian Lang, Zeng Bi, Junwen Pu


Optimising wood chemical modification with lactic acid oligomers by screening of processing conditions and chemical additives
2016 - IRG/WP 16-40741
Oligomer systems based on lactic acid (OLA), were impregnated in wood and polymerised in-situ by heat treatment to improve the properties of the treated wood especially regarding anti-swelling efficiency (ASE), hygroscopicity, water leaching resistance and durability. This article relates the optimisation of the heat treatment conditions and the consideration of selected chemicals for improvement ...
C Grosse, M-F Thévenon, M Noël, P Gérardin


Chemical, physical-mechanical characterization and durability of thermally modified beech and ash wood by thermo-vacuum process (Termovuoto)
2016 - IRG/WP 16-40758
The paper illustrates part of the results from the CIP Eco-innovation project “Thermo-vacuum: new process for new generation of thermally modified wood”. The project is part of the 7th Framework Programme for European Research and Technological Development, and thermo-vacuum modified wood is already on the European market. The project was selected by the European Commission, EASME Agency, as "...
M Jebrane, I Cuccui, O Allegretti, N Terziev


Accelerated weathering and fungal resistance of wood modified with isopropenyl acetate
2016 - IRG/WP 16-40764
Chemical modification of Rubberwood (Heveabrasiliensis Müll.Arg) with isopropenyl acetate (IPA) in presence of anhydrous aluminum chloride and iodine as catalysts was carried out. Modified wood surfaces were exposed to UV light source in an accelerated weathering tester to evaluate UV resistance. Anti-swelling efficiency (ASE) and fungal resistance of modified wood were also evaluated. Modified w...
G B Nagarajappa, K K Pandey


Overview of the treated wood quality control program in the United States with the recent challenges and advances
2017 - IRG/WP 17-20616
In the past two decades, there have been significant and rapid changes in wood protection technologies for residential applications which have moved away from long established heavy duty metal oxide based products such as chromated copper arsenate (CCA). The successor generation of wood protection systems usually contain copper as the primary biocide, in combination with carbon-based co-biocides s...
L Jin


Dimensional Stability of Melamine Formaldehyde-Treated Southern Pine
2017 - IRG/WP 17-40774
The objective of this preliminary study was to evaluate the influence of different levels of melamine formaldehyde (MF) and curing cycle on the dimensional properties of southern pine. Thirty samples for each combination of treatment and curing regimen plus untreated controls and controls subjected to the same curing regimen were tested. Shrinkage/swelling coefficients showed that up to 60% ASE c...
H M Barnes, L S Sites, T S F A França, M G Sanders, F J N França


Accessibility of hydroxyl groups in anhydride modified wood as measured by deuterium exchange
2017 - IRG/WP 17-40784
Acetylated wood shows improved properties largely due to the reduced amount of water in the acetylated cell wall. However, the exact mechanism by which water is excluded in acetylated wood remains unclear. Acetylation reduces hydroxyl content by substitution of hydroxyl groups in wood polymers but may also hinder access to unmodified hydroxyls by physical bulking. This work assesses hydroxyl acces...
G Beck, S Strohbusch, E Larnøy, H Militz, C Hill


Influence of hygro-thermal treatment temperature and duration on dimensional stabilisation of wood modified with poly(butylene succinate)
2017 - IRG/WP 17-40813
To improve wood properties, especially dimensional stability, a treatment based on poly(butylene succinate) oligomers (OBS) was experimented. After impregnation in wood, a further hygro-thermal treatment (HTT) was carried out in a pressurized reactor at 100% relative humidity (RH) at differing temperatures for differing durations. The aim of HTT is to induce partial swelling of wood cell walls so ...
C Grosse, M Noël, L Rautkari, P Gérardin


Understanding of the effect of ancestral and natural saltwater treatment on durability, fibers densification and chemical modification of palm wood
2018 - IRG/WP 18-10921
The palm-tree sector plays a very important role on both the socioeconomic and ecological levels, in Tunisia. There are three million trees in Tunisian palm plantations, ensuring a potential significant wood production, mainly in the craft and furniture industries. In the past, Date Palm wood (Phoenix dactylifera L.,) was also used as structural material. Its low natural durability and its low m...
M T Elaieb, A Namsi, M Tella, M-F Thévenon, K Chandelier


FTIR-ATR monitoring of chemical changes of thermo-chemically modified beech wood degraded by brown-rot fungus
2018 - IRG/WP 18-40823
Wood chemical modification with lactic acid oligomers (OLA) has been reported to confer promising properties for wood outdoors applications. To better understand the lactic acid interaction with wood, chemical changes following biological degradation have been characterized with a battery of tests. Fourier transform infrared (FTIR) spectroscopy has been proved to be a valuable tool for studying fu...
C Grosse, M Noël, M-F Thevenon, P Gérardin


Resistance of modified wood to termite attack assessed in laboratory and field testing: A review of internal research
2018 - IRG/WP 18-40824
Within the past decades, new wood modification technologies have been investigated in order to improve certain wood characteristics and enable the use of timber products for outdoor applications. Some of these non-biocidal technologies have been developed and commercialized recently. Thus, various material properties were studied intensively and shown to be improved. To a great extent, previous re...
L Emmerich, P Gascón-Garrido, H Militz


Long-term performance of DMDHEU-treated wood exposed in ground, above ground and in the marine environment
2018 - IRG/WP 18-40825
Chemical wood modification with N-methylol compounds such as 1.3-dimethylol-4.5-dihydroxyethyleneurea (DMDHEU) has been studied intensively since the 1990s. Research of the past years focused on treatment of Scots pine (Pinus sylvestris L.) and European beech wood (Fagus sylvatica L.) and was shown to be applicable to improve specific material properties. A high resistance against wood-destroying ...
L Emmerich, H Militz, C Brischke


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Development of beech wood thermo-chemical modification treatments based on different vinylic derivatives of glycerol and polyglycerol
2019 - IRG/WP 19-40855
In this study, a combination between chemical and thermal wood modification has been investigated. Seven types of a low concentration of 10% aqueous additive solution of vinylicglycerol [glycerol-maleic anhydride (Gly-MA), glycidyl methacrylate (GM), and Glycerol methacrylate-maleic anhydride (GM/MA(2eq))], vinylicpolyglycerol [polyglycerol-maleic anhydride (PG-MA), polyglycerol methacrylate (PGM...
M Mubarok, S Dumarcay, H Militz, K Candelier, M-F Thevenon, P Gerardin


Study on the ability of wood-destroying fungi to grow through chemically modified wood
2019 - IRG/WP 19-40858
Over the last decades, chemical wood modification technologies were developed to increase the resistance against attack by wood-destroying organisms without using biocides. Most of those technologies are based on an impregnation step initially. In most treated wood products, mainly by using solid wood in thicker dimensions as in posts, poles, sleepers, deckings etc. it is known that wood impregnat...
L Emmerich, S Strohbusch, C Brischke, S Bollmus, H Militz


Water interactions in wood polyesterified with sorbitol and citric acid
2020 - IRG/WP 20-40888
Polyesterifcation of wood with sorbitol and citric acid seems to be a promising chemical wood modification technique that is both low-cost and produced from bio-based chemicals. An interesting aspect of the modification is the interaction of water with the polyesterified wood since the relationship with moisture appears to be unique compared to other wood modification systems. This communication p...
G Beck, A Treu, E Larnøy


Mechanical and biological durability properties against soft-rot and subterranean termite in the field (grave-yard test) of beech wood impregnated with different derivatives of glycerol or polyglycerol and maleic anhydride followed by thermal modification in an opened or in a closed system
2021 - IRG/WP 21-40917
This paper presents mechanical and biological durability properties in soil beg test (soft-rot test) and field test (grave-yard test) against subterranean termite of the wood modified with an aqueous vinylic derivative of glycerol/polyglycerol or maleic anhydride cured in an opened or in a closed system. Wood modification was performed through impregnation of European beech (Fagus sylvatica) with ...
M Mubarok, H Militz, S Dumarcay, I W Darmawan, Y S Hadi, P Gerardin


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