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Proposed degradation pathway for quaternary ammonium compounds by mould fungi
1996 - IRG/WP 96-10166
One group of chemicals that has attracted considerable attention as potential wood preservatives are the quaternary ammonium compounds (QACs). Based upon results of previous research this study confirmed the degradation pathway employed in QAC-tolerant fungi. For this experiment the two dialkylammonium compounds didecyldimethylammonnium chloride and dioctyldimethylammonium chloride were used. QAC-...
J L Bürgel, J Dubois, J N R Ruddick


Tests on preservation of wood against marine borers
1976 - IRG/WP 417
The Instituto del Legno has carried out for some years a series of trials about the biodeterioration of wood in the sea. The investigations included the settlement and activity of marine borers, the natural durability of indigenous and tropical woods and the preservation of wood for marine use. This paper reports the trials on the effectiveness of some preservatives in protecting wood against mari...
A Gambetta, E Orlandi


Variation in Canadian bluestain fungi: Tolerance to DDAC and DOT
1999 - IRG/WP 99-10303
Bluestain in Canadian wood products results in significant and unpredictable losses each year. In order to develop rational methods to eliminate or reduce the sapstain problem, a more complete knowledge of the causal organisms must be gained. This includes a knowledge of the variability in tolerance of different fungal species and strains to commercially used chemicals. In British Columbia, the ma...
J Dubois, A Byrne, J E Clark, A Uzunovic


The preliminary evaluation of selected sulfonium salts for use in wood preservation
1984 - IRG/WP 3278
Five sulfonium compounds, including two sulfonium methosulfates, one sulfonium bromide and two amphoteric sulfonium propanesulfonates, were prepared in crude form and subjected to various biocidal screening tests. A rapid screening test in which treated Pinus radiata pulp pellets were exposed to one of three wood-decaying fungi growing on malt agar revealed that dodecyl dimethyl sulfonium methosul...
D V Plackett


The effect of didecyldimethylammonium chloride on growth of different strains of mould fungus Gliocladium roseum
1995 - IRG/WP 95-10105
The tolerance and degrading ability of different strains of Gliocladium roseum towards didecyldimethylammonium chloride (DDAC) were studied. All four of the strains of Gliocladium roseum were tolerant to DDAC and after their growth on amended malt agar, the retention of DDAC in the medium was reduced....
Yu Zheng, J N R Ruddick


Interaction mechanisms of F/Cr/As/B type preservative and wood
1981 - IRG/WP 3183
The paper reports results of investigations on the fixation of the components of a F/Cr/As/B preservative in wood and its lignin and cellulosic components....
N Ermush, I Andersone


Preservatives treatment and field test monitoring of spruce pole stock: CCA and fumigant treatments
1990 - IRG/WP 3619
The fumigants trichloronitromethane (chloropicrin) and sodium N-methyldithiocarbamate (SNMDC) were used to treat red spruce pole stock, either CCA treated or untreated, through holes bored through the pole's center. The poles were analyzed for the presence of microorganisms immediately before ground installation and again after installation at a pole test site. Monitoring of fumigant move...
A J Pendlebury, B Goodell


Antifungal properties of new quaternary ammonium and imidazolium salts against wood decay, staining and mould fungi
2004 - IRG/WP 04-30347
The biological activity of twenty-four potential wood preservatives – imidazolium and quaternary ammonium salts with a modified anion structure was determined employing screening agar-plate and agar-block methods. Experiments were carried out on Scots pine (Pinus sylvestris L.) wood. The aim of the performed studies was to investigate the effect of structure modification of IC and QAC with organ...
J Zabielska-Matejuk, W Wieczorek


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


Investigation of the fixation in wood of chromated zinc chloride and copperised chromated zinc chloride preservatives
1976 - IRG/WP 372
A biological method of evaluating the extent to which CZC and CCZC preparations are retained in wood in terms of the potential protection which they afford against destruction by Merulius lacrymans (dry rot) is given. CCZC is recommended for protection of wood under moderate leaching conditions, while the use of CZC under such conditions is not recommended....
V N Sozonova, D A Belenkov


Evaluation of an alkyl ammonium compound as a fungicide to control sapstain and mould during diffusion storage
1984 - IRG/WP 3282
An alkyl ammonium compound ('Akzo' ES 255) was evaluated for its effectiveness against mould and sapstain during diffusion storage of boron-treated rubber wood. Though ES 255 at 1.0% concentration was effective against mould (71%) and sapstain (89%) it is less satisfactory compared to 0.5% sodium pentachlorophenoxide against mould (92%) and sapstain (98%)....
R Gnanaharan


A potential anti-sapstain chemical for sawmills
1984 - IRG/WP 3300
Several biocidal formulations were tested under laboratory conditions in order to discover an alternative antisapstain chemical to chlorophenoxides. The formulations tested were experimental water solutions containing a quaternary ammonium chloride, a commercial fungicide and/or a sodium salt of some carboxylic acids. The effect of sodium carbonate and borax decahydrate in mixture with a quaternar...
I A Linderborg


Methyl bromide eradication of the oak wilt fungus in logs. Laboratory and field fumigation
1981 - IRG/WP 3168
Concern over accidental introduction of the oak wilt fungus (Ceratocystis fagacearum) into oak-importing nations has prompted a study supported by the U.S. National Lumber Exporter's Assn. to assess the efficacy of methyl bromide fumigation to eradicate the fungus from logs and lumber. Laboratory and field fumigation trials to develop a reliable and realistic treatment were performed on r...
E L Schmidt, M M Ruetze, D W French


Photo-discoloration and Degradation of Wood and its Stabilisation by Modification with Benzoyl Chloride
2004 - IRG/WP 04-40274
Photo degradation of Pinus roxburghii (chir pine) and Hevea brasiliensis (rubber wood) was studied under artificial accelerated weathering conditions in a Xenon test chamber. The irradiated samples were analyzed for color changes and chemical changes. Analysis of colour changes in wood surfaces by UV-Vis. irradiation was carried out using a colour measuring (CIELAB) system and chemical changes ...
K K Pandey


An investigation of organotin compounds in treated wood using Mössbauer spectroscopy
1983 - IRG/WP 3249
The influence of sample preparation on the 119mSn Mössbauer spectrum of tributyltin chloride in ponderosa pine was investigated. Initial studies with sawdust and compressed discs concluded that the latter were clearly superior. Further studies showed that compressed discs prepared from 0.4 g of treated wood and 0.1 g of cellulose were robust and gave excellent Mössbauer spectra. The possibility ...
J N R Ruddick, J K Ingram


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB. ...
H Härtner, S Schmitt, Futong Cui, H M Barnes


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


The influence of wood moisture content on the fungitoxicity of methylisothiocyanate in Douglas fir heartwood
1987 - IRG/WP 3430
The fumigant methylisothiocyanate (MIT) effectively controls decay fungi in large wood structures, but the influence of environmental factors on its performance are not well understood. Experiments found wood moisture content to greatly influence the fungitoxicity and sorption of MIT in Douglas fir heartwood. At constant, low MIT vapor concentrations (less than 1 µg/cc air), wood at 10% MC bound ...
A R Zahora, J J Morrell


Natural exposure weathering tests: Their role in the assessment of wood preservative efficacy
1993 - IRG/WP 93-20006
Previous work has demonstrated the potential and usefulness of natural ageing procedures in e evaluation of wood preservative efficacy. This results from the combination of physico-chemical influences and microbiological interactions with both substrate and wood preservative. In this paper, results are presented for a range of biocide types. Discussions are centred on the value of natural exposure...
G R Williams, J Brown


Field tests of preservative-treated radiata pine in Japan
1995 - IRG/WP 95-30083
Test stakes of radiata pine treated with various alkyl ammonium compound (AAC) formulations and with copper-chrome-arsenate (CCA) as reference preservative were installed in 3 test sites in Japan in 1981-82. When inspected in 1995, CCA-treated stakes showed less decay at all three sites than stakes treated with other formulations. Ammoniacal copper quaternary (ACQ)- treatment was only slightly les...
M E Hedley, K Tsunoda, K Suzuki


The fungal degradation of quaternary ammonium compounds in wood
1998 - IRG/WP 98-10263
This work focuses on the biodegradation of didecyldimethylammonium chloride (DDAC) by the mould fungus Gliocladium roseum within a woody matrix. Three sawdust types, distinguished by their treatment and amount of DDAC retained, were inoculated with the fungus and their DDAC loss was measured over 11 weeks. The rates of degradation varied depending on the sawdust; however, a significant loss of DDA...
J W Dubois, J N R Ruddick


Low polymer levels containing bioactive monomer polymerized in situ provide resistance to Gloeophyllum trabeum
1995 - IRG/WP 95-30066
Wood preservation based on in situ polymerization of potentially bioactive monomers has been studied. Tributyltin oxide acrylate (TBTOA) and pentachlorophenol acrylate (PCPA) were synthesized. Wood samples were treated at 2, 5, 10, 15 and 20% by weight solutions with varying amounts of crosslinker (trimethylolpropane trimethacrylate, TMPTM) and polymerized in situ in wood samples (2.54 x 2.54 x 0....
R E Ibach, R M Rowell


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


Fungitoxic effect of the quaternary ammonium compounds preservatives against Basidiomycetes by using agar-plate and agar-block methods
1996 - IRG/WP 96-30118
Results of investigations on the fungitoxic value of three versions of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethyl-benzylammonium bromide and alkylbenzyldimethylammonium chloride) and borates in relation to the wood destroying fungi have been presented. The agar-plate (screening) and agar-block method were applied. A wide ran...
J Wazny, P Rudniewski


Mixtures of fungicides screened for the control of sapstain on Pinus radiata
1984 - IRG/WP 3307
Fourty nine mixtures of fungicides were evaluated in a rapid laboratory screen for the control of stain, mould and decay fungi on Pinus radiata (D.Don). The most effective mixture was thiophanate methyl plus chlorothalonil closely followed by the mixtures of thiophanate methyl plus benzisothiazolone and thiophanate methyl plus dithio-bis (benzmethylamide). Benzalkonium chloride, thiram and ziram, ...
P J Hayward, W Rae, J Duff


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