Your search resulted in 109 documents. Displaying 25 entries per page.
Chemical analyses of IRG/COIPM INTERNATIONAL MARINE TEST (to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water) samples
1987 - IRG/WP 4114
Chemical analysis of CCA and CCB treated timber was carried out after exposure at tropical and temperate marine sites. Results indicated that losses of all elements had occurred. In particular, losses of boron were severe. Arsenic and copper were also lost. The chromium components in both formulations was the most dominant metal remaining. The results suggest that chromium modification was importa...
L E Leightley
Controlled fixation technology
1995 - IRG/WP 95-50040-12
Controlled fixation techniques have been developed and adopted in a number of countries where chromium containing preservatives are predominantly used. The purpose of this technology is to reduce both on-site pollution and holding requirements for freshly treated timber. The fixation mechanism is complex and the time taken to complete the reaction is dependent upon a number of factors. A number of...
M Connell, W J Baldwin, T Smith
The use of a physical field model to study the effects of remedially treated timber on the growth of perennial ryegrass (Lolium perenne) and rye (Secale cereale), and the accumulation of toxic preservative constituents in Lolium perenne
1995 - IRG/WP 95-50040-02
Low cost laboratory model systems can be used to give relatively rapid indications of the environmental effects of preservative treated timber in soil contact. This paper details the effects of remedially treated timber on the growth of crops of Lolium perenne and Secale cereale seeded on soilbeds of different texture in close proximity to remedially treated creosoted pole sections. Lolium perenne...
D C R Sinclair, G M Smith, A Bruce, H J Staines
A comparative study of CCA type C and B treated poles in service
1993 - IRG/WP 93-50001-05
CCA K33 type B and C treated utility poles, 9 pieces of each treatment type, were analyzed for preservative retention after 11 years in use. Borings were taking 1 m above and 0.3 m below the ground line. Also total amount of copper, chromium and arsenic was determined in soil surrounding the poles. The solubility of these active components in soil was monitored by using different leaching procedur...
A J Nurmi
Preliminary study on relation of wood structure to copper/chrome/arsenic (CCA) distribution in kempas (Koompassia malaccensis)
1995 - IRG/WP 95-40054
Kempas had been treated with copper/chrome/arsenic (CCA) preservative using full cell process. Analysis of preservative distribution at the micro level in relation to wood structure was carried out using scanning electron microscope (SEM) and energy dispersive X-ray (EDXA) analysis. The results showed that CCA elements were detected in all wood tissues at different ratios. Distribution of chemical...
S Ani, S Salamah
Acceleration of the fixation of chromated wood preservatives by UV-radiation
1989 - IRG/WP 3544
Preliminary laboratory tests demonstrated that the fixation of chromated water-borne wood preservatives may be accelerated by UV-radiation. The degree of fixation depends on the intensity of radiation and the prevailing temperature. Three hours radiation at 20°C in a device for artificial weathering diminished the leaching of chromium to 43% and of copper to 23% compared to not-radiated samples. ...
H M Illner, H Willeitner, K Brandt
Sampling variation in a copper chrome arsenic treated power transmission pole
1990 - IRG/WP 2351
The Queensland Forest Service routinely samples poles treated at all treatment plants throughout the State. Each treatment plant is issued with a Certificate of Registration and the accompanying documents list the different levels of preservative retention required for performance in various service conditions. The posted levels represent the.minimum permissible, and it is to these concentrations ...
J Norton
Determination of fixation properties by bioassays - A proposal for the assessment of safety indexes in wood protection
1990 - IRG/WP 3566
In the determination of environmental effects of chemicals tests with fishes, daphnia and algae have proved to be practicable. With respect to wood protection such bioassays are suitable to control effects of treated timber against aquatic organisms. By using the fish-acute-toxicity-test the development of a laboratory test method is described for the checking of the fixation rate of a copper-chro...
H-W Wegen
Kiln drying of CCA-treated wood - Some safety and environmental considerations
1987 - IRG/WP 3443
Vapours and condensate from a condenser kiln in which CCA-treated wood was being dried have been collected and analysed. The concentrations of arsenic, copper and chromium found in the vapours from the drying process were well below Swedish threshold limit values. The contents of arsenic and chromium were also low in the condensate, although the copper content was fairly high. The latter result wa...
J Jermer, B Lundberg
Applications of the shower test. Part B: Results from CC and CCB treated wood: influence of fixation process
1993 - IRG/WP 93-50010
This report outlines the results of shower tests conducted on CC and CCB treated wood. The results indicate the fairly good fixation of chromium and the reasonable fixation of copper in CC and CCB formulations, as judged by the leaching limits within the Environmental Regulations. In general boron leaches to a higher extent than chromium and copper. The shower test has proven to be a useful qualit...
W J Homan, H Militz
Assessment of dehydrogenase activity, fluoride content and total chromium content of soil profiles exposed to preservative treated wood within a model system
1993 - IRG/WP 93-10015
The development and prospective use of a closed model system to facilitate study of a number of indicators of environmental impact of wood preservatives laboratory conditions has been described (IRG/WP/2395-92). Chemical analysis of leachate samples collected from drained soil profiles containing creosoted pole sections remedially treated with a chromated fluoride preservative indicated small incr...
G M Smith, D C R Sinclair, A Bruce, H J Staines
Effectiveness of copper/chromium salts as wood preservatives against Limnoria tripunctata Menzies in laboratory tests
1977 - IRG/WP 431
During the last joint meeting of IRG and COIPM a co-operative programme of tests with copper/chromium salts as wood preservatives against marine borers was discussed and agreed. In this connection the results of a laboratory test in the BAM with Limnoria tripunctata Menzies will be of interest. But as the respective paper is written in German (H. Kühne; G. Becker: Laboratoriumsversuche über die ...
H Kühne
Initial results and observations of a model system to assess the efficacy and environmetal impact of preservative treated wood
1993 - IRG/WP 93-50001-02
The development of a closed model system for the laboratory assessment of the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles has been described (IRG/WP/2395-92). The model consists of a precipitation apparatus above a treated pole section positioned in a soil profile from which leachate was collected via a series of simulated field dra...
D C R Sinclair, G M Smith, A Bruce, H J Staines
Report on the burning of wood treated with wood preservatives containing copper, chromium and arsenic
1976 - IRG/WP 379
Mixtures of copper, chromium and arsenic salts are used extensively in the UK to preserve timber. This report is concerned with the fate of these metals when timber treated with these salts is burned. A large percentage of the arsenic present in the timber is shown to be volatilised during combustion and the potential environmental implications of this are assessed by comparison with the release o...
A J Dobbs, C Grant
The environmental chemistry of chromium: Science vs. U.S. law
1993 - IRG/WP 93-50014
The cooperation which existed among chromium chemical producers, industrial health laboratories, and governmet agencies was destroyed after 1970 by the advent of environmental activism and regulatory legislation. As prewar plants had been found to pose a serious cancer risk, this fact was the basis of EPA regulations, especially during the term of Joe Califano in HEW under Jimmy Carter. However, a...
W H Hartford
Investigation of temperature effect on fixation of Celcure preservative (ACC) in beech (Fagus orientalis)
2001 - IRG/WP 01-40200
In this research, the fixation speed of Celcure 2% (ACC) preservative salt, under temperature of 17°C, 27°C and 50°C, on intact and stained wood specimens of beech was investigated. For this purpose, blocks of wood with 5x5x7 cm dimensions were prepared and saturated with 2% ACC concentration by full-cell process. The specimens were put in three incubators at the above-mentioned temperatures. F...
A Karimi, M Ghorbani
The implementation of restrictions on the use of arsenic and chromium based wood preservatives in Sweden
1995 - IRG/WP 95-50062
In 1992 the Swedish National Chemicals Inspectorate introduced restrictions on the use of wood treated with arsenic and/or chromium based wood preservatives. Such wood is now in principle only allowed for use in ground contact or in water. These restrictions have had considerable influence on the use of wood preservatives for sawn timber for the Swedish domestic market. Thus only 35% of the preser...
J Jermer, M-L Edlund, K Nilsson
Studies on the mobility of arsenic, copper and chromium in CCA-contaminated soil
1990 - IRG/WP 3571
CCA contaminated soils from six Swedish preservation plants were investigated primarily to study the mobility of arsenic but also that of copper and chromium in the soils. The soil samples represented average types with different amounts of clay, organic matter, arsenic, copper, chromium and different pH. The total soluble amounts of the elements were measured. The pH dependent solubility and the ...
J Bergholm
Inorganic preservatives in wood dust - Cause of nasal cancer?
1997 - IRG/WP 97-50085
Since 1985 dust particles from beech and oak trees have been classified by the Senate Commission of the German Research Council (DFG) as being ,,working materials which are definitely carcinogenic to humans". All other wood dusts, including those from softwoods, are classified as being materials ,,with reasonable suspicion of carcinogenic potential". The carcinogenic principle of action continues ...
A O Rapp, K Brandt, R-D Peek, U Schmitt
Selective chromate elimination from the storage-drainage-water of a wood impregnation plant
1980 - IRG/WP 3153
With the Enviro-Chrom-Ex process it is possible to eliminate ecologically and economically hexavalent chromium (chromate) from water selectively. The process which is based on the principle of selective ion exchange works with different chromate concentrations and under the presence of other ions, irrespective of the water hardness. The values of water-offtake reach 0.1 mg CrVI at maximum, causing...
O Wälchli, R Ott, R Hugener, E Graf, B Lieberherr
Fungal remediation of CCA-treated wood
2004 - IRG/WP 04-50210
This study evaluates oxalic acid accumulation and bioremediation chromated copper arsenate (CCA) treated wood by three brown-rot fungi, Fomitopsis palustris, Coniophora puteana, and Laetiporus sulphureus and ten mold and staining fungi, Aspergillus niger, Aureobasidium pullulans, Gliocladium virens, Penicillium funiculosum, Rhizopus javanicus, Ceratocystis pilifera, C. peceae, Alternaria alternata...
S N Kartal, Y Imamura
The non-uniform uptake of chromium and copper during the impregnation of wood using the example of a CCB-salt
1998 - IRG/WP 98-20137
The correct impregnation of wood requires among other things a regular control of the concentration of the treating solution as this and/or its stoichometric composition can change as a result of the impregna-tion process and the treated wood. The preferential uptake of individual wood preservative components by the wood is of particular importance in this connection.
Dipping and vacuum impregnat...
P Jüngel, E Melcher, R-D Peek
The mechanism of leaching of copper-chrome-arsenic preservatives from treated timber in saline waters
1976 - IRG/WP 374
A mechanism for the leaching of copper-chrome-arsenic preservatives is proposed on the basis of theoretical calculations and experimental studies using timber subjected to a range of water types of different ionic compositions. Complex formation by copper (II) and chromium (III) with chloride and hydroxide ions is shown to affect the leaching rate. Of even greater importance is the salt effect on ...
J Irvine, S-E Dahlgren
Economical analysis of the chemicals used on remediation copper, chromium and arsenic from out of service CCA-treated utility poles in Turkey
2004 - IRG/WP 04-50217
There are 20.7 million hectare forested area in Turkey. However, the wood products supplies do not meet demand. One of the wooden products is the utility poles. In Turkey, impregnation of utility poles has been started since 1960's and 5 million utility poles have been used until today since then. Although life time of the utility poles may vary depending on climatic conditions, average s...
E D Gezer, D Toksoy, Ü C Yildiz
Distribution of copper/chrome/boron preservative in light red meranti (Shorea leprosula) before and after exposure test for 72 months
1995 - IRG/WP 95-20073
Copper/chrome/boron (CCB) preservative at 6% w/w was impregnated into light red meranti (Shorea leprosula) by full cell process. The quantitative analysis for copper, chrome and boron contents in treated wood samples was carried out by Inductive Couple Plasma (ICP). Electron Probe Microanalyser (EPMA) was used to monitor the distribution of copper, chrome and boron in the various treated wood tiss...
S Salamah, S Ani