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Controlling the sapstain fungus Ceratocystis coerulescens by metabolites obtained from Bjerkandera adusta and Talaromyces flavus
1993 - IRG/WP 93-10024
Sapstain causes severe damage to wood and wood products, posing a major economic problem for the wood industry. The purpose of this study was to determine if metabolites from Bjerkandera adusta and Talaromyces flavus would (1) decolorize stain in wood caused by Ceratocystis coerulescens and (2) prevent sapstain by Ceratocystis coerulescens. We studied the interaction of the sapstain fungus Ceratoc...
S C Croan, T L Highley


A laboratory evaluation of the fumigant, sulfuryl fluoride (VikaneR), against the Formosan termite Coptotermes formosanus Shiraki
1982 - IRG/WP 1164
A series of laboratory experiments showed that the fumigant sulfuryl fluoride (VikaneR) was effective against small groups of Coptotermes formosanus Shiraki exposed to the gas directly at temperatures from 20-40°C. At 10°C fumigations failed regardless of initial gas concentration. Very high or total mortality was observed at concentrations of 0.79 cc/L or higher. A second series of experiments ...
J P La Fage, M Jones, T Lawrence


Performance of boron and fluoride based rods as remedial treatments in Douglas-fir poles
1995 - IRG/WP 95-30070
Boron and fluoride are widely used for remedial internal treatments, but their use in North America has been limited. Recently, however, interest in these chemicals has increased as the result of concerns about the risks of fumigant usage. The performance of boron or a boron/fluoride combination was assessed in Douglas-fir poles over 1 to 3 year periods. Both chemical formulations diffused well th...
J J Morrell, P F Schneider


The effect of different concentrations of polesaver rods on the survival of selected decay fungi in liquid culture
1998 - IRG/WP 98-30166
An in-vitro method was developed to determine the effect of solutions of Polesaver Rods on the survival of selected decay fungi. Polesaver Rods are a diffusing preservative treatment containing fluorine and boron designed for the internal remedial treatment of power poles. Two white-rot fungi, Perenniporia tephropora and Trametes versicolor, and two brown-rot fungi, Polyporus verecundus and Gloeo...
M A Powell, T Deldot, C McEvoy


Determination of total fluoride and boron in preservative-treated wood fluoride by ion selective electrode without steam distillation, and boron colorimetrically using azornethine-h
1998 - IRG/WP 98-20135
An analytical method was developed to determine total fluoride and boron in wood treated with aqueous or solid diffusing fluoride or borate-fluoride formulations. Ground wood was mixed with 30% sodium hydroxide solution and oven-dried for 2 hours before furnacing at 600° C for 1 hour. The cool fused product was dissolved in hot water, transferred to a plastic beaker and neutralised. Fluoride was ...
P A Collins, M J Kennedy


Production of exraxellular hydrogen peroxide and oxalic acid by brown-rot fungus Poria placenta
1995 - IRG/WP 95-10112
Hydrogen peroxide and oxalic acid have been suggested to be essential in the degradation of wood carbohydrates by brown-rot fungi. Hydrogen peroxide has been suggested to be one of the diffusible low molecular weight agents produced by brown-rot fungi for the degradation of wood carbohydrates by generating highly active radicals. The production of hydrogen peroxide and oxalic acid by Poria placent...
A-C Ritschkoff, M Rättö, J Buchert, L Viikari


Extracellular hydrogen peroxide producing and hydrogen peroxide reducing compounds of wood decay fungi
1991 - IRG/WP 1516
Extracellular H2O2-producing and H2O2-reducing compounds were isolated from wood-containing cultures of all the white-rot and brown-rot fungi and Ascomycetes which well degraded wood, but were not detected in the culture of the fungi which degraded little wood. The compounds are glycopeptides with a low molecular weight, require H2O2 for one-electron oxidation, catalyze the redox reaction between ...
A Enoki, G Fuse, H Tanaka


Development of a model system to assess the efficacy and environmental impact of a chromated fluoride remedial treatment for creosoted distribution poles
1992 - IRG/WP 92-2395
A closed model system was designed to facilitate a controlled study of the leachability and environmental fate of a remedial preservative under laboratory conditions. The elements of the model include a precipitation apparatus above a treated pole section which is positioned in a representative soil profile supporting a sward of perennial ryegrass. The model will allow detailed examination of the ...
D C R Sinclair, G M Smith, A Bruce, B King


Diffusion of chromium and fluoride in Rentex treated creosoted pole sections
1991 - IRG/WP 3659
A chromated fluoride preservative was applied by injection to the groundline regions of creosoted distribution pole sections and these were erected at a filed site in Scotland. Wood samples were recovered for chemical analysis at one week, two, five and twelve months after treatment. Small sample mass and destructive nature of the analysis necessitated modification of an alkali fusion technique to...
D C R Sinclair, G M Smith, A Bruce, B King, H J Staines


Extracellular substance from the white rot basidiomycete Irpex lacteus involved in wood degradation
1992 - IRG/WP 92-1571
Cellulases, phenol oxidase, and a substance that both produced and reduced H2O2 were isolated from cultures containing wood or glucose on which the white-rot fungus Irpex lacteus was growing. The rate of wood degradation by the fungus with different amounts of glucose in the medium was measured. More of the substance that produced and reduced H2O2 was found extracellularly in cultures containing w...
H Tanaka, T Hirano, G Fuse, A Enoki


Basisiospore production by Lentinus lepideus in vitro
1987 - IRG/WP 2276
Evaluation of fungicides active against the lower fungi by spore based bioassays is very common. Possibilities of using similar assays to evaluate preservatives against brown rot and white rot fungi, especially for use in above ground constructions, are limited by the lack of methods for production of basidiospores. Tested media containing glucose 10-30 g/l and ammonium tartrate concentrations 2-2...
J Bjurman


The role of oxidation in wood degradation by brown-rot fung
1992 - IRG/WP 92-1562
Brown-rot fungi are suggested to degrade cellulose by oxidation with hydrogen radicalsformed eg. in the conversion of hydrogen peroxide in the Fenton type reactions. The stuctural changes in the holocellulose in wood induced by Fenton's reaction on wood components are very similar to those caused by brown-rot fungi. In this work the effect of the Fenton reaction on wood components was stu...
A-C Ritschkoff, J Pere, J Buchert, L Viikari


Mechanistic aspects of the reactions of copper complexes with lignin in the presence of hydrogen peroxide and lipid hydroperoxide model compounds as proposed for white rot fungi
2001 - IRG/WP 01-10399
The structural principles and the oxidative reactions of the catalytic system consisting of copper, hydroperoxides, and copper coordination compounds that contain aromatic nitrogen atoms are similar to those of catalytic centers of oxidative enzymes involved in delignification reactions of white rot fungi. The system is capable of selectively degrading lignin and its low molecular weight would all...
K Fackler, P Lamaipis, E Srebotnik, M Humar, C Tavzes, F Pohleven, M Sentjurc, T Watanabe, K Messner


Extracellular hydrogen peroxide-producing and one-electron oxidation system of brown-rot fungi
1990 - IRG/WP 1445
Wood-component-degrading compounds involved in the initial degradation of the cellulose and lignin in wood were isolated from wood-containing culture of brown-rot fungi, Gloeophyllum trabeum and Tyromyces palustris and partially purified by gel filtration on Sephadex G-25 and DEAE-Sepharose ion-exchange chromatography. The compounds were glycoproteins. The molecular weights of the glycoproteins as...
A Enoki, S Yoshioka, H Tanaka, G Fuse


Site characteristics impacting historic waterlogged wood: A review
2000 - IRG/WP 00-10344
Survival of waterlogged wood from hundreds and in rare cases millions of years presents scientists with a unique opportunity to examine wood specimens which, due to select properties of the wood itself and/or the depostional environment, have not been completely degraded. Although degradation patterns of various types of microbial wood decay have been studied in detail, the site parameters of the ...
B A Jordan, E L Schmidt


Experiments on the degradation of tributyltin oxide: A progress report
1984 - IRG/WP 3287
A variety of experiments designed to assess the chemical and physical factors affecting the degradation of tributyltin oxide in treated timber are described. Simple procedures in which temperature and oxygen availability were increased in the presence of wood and water suggest that the wood itself was of prime importance. Attempts to decrease degradation with antioxidants were unsuccessful but led...
R J Orsler, G E Holland


Fluoride movement through Douglas-fir and hem-fir lumber following dipping in potassium/ammonium bifluoride
1995 - IRG/WP 95-40040
The ability of ammonium and potassium fluoride to diffuse through Douglas-fir and hem-fir lumber was evaluated over a 90 day period. Boards were dipped in a solution containing 10% (by weight) of ammonium and potassium bifluoride, then stored under cover for 90 days. Samples removed 30, 60 and 90 days after treatment indicated that the fluoride was unable to completely penetrate the wood. Penetrat...
J J Morrell, C S Love


In-house accelerated method for testing decay resistance of treated wood
2004 - IRG/WP 04-20286
Fungicidal compounds often change their effectiveness when they are incorporated into candidate formulations. For this reason fungistatic effectiveness needs to be re-evaluated as many times as the formula has been modified for better performance. To avoid multiple expenses, in-house fungistatic tests are essential. Our goal was to develop in-house usable, simple but reliable and reproductive proc...
N Vidovic


Optimisation of an analytical method for the determination of total fluoride in preservative-contaminated soils using water steam distillation and an ion-selective electrode
1999 - IRG/WP 99-20153
This paper describes a simple modified procedure for the quantitative fluoride determination of different origin in a soil matrix using a water steam distillation and an ion-selective electrode. Distillation methods generally require a preliminary preparation step like fusing. The modified method presented here is based on the direct distillation of fluoride so that no further sample preparation i...
E Melcher


The production of extracellular hydrogen peroxide by some brown-rot fungi
1990 - IRG/WP 1446
The role of hydrogen peroxide (H2O2) has been discussed in the degradation of wood by wood-rotting fungi. The production of extracellular hydrogen peroxide was studied by detecting the oxidation of the chromogen 2,2'-azinobis(3-ethylbenzthiazoline-6-sulphonic acid) (ABTS) by H2O2 and horse radish peroxidase (HPR). ABTS and HPR were added to a solid wood based culture media. In this study ...
A-C Ritschkoff, L Paajanen, L Viikari


Assessment of the effects of rentex remedial treatment on some wood pole inhabitant micro-organisms
1994 - IRG/WP 94-30053
The effects of a remedial ground-line treatment using Rentex, a stabilised paste containing a mixture of fluoride and dichromate salts, on the micro-organisms inhabiting a sample of some 160 creosoted, on-line, electricity distribution poles, have been investigated as part of an appraisal of the efficacy of this remedial treatment. Half of the poles were treated and the other half used as controls...
D C R Sinclair, G M Smith, A Bruce, H J Staines


Performance of groundline bandage remedial treatments in western US species transmission poles
1993 - IRG/WP 93-30019
Groundline bandages are an important element in remedial treatment strategies for utility poles in the United States. Several bandages containing new or reformulated components have recently been developed but have not been adequately tested. This paper reports on the degree of diffusion of copper naphthenate, boron, and sodium fluoride from groundline bandages into pressuretreated Douglas-fir, po...
P G Forsyth, J J Morrell


The influence of drilling patterns on the distribution of toxicants from Polesaver Rods in hardwood poles
1994 - IRG/WP 94-30051
Polesaver Rods are solid rods of wood preservative that are used as a groundline maintenance treatment to control biodeterioration in hardwood transmission poles in Australia. The rods are inserted in holes that are drilled in a prescribed manner to distribute the toxicants into the critical groundline region of the poles. To determine the influence of drilling patterns on the distribution of toxi...
W D Gardner, C N McEvoy


On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


Effects of chemical pretreatment of Douglas-fir heartwood on efficacy of potential bioprotection agents
1990 - IRG/WP 1440
Biological protection against wood decay fungi represents an environmentally attractive alternative to the use of chemicals; however, the process of identifying suitable candidates and the conditions that ensure successful protection pose major challenges. One critical aspect of this problem is to identify organisms that can rapidly and uniformly colonize the wood. Wood contains low levels of nutr...
B Dawson-Andoh, J J Morrell


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