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The fungal degradation of quaternary ammonium compounds in wood
1998 - IRG/WP 98-10263
This work focuses on the biodegradation of didecyldimethylammonium chloride (DDAC) by the mould fungus Gliocladium roseum within a woody matrix. Three sawdust types, distinguished by their treatment and amount of DDAC retained, were inoculated with the fungus and their DDAC loss was measured over 11 weeks. The rates of degradation varied depending on the sawdust; however, a significant loss of DDA...
J W Dubois, J N R Ruddick


Some factors affecting the treatability of spruce roundwood with ammoniacal preservative solutions
1976 - IRG/WP 371
Permeable wood species for use in preservative-treated commodities are becoming depleted in Canada. Spruce can be a convenient replacement for them from local resources provided it can be treated to levels adequate for protection of commodities in ground contact. Basically, two approaches were taken to improve treatability of difficult-to-penetrate softwood species; first, to improve the permeabil...
J Rak


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


Marine trials with ammoniacal wood preservatives
1980 - IRG/WP 423
Ammoniacal wood preservatives have been known for many years and are considered among the best water-borne systems for protecting wood in ground contact. In recent years attention has been increasingly focussed on these preservatives because of their ability to penetrate difficult-to-treat species better than most other fixed water-borne preservatives. This is particularly important for example, i...
M A Hulme, D P Ostaff


A marine borer test with water-borne preservatives
1980 - IRG/WP 452
The use of preservative treated timber in sea-water where marine borers are active is of great economic importance, since untreated wood immediately will be damaged. Vacuum/pressure treated timber has been tested in several marine exposure trials on the Swedish west coast since the 1930s (Hager 1941, Hultman 1949, Sandstrom 1951, Nylinder-Norman et al. 1974). Since new interesting materials or pre...
B Henningsson, E Norman


Adsorption of ACQ and CuMEA Wood Preservatives in Red pine
2005 - IRG/WP 05-30374
The rates of stabilization or fixation of ACQ subcomponents (CuO, DDAC and MEA) in red pine (Pinus resinosa) were compared for different solution concentrations (0.75%, 1.5%, 2.25% and 3% ACQ-D) and post treatment conditioning temperatures. Preservative solutions were impregnated into red pine sapwood by a full-cell treatment. Copper and MEA adsorptions from copper monoethanolamine solutions witho...
C Tascioglu, P A Cooper, Y T Ung


Fungitoxic effect of the quaternary ammonium compounds preservatives against Basidiomycetes by using agar-plate and agar-block methods
1996 - IRG/WP 96-30118
Results of investigations on the fungitoxic value of three versions of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethyl-benzylammonium bromide and alkylbenzyldimethylammonium chloride) and borates in relation to the wood destroying fungi have been presented. The agar-plate (screening) and agar-block method were applied. A wide ran...
J Wazny, P Rudniewski


Toxic value estimation of wood preservatives by using the probit analysis
1990 - IRG/WP 2348
As it was assumed from previous experiments, the probit analysis appears to be the most suitable method of all used to estimate the toxic value of wood preservatives. With the help of the classical agar-block method the probit analysis was tested for its suitability in: 1) fungitoxic value estimation of the WR-3 preservative (quaternary ammonium compound + borate), as compared to different test fu...
J Wazny, K J Krajewski


Evaluating the potential of amine chemicals for use as wood protecting agents. Part 1: Investigation of cation components of quaternary ammonium compounds
1994 - IRG/WP 94-30049
Quaternary ammonium compounds (quats) have shown a great potential as more environmentally acceptable wood preservatives. In order to identify chemicals possessing the wood protecting potential, an evaluation was carried out of a range of commercially available 'quats', using a modified soil block test. Ponderosa pine sapwood blocks were treated with selected 'quat&a...
Hang Tang, J N R Ruddick


Tests with ammoniacal copper and alkyl ammonium compounds as wood preservatives
1984 - IRG/WP 3299
Formulations based on copper and alkyl ammonium compounds in ammonia solution have been tested in a fungus cellar on Pinus radiata and Fagus sylvatica. This type of products gives promising results as wood preservatives, especially on hardwood and are safe to destroy by e.g. combustion. The best results were achieved with a dialkyl ammonium compound, Cu/octyldecyl dimethyl ammonium chloride (NH3)....
C-E Sundman


The effect of chemical treatment on the moisture distribution of Pinus radiata D.Don subjected to wick action
1999 - IRG/WP 99-40135
Radiata pine sapwood stakes were treated with a range of chemicals, including an ammoniacal copper quaternary ammonium compound (ACQ), a copper-chrome and arsenic (CCA) solution and a CCA-oil treatment, potassium linoleate copper linoleate, a paraffin wax and a proprietary alkyd resin. The effect of these treatments on the extent of water absorption and moisture movement through the stakes was inv...
J Hann, P Vinden


Aspects of the fungal degradation of quaternary ammonium compounds in liquid culture
1997 - IRG/WP 97-30160
Didecyldimethylammonium chloride (DDAC) is a quaternary ammonium compound (QAC) that has found use as an anti-sapstain preservative for the transportation of softwood lumber from Canada to overseas markets. However, its use is limited by the knowledge that certain mould fungi seem capable of degrading it. The aim of this research was to gain knowledge about the fungal degradation of DDAC. The effe...
J W Dubois, J N R Ruddick


The effect of pretreatments on the impregnation of air-dried sawn Belgian spruce
1988 - IRG/WP 3490
In general the impregnation of airdried spruce results in a variable treatment and limited penetration. This is the result of pit aspiration that occurs during drying of the spruce sapwood and heartwood. Spruce timber is becoming of greater importance in Belgium and hence research for better treatment of this vulnerable wood species is needed. Squared airdried timber of different dimensions were e...
J Van Acker, M Stevens


Leachability of didecyldimethylammonium chloride (a quaternary ammonium compound) from four wood species
1982 - IRG/WP 3204
Sapwood blocks prepared from red pine, ponderosa pine, southern yellow pine and hem-fir (a commercial mixture of western hemlock and amabilis fir) were treated with didecyldimethylammonium chloride, (an alkylammonium compound, AAC). After oven drying the blocks were vacuum impregnated with distilled water and subjected to a static leach cycle for 48 hours. The leachate was analyzed and the amount ...
J N R Ruddick, A R H Sam


Laboratory and field trials of novel antisapstain formulations
1997 - IRG/WP 97-30146
This document covers the results of laboratory and field trials of combinations of fungicides formulated using a patented technology (PCT NZ 96/00143). A 3 week laboratory trial that uses radiata pine (Pinus radiata D. Don) branch discs as a substrate was used to determine which combinations possessed a suitable spectrum of fungitoxicity against key sapstain, mould and decay fungi. In particular f...
R N Wakeling, P N Maynard, D R Eden, C M Chittenden, B Carpenter


The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


Efficacy of Didecyl Dimethyl Ammonium Chloride (DDAC), Disodium Octaborate Tetrahydrate (DOT), and Chlorothalonil (CTL) against Common Mold Fungi
2004 - IRG/WP 04-30338
The fungitoxic properties of four fungicides, alone and in combination, against four different mold fungi commonly associated with indoor air quality problems were evaluated on two different wood species and sheetrock. The fungicides were chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile) (CTL) in a 40.4% aqueous dispersion, disodium octaborate tetrahydrate (DOT) in two different forms - a ...
J A Micales-Glaeser, J D Lloyd, T L Woods


Effectiveness of some microbiocides against the development of molds and sapstain in Pinus elliottii
1981 - IRG/WP 3169
Eleven commercial biocidal formulations were tested in the field to determine their effectiveness in protecting logs and lumber of Pinus elliottii sapwood from sap stain and molds. Among these formulations 2-(thiocyanomethylthio) benzothiazole showed the best performance in controlling both types of fungi. Potassium N-hydroxymethyl-N-methyl dithiocarbamate and the mixture potassium N-methyl dithio...
S Milano


Determination methods of phytotoxic effect of wood preservatives
1990 - IRG/WP 2349
The phytotoxic effect of wood preservatives so widely used plays a considerable role in the protection of natural environment. A review was made of the existing methods with which to assess the phytotoxicity of the above chemicals and some suggestions were given concerning the methods most appropriate for their unification. Two areas of research are proposed: 1) estimating the direct effect on ind...
A Kundzewicz, J Wazny


Movement of water through quaternary ammonium treated wood
1987 - IRG/WP 3440
Radiata pine sapwood stakes were treated with didodecyl methyl 1, 3 dichloropropenyl ammonium chloride and distearyl dimethyl ammonium chloride. Various ratios of these two chemicals were, tested to determine the extent of water movement through the treated wood. Measurements were taken of the amount of water moved through the wood, degree of wetting of various sectors of the stakes, and the distr...
P J Hayward, J Duff


Decay and termite resistance of wood treated with boron-containing quaternary ammonia compound, didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin
2004 - IRG/WP 04-30334
This study evaluates the decay and termite resistance of surface-treated wood with didecyl dimethyl ammonium tetrafluoroborate (DBF) incorporated with acryl-silicon type resin emulsion. DBF is a quaternary ammonia compound and contains boric tetrafluoride (BF4-) as a counter ion in its chemical structure. In the study, DBF was incorporated with an acryl-silicon type resin to increase water-resista...
S N Kartal, W J Hwang, K Shinoda, Y Imamura


Diffusion and interaction of components of water-borne preservatives in the wood cell wall
1988 - IRG/WP 3474
This study investigates the rates of diffusion and ultimate distributions of copper and arsenate components of wood preservatives in wood cell walls following vacuum treatment. Adsorption studies of copper on red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) wood confirm the importance of cation exchange reactions on the ultimate distribution of copper in the wood substance and i...
P A Cooper


Ammoniacal wood preservatives for use in non-pressure treatment of spruce and aspen poplar. Part 2
1984 - IRG/WP 3274
A series of thermal diffusion treatments were carried out on unseasoned white spruce (Picea glauca (Moench) Voss) lumber and air dry aspen poplar (Populus tremuloides Michx.) timbers using an ammoniacal copper arsenate wood preservative. Under the specific conditions described, certain charges of lumber met the present Canadian Standards Association Wood Preservation Committee's requireme...
C D Ralph, J K Shields


Stake test with ammoniacal copper in combination with different agents started in 1962
1997 - IRG/WP 97-30130
In 1962 a stake test was started with ammoniacal copper in combination with chromium, arsenic, pentachlorophenol, boron, salicylic acid, benzoic acid, sorbic acid, pyridine and tannin. Different concentrations of the copper component were used as well as the added agents. For each concentration and test site, ten stakes of Pinus sylvestris L. sapwood were treated. The stakes were set out at two te...
B Häger, Ö Bergman


Fungitoxic effect of the quaternary ammonium compounds wood preservatives against the Ascomycetes and Deuteromycetes
1997 - IRG/WP 97-30138
Results of investigation on fungitoxic value of the three formulations of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethylbenzylammonium bromide, alkylbenzyldimethylammonium chloride) in relation to the surface wood colouring (moulds) and soft-rot fungi have been presented. The agar-plate (screening) and agar-wood plate for mouldi...
J Wazny, P Rudniewski


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