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Silicic acid-Boric acid complexes as wood preservatives
2001 - IRG/WP 01-30273
A silicic acid monomer aqueous solution (SAMS) or colloidal silicic acid solution (CSAS) was combined with various metal compounds or boric acid. Agents where SAMS or CSAS was combined with boric acid gave good protection against decay caused by the brown-rot fungus Fomitopsis palustris, the treated wood (Cryptomera japonica D. Don) specimens after the leaching test maintained a high resistance to...
H Yamaguchi


A laboratory evaluation of tributyltin ethanesulphonate as an aqueous fungicide in wood preservation
1983 - IRG/WP 3229
Toxic limit data, using both leached and unleached wood test blocks, are reported for aqueous solutions of tributyltin ethanesulphonate against four Basidiomycete fungi, Poria placenta, Gloeophyllum trabeum, Coriolus versicolor and Coniophora puteana. An in situ study of the tributyltin compound in Scots pine and ponderosa pine sapwood has been carried out, using the technique of 119mSn Mössbauer...
R Hill, P J Smith, J N R Ruddick, K W Sweatman


Migration of chlorothalonil and carbendazim in fruits stored in wood treated with the anti-sapstain formulation Tuff Brite C
1997 - IRG/WP 97-50097
Fruits and vegetables stored in treated wood boxes are in contact with the products used for the treatment. In order to obtain regulatory approval for incidental food contact it is necessary to determine the quantity of residues on these fruits or vegetables. When the active materials are used in agriculture it is required that residues found are below to the MRL fixed for these substances. In the...
J F Cooper, D Riboul, M De Vleeschauwer, T L Woods


Effect of aqueous polymer treatments on wood properties. Part 2: Mechanical properties
1990 - IRG/WP 3611
Partially air-dried sapwood of sweetgum (Liquidambar styraciflua) and southern pine (Pinus spp.) was treated with either aqueous polyacrylate or aqueous dimethyloldihydroxyethyleneurea (DMDHEU) solutions. Tests for static bending, toughness, and hardness were conducted on matched treated and untreated pieces according to ASTM Standards. Properties of pine were not affected by treatment with the po...
Z Ashaari, H M Barnes, D E Lyon, R C Vasishth, D D Nicholas


The effect of aqueous leaching on moisture uptake by CCA-treated blocks during soil burial
1987 - IRG/WP 2283
Mass loss, moisture content and nitrogen data from two soil burial experiments with untreated and CCA-treated Scots pine (Pinus sylvestris L.), Sitka spruce (Picea sitchensis Carr) and lime (Tilia vulgaris Hayne) are presented. These show that aqueous leaching of CCA-treated wood prior to burial significantly reduces its subsequent moisture uptake from soil. In the case of lime, a reduction in the...
C A Green, G M Smith, B King


An anti-termite formulation for soil treatment with natural products and its efficacy against Coptotermes formosanus Shiraki
2003 - IRG/WP 03-30319
An anti-termite formulation of an environmental conservation type for soil treatment was developed. The formulation was composed of decanoic acid (n-capric acid, an fatty acid derived from coconut oil with ten carbons) as an active ingredient and other natural products. Experiments to examine the efficacy of the formulation against Coptotermes formosanus Shiraki were conducted at the termite field...
S Yoshida, T Nakagaki, A Igarashi, A Enoki


Decomposition of biocides in aqueous media cases of MTC and TCMTB
1993 - IRG/WP 93-50001-26
Our laboratory is interested in the fate of modern biocide molecules in the environment. Here we present recent work which has been done on the fate of two compounds with fungicidal and bactericidal properties: methylenedithiocyanate (MTC: NCS - CH2 - SCN) and thiocyanomethylthiobenzothiazol (TCMTB). We have studied separately the influence of pH, temperature and ultraviolet irradiation in aqueous...
R Perraud, M Papazian


Effect of aqueous polymer treatments on wood properties. Part 1: Treatability and dimensional stability
1990 - IRG/WP 3610
Partially air-dried sapwood of sweetgum (Liquidambar styraciflua) and southern pine (Pinus spp.) was treated with either aqueous polyacrylate or aqueous dimethyloldihydroxyethyleneurea (DMDHEU) solutions. Tests for dimensional stability were conducted on matched treated and untreated pieces. Measurement of the antishrink efficiency indicated that DMDHEU was a better stabilizer than the polyacrylat...
Z Ashaari, H M Barnes, R C Vasishth, D D Nicholas, D E Lyon


Effects of boron formulation on specific timber types used in ships of historical importance
1991 - IRG/WP 3676
This paper reports results of preservative treatment and leaching experiments, using borax, polybor and boracol 20, on small wood blocks of English oak and American pitch pine heartwood. Earlier experiments on the performance of various biocides as possible additives to bilgewater to prevent fungal decay of shipping timbers had suggested that some formulations of boron might be associated with phy...
B King, G M Smith, J W Palfreyman, S McCutcheon


Protection of wood for above ground application through modification with a fatty acid modified N-methylol/paraffin formulation
2007 - IRG/WP 07-40378
Hydrophobic chemical modification can be regarded as an alternative approach to conventional wood preservation using biocides in order to protect wood in hazard class 3 according the European Standard EN 335-1. A formulation containing fatty acid modified N-methylol/paraffin and an aluminium salt catalyst was used to change the material properties of wood in order to protect wood from fungal dec...
Nguyen Hong Minh, H Militz, C Mai


Amine Oxides for Use in Wood Protection: I. A Formulation Adjuvant and Performance Enhancer for Wood
2007 - IRG/WP 07-30425
Amine oxides have great potential for use in the area of wood protection. This paper highlights the advantages of using amine oxides as a formulation adjuvant and performance enhancer for different azoles. It was found that azoles are readily soluble in aqueous amine oxide solutions and form soluble concentrates. These azole/amine oxide concentrates have excellent storage stability and can be dilu...
Xiao Jiang, L Walker


The role of chromium in wood preservatives under BPD - a review and the current situation in Europe
2008 - IRG/WP 08-30468
Already during the IRG-meeting in Trømso a paper was presented to give an overview regarding the situation on chromium (JÜNGEL et al. 2006). Already in that year there was an increased attempt to achieve a science-based correct and harmonised solution in Europe regarding the chromium-question by the European Commission. Nevertheless the competent authorities (CAs) and the industry were similarly...
P Jüngel, S Hellkamp


Evaluation of formulation type on the efficacy of bifenthrin as a glueline termiticide for veneer based wood products
2010 - IRG/WP 10-40486
Field trials were carried out in Australia on Coptotermes acinaciformis to evaluate the efficacy of various bifenthrin formulations. One trial tested plywood made by Zelam at their research facility in New Zealand and compared three emulsifiable concentrate formulations (EC), a suspension concentrate (SC) and an encapsulated formulation (CS). A second trial compared laminated veneer lumber (LVL)...
P Lobb, A Siraa


Sorption properties of wood impregnated with aqueous solution of boric acid and montan wax emulsion
2010 - IRG/WP 10-40492
Non-biocidal techniques for wood protection become more and more important, nowadays. One of the possible treatments is use of water repellents. In the present research influence of, one of the possible water repellent, the montan wax emulsion, on the moisturizing and the sorption characteristic of impregnated wood was investigated. To achieve a better protection against wood decay fungi, montan w...
B Lesar, M Humar


Effects of intumescent formulation of vinyl acetate-based coating on flame-retardancy of thin painted red lauan (Parashorea spp.) plywood
2011 - IRG/WP 10-40537
Using intumescent coatings on wood-based materials is an effective method for fire safety. The intumescent coatings consist of four major components: (1) binder resin (BR), (2) carbonizing substance (CS), (3) foam producing substance (FPS) and (4) dehydrating agent (DA). Previous studies have demonstrated that the formulation of the four components strongly influences the performance of coatings. ...
Chih-Shen Chuang, Kuang-Chung Tsai, Te-Hsin Yang, Ming-Kuang Wang, Chun-Han Ko


The Effect of Water Repellent on Semi-Field Leaching of Active Substances from Metal Free Wood Preservative Formulation
2013 - IRG/WP 13-30615
The risk assessments for the use of wood preservatives proposed by the OECD and used under the Biocidal Products Directive (BPD) (98/8/EC) require the derivation of leaching rates for active substances. These rates are to be used as input data in to agreed exposure scenarios. A comparison of the leaching of active substances from wood treated with a metal free preservative formulation with and wit...
D G Cantrell


Dynamic mechanical analysis (DMA) of nano cupric oxide (CuO) modified aqueous phenol formaldehyde (PF) resin
2014 - IRG/WP 14-40654
Phenol formaldehyde (PF) resins, modified by nano CuO incorporating alkane surfactant and polyvinyl alcohol (PVA) 17-99, were analyzed by dynamic mechanical analysis (DMA). The mechanical properties of its bonded plywood including tensile strength, modulus of rupture (MOR), modulus of elasticity (MOE) and shear strength under five test conditions were evaluated. Results indicated that the incorpor...
Wei Gao, Guanben Du


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


The use of new, aqueous chemical wood modifications to improve the durability of wood-plastic composites
2017 - IRG/WP 17-40787
The wood flour used in wood-plastic composites (WPCs) can biologically deteriorate and thus the overall mechanical performance of WPCs decrease when exposed to moisture and fungal decay. Protecting the wood flour by chemical modification can improve the durability of the wood in a nontoxic way so it is not harmful to the environment. WPCs were made with modified wood flour and then evaluated for m...
R E Ibach, C M Clemons, G C Chen


Polyesterification of wood using sorbitol and citric acid under aqueous conditions
2018 - IRG/WP 18-40851
The aim of this research is to determine if the polyesterification of sorbitol and citric acid in wood has a future potential as a wood modification process. Pine wood was impregnated with an aqueous solution containing citric acid and sorbitol and was thereafter cured at 103, or 140°C for 18 hours. The dimensional stability and leaching resistance were studied for both modification temperatures....
E Larnøy, A Karaca, L R Gobakken, C A S Hill


A new approach to wood protection: Potential of biologically synthesised CuO and ZnO nanoparticle formulation as a wood preservative
2022 - IRG/WP 22-30758
Even though metal nanoparticles are effective in protecting wood, they are less preferred, as they are synthesised using methods which are expensive and are not environmentally friendly. Biological synthesis of nanoparticles using plants, fungi, yeast, bacteria and viruses, has been accepted as an alternative approach and is referred to as green synthesis. Utilization of biologically synthesised n...
Shiny K S, R Sundararaj, N Mamatha


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