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Chromated copper arsenate preservative treatment of hardwoods. Part 2: leaching performance of seven North American hardwoods
1997 - IRG/WP 97-30132
Seven North American hardwood species were treated with 2% CCA-C solution and fixed at temperatures of 21°C and 50°C and conditions of high relative humidity (95%) as described in Part 1 of this presentation. Red pine (Pinus resinosa) was included as a softwood for comparison. Adequately fixed wood blocks (99.9% chromium fixation) were exposed to leaching tests according to AWPA E11-87 test. Par...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Properties of particleboard made from recycled CCA-treated wood
2000 - IRG/WP 00-50146
Recovery of chromated copper arsenate (CCA)-treated wood for reuse ha s been the focus of several international research groups due to the imminent disposal problem created when large quantities of CCA-treated wood ultimately come out of service. Bioleaching with Bacillus licheniformis CC01 and oxalic acid extraction are two methods known to remove significant quantities of metals from CCA-treated...
C A Clausen, S N Kartal, J H Muehl


Comparison of the inhibitory effects of borate, germanate, tellurate, arsenite and arsenate on 6-phosphogluconate dehydrogenase
1991 - IRG/WP 1508
Sodium borate inhibits the enzymatic activity of many dehydrogenases, and it is thought that this is due to the complexation of the borate anion with the coenzyme nucleotide. It has been suggested in the past that complexation of this type, leading to enzyme inhibition and other biological effects, is responsible for the inhibition of fungal growth and consequently the protection of boron treated ...
J D Lloyd, D J Dickinson


Effect of treatment process on performance of copper-chrome-arsenate. Part 1: Fungus cellar tests
1995 - IRG/WP 95-40045
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation, fungus cellar stakelets, 5 x 10 x 180 mm³ were cut from treated material and after leaching were exposed in unsterile soil beds in ...
M E Hedley, J Anderson, J B Foster, B E Patterson


Management strategies for the disposal of CCA-treated wood
2000 - IRG/WP 00-50155
A two-fold management strategy is presented for the disposal of wood treated with chromated copper arsenate (CCA). The first part focuses on the use of alternative wood treatment preservatives. The second part of the management strategy addresses short-term disposal issues (less than 25 years) by developing new methods to handle the waste. A set of seven alternative wood preservatives were evaluat...
H M Solo-Gabriele, T G Townsend


After 18 years, preservative dipping and brush treating continue to provide protection to shingles of western wood species
1997 - IRG/WP 97-30156
The presence of residual preservation in dip-treated and brush-treated shingles of various species from the western United States was assessed 18 years after installation using Aspergillus bioassays. The performance of western redcedar (Thuja plicata) was compared to western hemlock (Tsuga heterophylla), sugar pine (Pinus lambertiana) and western larch (Larix occidentalis). Untreated shingles of a...
T C Scheffer, D J Miller, J J Morrell


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


The micro-distribution of copper/chrome/arsenate in Acer pseudoplatanus and Eucalyptus maculata
1973 - IRG/WP 319
The excellent field performance of copper-chrome-arsenate (CCA) treated timber has been accepted for many years. The preservative loadings used in practice have been based on field trial results, backed by service tests. The performance of treated hardwoods in trials and practice indicated that provided the required loading and penetration could be achieved the performance would be good. Recent un...
D J Dickinson


CCA removal from treated wood by chemical, mechanical and microbial processing
1998 - IRG/WP 98-50101-26
Most preservative-treated wood produced and consumed in the U.S. is treated with toxic inorganic compounds containing copper, chromium, and arsenic. Because chromated copper arsenate (CCA) is fixed to the wood, treated wood has not been considered toxic or hazardous and is currently landfilled. Increasing public concern about environmental contamination from treated wood combined with increasing q...
C A Clausen, R L Smith


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


Exclusion of anions from the wood cell wall
1991 - IRG/WP 3661
Anionic components of wood preservatives and fire retardants such, as arsenates and phosphates, equilibrate at much lower concentrations in the cell wall bound water than in the free solution in the cell lumens. A degree of anion exclusion is expected in wood, due to the Donnan membrane effect. Fixed anions in the wood cell wall, produced by pH-dependent dissociation of the weak acid groups in woo...
P A Cooper


Effect of soil chemistry and physical properties on wood preservative leaching
1998 - IRG/WP 98-50111
When treated wood is placed in contact with soil, complicated mass transfer and chemical reactions occur which causes the preservative components to leach from the wood. There are several factors that are known to affect the amount of chemical leached from wood. These are properties of the preservative and carrier, preservative retention, degree of fixation, exposure time, grain orientation, surfa...
Joan-Hao Wang, D D Nicholas, L S Sites, D E Pettry


Ecotoxicological effects of exposed CCA preservative treated wood in environments
2001 - IRG/WP 01-50173
For the evaluation of environmental effect of CCA treated wood exposd in the field, the simulated soil pot system of the laboratory was used. The effective components of preservatives were leached and determined after artificially conditioning a soil pot of CCA treated wood with more than 500mm water, the average monthly precipitation. As the water passed through the soil, As, Cr and Cu in the soi...
Dong-heub Lee, Dong-won Son


Environmental Impacts of CCA-Treated Wood: A Summary from Seven Years of Study Focusing on the U.S. Florida Environment
2003 - IRG/WP 03-50205
Wood treated with chromated copper arsenate (CCA) was identified in 1995 as the cause of elevated arsenic concentrations within wood fuel used for cogeneration within Florida. Since this time a research team from the University of Miami and University of Florida has evaluated the environmental impacts of CCA-treated wood within the State. Research has focused on two distinct areas: in-service l...
H M Solo-Gabriele, T G Townsend, J D Schert


Chromated copper arsenate preservative treatment of hardwoods. Part 1: CCA fixation performance of seven North american hardwoods
1997 - IRG/WP 97-30131
There has been an increased interest in utilisation of hardwoods from eastern North America for exterior applications which require protection with preservatives such as CCA. We have examined CCA fixation at two selected temperatures of seven common North American species: red maple (Acer rubrum L.,), white birch (Betula papyrifera ), yellow poplar (Liriodendron tulipifera L.), trembling aspen (Po...
T Stevanovic-Janezic, P A Cooper, Y T Ung


Long term marine performance of ACZA treated Hem fir in Krishnapatnam harbour, east coast of India
2006 - IRG/WP 06-30409
The performance of Hem fir (Tsuga heterophylla) and Southern pine (Pinus sp.) treated with ammoniacal copper zinc arsenate (ACZA) and copper dimethyldithio carbamate (CDDC) at two retention levels of each preservative was assessed in tropical marine waters at Krishnapatnam harbour on the east coast of India. Panels treated with ACZA of lower loadings (23.1 Kg/m3) had failed in 38 months while the ...
B Tarakanadha, K S Rao, J J Morrell


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Above and Below-Ground Copper-Azole and Copper, Chrome Arsenate Depletion from Pinus radiata and Fagus sylvatica at Thirteen New Zealand & Australian Sites
2008 - IRG/WP 08-30460
The objective was to determine the significance of site on preservative depletion from Pinus radiata D. Don and Fagus sylvatica L. 20 x 20 x 500 mm field test stakes treated with a ground contact retention of copper amine plus tebuconazole (CuAz) and copper chrome arsenate (CCA) after approximately 5 years exposure to widely different soil and climate conditions. Site, wood species and their inter...
R Wakeling


Thermochemical Remediation of Preservative-Treated Wood
2008 - IRG/WP 08-50254
Remediation methods continue to be developed and refined for CCA-treated wood in order to divert this material from landfills and create secondary products from the wood fiber. A two-step thermochemical remediation method was developed to assess the efficiency of metal removal from CCA-treated spruce flakes. Nearly all the metals (As, Cr, and Cu) were thermochemically extracted from chromated copp...
R Sabo, C A Clausen, J E Winandy


Comparison of laboratory and natural exposure leaching of copper from wood treated with three wood preservatives
2008 - IRG/WP 08-50258
Standard and non-standard laboratory and field leaching tests were used to compare copper leaching from wood treated to above ground and ground contact specified retentions for three wood preservative systems, CCA-C, ACQ-D and a micronized copper formulation with quat DDAC as co-biocide. Copper leaching was highest for the ACQ formulation. Percent leaching was lowest for the micronized copper sy...
P A Cooper, Y T Ung


Rapid Microwave-Assisted Acid Extraction of Metals from Chromated Copper Arsenate (CCA)-Treated Southern Pine Wood
2009 - IRG/WP 09-50262
The effects of acid concentration, reaction time, and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with three different acids (i.e., acetic acid, oxalic acid, and phosphoric acid) was investigated using in microwave reactor. Oxalic acid wa...
Bin Yu, Chung Y Hse, T F Shupe


Seasonal shifts of fungal community structure at the interface of treated or untreated wood and soil
2010 - IRG/WP 10-10721
Many wood species are degraded rapidly in soil by the fungal community. In order to preserve wood and structures in which it is used, chemical preservatives are used. Little is known about the interaction of treated wood and the surrounding soil fungal community. For this work, presented at IRG 41, wooden specimens (Pinus sylvestris sapwood, sizes 25 mm x 50 mm x 500 mm (longitudinal)) were treate...
M Noll, I Stephan


Microwave-Assisted Organic Acids Extraction of Chromate Copper Arsenate (CCA)-Treated Southern Pine
2010 - IRG/WP 10-50267
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of CCA-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from chromated copper arsenate (CCA)-treated southern pine wood samples with two different organic acids (i.e., acetic acid and oxalic acid) was investigated using a microwave reactor. Oxalic acid was e...
Bin Yu, Chung Y Hse, T F Shupe


Metal Migration from Douglas-fir Poles Treated with Ammoniacal Copper Zinc Arsenate According to Best Management Practices
2010 - IRG/WP 10-50272
The potential for migration of metal components from ammoniacal copper zinc arsenate treated (ACZA) poles was examined using pole sections treated using Best Management Practices. Copper and zinc levels were highest in runoff collected following the first rainfall events, then declined. Copper and zinc levels in runoff averaged 20 ppm and 5 pm respectively. The metal levels were then used to pr...
J J Morrell, C S Love, C Freitag


Incidence of soft rot attack on preservative treated Douglas-fir poles: a preliminary survey
2014 - IRG/WP 14-10818
Occurrence of soft rot decay in Douglas-fir poles treated with ammoniacal copper zinc arsenate (ACZA) or pentachlorophenol in oil was studied. Soft rot was less prevalent in poles treated with penta, but some soft rot was found in approximately 20 % of poles examined. Soft rot was more common in poles treated with ACZA, and, when present, was found in almost 20% of the cells examined. The potenti...
P Torres Andrade, J J Morrell


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