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Long term experiments for assessing the diffusion of boric acid and diluorides from local preservative pills in spruce and pine
1996 - IRG/WP 96-40065
For the experimental assessment of the diffusion of boric acid and difluorides over a three year period 2 tests were set up. In a test with large spruce blocks (150 x 150 x 300 mm³) 3 different pill types were exposed to 3 different climates: climate room (20°C, 65% r.h.), wet room (20°C, 95% r.h.), and to outside exposure. In a test with open L-joints without paint, with an alkyd paint and with an acrylic paint the same pill types were exposed outside, to the Dutch weather. From both tests it was concluded that the diffusion of difluorides is good under all circumstances and that differences in m.c. did not influence the diffusion to a large extent. The boric acid diffusion rate is much slower and very dependent upon m.c. In unglued samples with alkyd paint the highest m.c.'s were reached and thus the best diffusion.
W J Homan, H Militz


The lasting dehydration of wood treated by bifluorides worked up in Diffusec noticed by a continual drying of the wood
1999 - IRG/WP 99-30196
After an immersion of sound wood in a solution of Diffusec, in which a combination of acid potassium and ammonium bifluorides = FHF- in dissociated form is present, their potassium and ammonium fluoride ions together with the bifluoride ion = (FHF-) diffuse into the wood. They make use of the woodmoisture available as O-H-O bonds directly attached to the cellulose in the wood fibres to attract the dissociated ions, which after fusion are replaced by F-H-F bonds. If any substance that contains ions or centers of electric charge (from polar bonds) is brought into contact with water, sufficient electrical disturbance result in rupture of the hydrogen bonds. This means that the hydrogen bonds in water are readily broken. The released water dipoles are then attracted to these charge centers. Acid fluorides, as F- and FHF-, act permanently as F-H-F bonds upon OH groups of the cellulose. They are able to gather from the "watercoating" which surrounds the OH groups, so to speak thin layers which leave the wood in the form of vapour. Besides that they are able to occupy the vacant places. Near it watermolecules of the outer layers will easier release as those ones more directed inside. The uptake of the hydrogen in the air is dependent of the RH uptill air-dry wood is reached with the EMC belonging to it. No thermic intervention is necessary according to prof. dr. J. B. van Duijneveldt.
H F M Nijman


Synergistic effect of boron on Streptomyces rimosus metabolites in preventing conidial germination of sapstain and mold fungi
1992 - IRG/WP 92-1565
We evaluated the synergistic effect of boron (4% BAE solution of Tim-Bor or 4% boric acid) on Streptomyces rimosus metabolites in preventing spore germination of sapstain and mold fungi using plate bioassay, Southern yellow pine and sweetgum block tests, and green pine log sections: sapstain -- Ceratocystis coerulescens, Ceratocystis minor, and Aureobasidum pullulans; mold fungi -- Aspergillus niger, Penicillium spp, and Trichoderma spp. Inhibition of spore germination in plate bioassay by metabolites with boron was more effective than without added boron. Treatment of wood samples with the mixture of boron and unconcentrated metabolites also resulted in the synergistic effect and completely inhibited spore germination of sapstain and mold fungi.
S C Croan, T L Highley


Health aspects concerning the use of bifluorides in wood
1981 - IRG/WP 3173
An attempt has been made to find a correlation between the quantities F¯ and HF present among other ions in an 'Improsol' solution consisting of NH4F.HF and KF.HF, the quantity absorbed by the wood from this after immersion and the toxicological effects of this treated wood when it is used in rooms destined for the residence of people or animals or for the storage of foodstuffs.
H F M Nijman


A new concept of oxalic acid biosynthesis in physiology of copper-tolerant brown-rot fungi
2001 - IRG/WP 01-10394
Recently, a wide variety of roles of oxalic acid (oxalate) in wood decay systems have been receiving much attention. Copper tolerance of wood-rotting basidiomycetes has been believed to be due to the detoxification of copper wood preservatives by oxalate produced by these fungi. However, biochemical mechanism of oxalate biosynthesis in relation to physiology of wood-rotting fungi has not been elucidated although two oxalate-forming enzymes, oxaloacetase and glyoxylate dehydrogenase, have been studied in our laboratory. Recently, a new role of glyoxylate cycle in oxalate biosynthesis in wood- rotting fungi has been presented, and the cycle commonly occurred to varying extents among the fungi although they were grown on glucose. Enzymatic analyses showed that isocitrate was cleaved by isocitrate lyase in the glyoxylate cycle rather than oxidized by isocitrate dehydrogenase in tricarboxylic acid (TCA) cycle, and the fungi were found to lack a normal TCA cycle due to the absence of - ketoglutarate dehydrogenase. It is noteworthy that glucose was efficiently converted to oxalate in a theoretical yield of about 80%, accumulating in the culture media of F. palustris. The results further indicate that acetyl-CoA derived from glucose was not completely oxidized to CO2 in TCA cycle but was mainly converted to oxalate with help of the other coupling metabolic cycles, including glyoxylate cycle. Formation of oxalate from several intermediary metabolites using cell-free extracts of F. palustris confirmed that oxalate is also the final product of the metabolic pathway in the in vitro system. Thus, it is proposed as a new concept that most of copper-tolerant brown-rot fungi may acquire the energy by oxidizing glucose to oxalate, i.e. oxalate fermentation expressed in the following equation; Glucose + 5O2 --> 2 Oxalate + 2CO2 + 4H2O.
E Munir, T Hattori, M Shimada


Response of the Formosan Subterranean Termite (Coptotermes formosanus) to Cellulose Insulation Treated with Boric Acid in Choice and No-Choice Tests.
2004 - IRG/WP 04-10532
The tunneling ability of the Formosan subterranean termite Coptotermes formosanus Shiraki through a cellulose insulation material containing11.1% boric acid was tested in choice and no-choice bioassays. We examined tunneling behavior and mortality of termites exposed to treated and untreated insulation material in miniature simulated wall voids. In a choice test termites tunneled through untreated insulation in all but one of the replicates used. Termites were unable to fully penetrate any of the replicates containing treated insulation and experienced a significantly higher mortality (78.4 ± 18.4%) than termites exposed to untreated insulation (11.6 ± 5.6%, F = 60.4, df = 1, P < 0.0001). In a no- choice test termites fully penetrated all replicates containing untreated insulation and experienced 37.1 ± 37.2% mortality. Termites exposed to treated insulation in this test experienced a significantly higher mortality of 100.0% (F = 14.3, df = 1, P < 0.005), and did not fully penetrate the treated insulation.
M E Mankowski, J K Grace


Boron treatments for the preservation of wood - A review of efficacy data for fungi and termites
1994 - IRG/WP 94-30037
Boron treatments have been used for many decades for protection of timber from biological attack and also as a fire retardant treatment. In recent years there has been an increased interest in boron treatments as an option for protection of structural timbers&apos; e.g. timber framing used in termite risk areas. This paper reviews efficacy data for both fungi and termites relevant to this end-use.
J A Drysdale


Preliminary results of investigations on screening test of chemical compounds suitable for the preservation of lignocellulosic materials against biodeterioration
1976 - IRG/WP 262
This paper investigates the possibilities of reducing the time needed for the determination of the effectiveness of chemical compounds from the point of view of their eventual application to lignocellulosic materials for preservation against decay and soft-rot.
K Lutomski, S S Neyman


Patent on the use of tannic acid and ferric chloride against marine borers, etc
1982 - IRG/WP 495
R Mitchell, T D Sleeter


Comparative investigations on the influence of wood seasoning, wood properties and temperature on the toxic values of wood preservatives against Hylotrupes egg larvae
1970 - IRG/WP 28
Comparative tests carried out at three institutes indicated the influence of kiln temperature, position of wood specimens in the cross sectional area and test temperature on the toxic values determined in accordance with DIN 52165 with egg larvae of the house longhorn beetle (Hylotrupes bajulus L.). The preservatives applied were boric acid in distilled water and g-benzene-hexachloride dissolved in chloroform; the timber species used was pine sapwood, (Pinus sylvestris L.). The method of seasoning had no influence on the toxic values of boric acid. With the g-BHC, however, the toxic values gradually increased with rising kiln temperatures (20°C, 70°C, 105°C). With boric acid the position of the sapwood samples in the log had no influence on the toxic efficacy; with g-BHC the efficacy was slightly greater in the outer sapwood, compared with the inner sapwood. The test temperatures (20°C, 24°C, 28°C) yielded different toxicity results for boric acid. At 24°C and 28°C the threshold values were somewhat below those of 20°C; they agreed with the values obtained at 20°C after a longer test period. With g-BHC different temperatures did not affect the results. An explanation is suggested for the causes of the influence exerted by the kiln temperature and wood properties on the toxic values of g-BHC. There was good agreement between the toxic values obtained in the different institutes.
G Becker, T Hof, O Wälchli


Options for accelerated boron treatment: A practical review of alternatives
1985 - IRG/WP 3329
Boron wood preservatives are almost exclusively applied by momentary immersion and block diffusion storage. Alternative techniques are described which can be used to accelerate boron treatment. Diffusion coefficients have been derived to define the acceleration of diffusion with increasing temperature. Schedules are described for pressure impregnation of green timber, involving steam conditioning, evacuation and alternating pressure method treatment. Timber Preservation Authority penetration and retention requirements can be met in approximately 4-5 h. The optimum schedule, however, included a 12 hour holding period between steaming and preservative treatment. A method of applying boron preservatives as a vapour is described, Trimethyl borate vapour reacts with wood moisture to form boric acid. The kinetics of this reaction, however, are very fast. This limits treatment to timber dried to very low wood moisture contents.
P Vinden, T Fenton, K Nasheri


Movement of boron from fused boron rods implanted in Southern pine, Douglas fir, red oak, and white oak timbers
1995 - IRG/WP 95-30061
This paper reports the distribution of boron from fused boron rods installed into six-inch (15.2 cm) square timbers of Douglas-fir, Southern Pine, red oak and white oak exposed aboveground. The composition and size of rods was: sodium borate and sodium borate-copper oxide (8.5 x 100 mm²); sodium borate-copper, sodium borate and boric oxide-copper oxide (12 x 76 mm²). The boric acid equivalent was roughly monitored by the curcumin/salicylic acid color test and the presence of copper was detected by the chrome azurol-S reagent. One year after installation of rods, movement of boron was determined by application of curcumin dye to increment cores removed at various distances from the site of boron rod installation. A portion of a sodium borate treated Southern Pine timber was also analyzed by spraying curcumin dye on sawed longitudinal and transverse sections. At 2 years, one foot sections were removed from all timber species, sawed as above, and boron and copper detection reagent sprayed on the sawed surfaces. Movement of copper from rods in all timbers was virtually nil. Both transverse and longitudinal movement of boron from rods was greatest in Southern pine which also had the highest moisture content. Movement of boron was next best in red oak. There was little movement of boron away from the rods in white oak and Douglas-fir.
T L Highley, L Ferge


The influence of boric acid on respiratory quotients and methane production of subterranean termites
1995 - IRG/WP 95-10136
The toxicity of boron compounds to subterranean termites (Reticulitermes lucifugus) was studied by analysing changes in the levels of oxygen uptake respiratory quotients and methane production. Termites were fed with filter paper treated at different levels of boric acid, the RQ was evaluated by constant volume manometry and the methane production by gas chromatography. Results are discussed in relation to termite gut symbiontes.
L Nunes, D J Dickinson


A new approach to the maintenance problems of wooden railway sleepers
1986 - IRG/WP 3392
The microenvironment of wooden railway sleepers is being investigated to assess their condition to determine the necessary treatment, repair and replacement criteria. The research work involves the development of an integrity tester to determine the condition of sleepers, a remedial treatment of sleepers by selective application of boric acid and a synthetic repair system.
W Beauford, P I Morris.


Diffusion treatment plants (Latin America - Africa)
1974 - IRG/WP 333
B N Prasad


A field test with Benzotar, an industrial residue, as a wood preservative
1985 - IRG/WP 3349
Benzotar, a residue of production of benzoic acid, was tested in field as a wood preservative. Results, after 6.5 years of exposure, showed that this product presents properties that improve the performance of wood in ground contact. This paper describes these results and presents a discussion an some aspects of its potential utilization in Brazil.
S Milano, L R Silva


Testing of alkylammonium compounds
1981 - IRG/WP 2152
Following laboratory soil block tests which showed that Bardac 20 possessed a fungicidal threshold similar to that of chromated copper arsenate, treated ponderosa pine sapwood stakes were installed in a field test site near Vancouver, Canada. Two years after installation all the stakes show signs of fungal degradation. Seven stakes have been removed from the test due to total loss of strength after only two years, and many others are near failure due to extensive decay. It may be concluded from this study, that under the conditions of the test, Bardac 20 has failed to prevent wood-destroying fungi from decaying the stakes. Further investigation of treated "check" stakes and failed field tested stakes has revealed an uneven distribution of the chemical in some stakes treated to low retentions.
J N R Ruddick


Treatment of dried sawn spruce and redwood building timbers with water-borne preservatives under a scheme for the quality control of the preservation and preserved wood in the Netherlands
1978 - IRG/WP 3123
Treatment of dried sawn spruce and redwood Building Timbers with water-borne preservatives under a scheme for the quality control of the preservation and preserved wood in the Netherlands. The aim of this article is to give the reader a modest description of the evaluation of fundamental research in wood preservation into a practical application.
H F M Nijman, N Burgers


In-situ pressure injection for preservation of rubber wood (Hevea brasiliensis Muel Arg.)
1992 - IRG/WP 92-3688
Rubber wood is widely used for the manufacture of furniture, doors for housing and packing cases. However in an untreated condition it is highley susceptible to sapstain and decay fungi and borers. Its utility gets considerably reduced if the wood is not treated well in time. Preservative treatment has to be given within the period of felling and transport to prevent not only loss of structural properties and wood material. Although Boucherie, hot-cold bath diffusion, pressure impregnation, vacuum-pressure impregnation processes for treating timbers have been successfully employed for protection, but the process in cumbersome and difficult to adopt at the site of extraction. Hence, it was found necessary to evolve a simple and convenient method to treat trees in-Situ. A simple pressure injection technique was adopted to treat the standing tree using an instrument designed at the Institute (IWST). This instrument is easy to operate and inexpensive. It was observed that the movement of preservatives was satisfactory and effective. Samples of wood taken from treated stem of such trees were subjected to attack by brown and white rot fungi in the laboratory. It was observed that wood samples treated with Borax, boric acid and Bavistin (1:1:0.2); Borax, boric acid and Sodium pentachlorophenoxide (1:1.5:1) and Bavistin and Ekalux (0.5:0.5) showed higher resistance to fungi and insect attack compared to boric acid and Borax (1:1) in both laboratory and field conditions. Treated wood also retained natural colour and was free from fungal and insect attack for over 24 months in storage. Studies in this method of treatment of plantations species are in progress.
H S Ananthapadmanabha, V R Sivaramakrishnan


Localization of oxalate decarboxylase in the brown-rot fungus Postia placenta
1996 - IRG/WP 96-10161
Oxalate decarboxylase, the enzyme that breaks oxalic acid down into formic acid and carbon dioxide, was recently detected in mycelial extracts of the brown-rot fungus Postia placenta. Differential centrifugation was used to demonstrate that the enzyme is loosely associated with the hyphal surface. Enzyme activity can be removed by washing the hyphae with a low pH buffer. Only low levels of activity were detected in soluble and membrane-bound intracellular fractions. The presence of the enzyme on the hyphal surface and possibly in the hyphal sheath supports the hypothesis that this brown-rot fungus actively regulates the pH and oxalic acid concentration of its environment.
J A Micales


CCA fixation experiments. Part 2
1989 - IRG/WP 3505
CCA fixation in wood was measured by both squeezing solution from treated wood that had not been dried and analyzing the solution for copper, chromium and arsenic, as well as using a chromotropic acid test to detect the presence of chromium VI. Both methods provide useful information on the CCA fixation process and illustrate that chromium VI disappears as CCA becomes fixed within wood.
W S McNamara


First draft of a monographic card for Fomitopsis pinicola (Fr.) Karst
1980 - IRG/WP 196
P W Perrin


Ground contact performance of wood treated by the MSU process
1990 - IRG/WP 3609
Environmental concerns have prompted a renewed interest in accelerated fixation schemes for CCA-treated wood. Results from stake tests of southern pine (Pinus sp.) treated using a conventional Bethell cycle are compared with matched stakes treated using the MSU Process. The effects of adding boric acid to the preservative formulation are also discussed. Differences among test plots are discussed.
H M Barnes, T L Amburgey, R W Landers


Effect of fatty acid removal on treatability of Douglas-fir
1993 - IRG/WP 93-40008
Treatment of Douglas-fir with chromated-copper-arsenate (CCA) poses a major challenge. Several hypotheses based on the anatomical aspects as well as chemical reactivity of the preservative formulations with cell wall constituents and deposits have been proposed. Techniques to prevent pit aspiration or slow fixation reactions have, however, not significantly improved treatment. The presence of high molecular weight fatty acids have been reported to be responsible for higher hydrophobicity in some wood species. These acids can react with Cu+2/Cr+3 ions to form insoluble metallic soaps, thereby immobilizing Cu/Cr and increasing wood hydrophobicity by a mechanism similar to that employed in paper sizing. The effect of fatty acids on treatability was explored by removing these components via several extraction methods. In general, extracted wood had higher gross solution absorptions and chemical retentions, but preservative penetration was largely unaffected. The results suggest that removal or disruption of fatty acids can improve treatability of Douglas-fir heartwood.
S Kumar, J J Morrell


The formation of organotin carboxylates in bis(tributyltin) oxide - treated Pinus sylvestris sapwood
1990 - IRG/WP 3618
Tributyltin compounds have been successfully used for many years as wood preservatives, although their chemical nature in timber have not been fully elucidated. This study by 119Sn and 13C NMR spectroscopy has shown that, on impregnation into Pinus sylvestris sapwood, bis(tributyltin) oxide, (Bu3Sn)2O, is rapidly converted to tributyltin carboxylates, Bu3SnOCO·R, via reaction with components of the wood resin. It is further suggested that the formation of these species is a prerequisite for the known disproportionation reaction which occurs in (Bu3Sn)2O - treated timber.
S J Blunden, R Hill


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