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Remediation of CCA-treated wood by chitin and chitosan
2005 - IRG/WP 05-50229
Chitin and chitosan are naturally abundant biopolymers which are interest of to research concerning the sorption of metal ions since the amine and hydroxyl groups on their chemical structures act as chelation sites for metal ions. This study evaluated the removal of copper, chromium, and arsenic elements from chromated copper arsenate (CCA)-treated wood via biosorption by chitin and chitosan. Expo...
S N Kartal, Y Imamura


Termites in Uruguay; control, prevention and environment
1991 - IRG/WP 1474
When Prof. La Fage's questionaire on termites was received by 1987, few were aware of termite damage in Uruguay and infestations were not much reported. Further contacts between scientists, operators and homeowners, are now shaping the real threat of termite attack. Before letting the problem faIl in the hands of the layman, with all ist environmental risks, it seemed reasonable to: 1) re...
A Aber, G Baillod


Non leachability of arsenic, copper and chromium from 15 years old CCA-C treated southern pine poles used in brackish water as jetty piles in Bangladesh
1998 - IRG/WP 98-50103
Revealed that chromated copper arsenate type C (CCA-C) treated southern pine poles used in Central Warehouse Jetty of REB, Khulna are stable and resistant to chemical and biological attack without loss of any component from outer 0-12.5 mm zone after 15y of use. Slightly reduced retention (4.44% less) was noted in above water location of piles (bottom end of tree) which would be due to continuous ...
A K Lahiry


Notes on a wood preservation industry in Medan, North Sumatera, Indonesia
1987 - IRG/WP 3405
This paper deals with a descriptive account on the development of a wood preservation industry in Medan, North Sumatera (Indonesia). The industry was established in 1974 when the State Owned Electicity Corporation decided to use wooden power poles for their distribution network in North Sumatera province. However, the use of wooden power poles was discontinued in 1981, so as the preservation indus...
N Supriana, A Murad


The performance of metal-chromium-arsenic formulations after 32 to 38 years' in-ground exposure in Australia
2000 - IRG/WP 00-30240
Two trials of metal-chromium-arsenic preservatives were exposed in-ground in Australia. In Trial 1, Pinus radiata stakes treated with Boliden K.33, Boliden S.25, Celcure A, Tanalith C and Tanalith CA were installed at Sydney and Narrandera in 1961/1962. In Trial 2, P. radiata and Eucalyptus regnans sapwood were treated with Celcure A, Celcure A21-N, Celcure A 21-O and Tanalith CA (new) and install...
G C Johnson, J D Thornton, J Beesley


Preliminary PIXE micro-analysis of copper-chrome-arsenic preservative treated Malaysian hardwoods
1999 - IRG/WP 99-20169
The novel nuclear microscopy, essentially the Particle-induced X-ray Emission (PIXE) system, was applied for examining the macro-distribution and micro-analysis of copper-chrome-arsenic (CCA) preservative in Malaysian hardwoods Koompassia malaccensis, K. excelsa, Alstonia spp. and Dipterocarpus spp., and one temperate pinewood Pinus sylvestris, where the preservative retention differed between the...
A H H Wong, R B Pearce, G W Grime, F Watt


Recovery of copper chromium and arsenic from old CCA treated commodities
1998 - IRG/WP 98-50118
Due to the expected increase in spent treated wood over the next several decades, numerous means to reuse and recycle preserved wood have been proposed. Burning this wood for cogeneration or recycling of CCA treated wood into reconstituted composites are possible methods, but they are limited to laboratory scale because of environmental air emission issues and the manufacturing process. In the av...
D P Kamdem, Wanli Ma, Jun Zhang, J Zyskowski


Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines


Laboratory studies of CCA-C-leaching: influence of wood and soil properties on extent of arsenic and copper depletion
2002 - IRG/WP 02-50186
The extent which a wood preservative leaches is important for efficacy studies and environmental concerns. However, little information exists on the effect soil properties have on leaching. This study investigated leaching of stakelets which had been cut from five different southern yellow pine (SYP) sapwood boards then treated with CCA-C to a target retention of 6.4 kgm-3 (0.4 pcf). All stakel...
D Crawford, R F Fox, D P Kamden, S T Lebow, D D Nicholas, D Pettry, T Schultz, L Sites, R J Ziobro


Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden


Accelerated diffusion treatment of sawn Sitka spruce grown in the UK
1986 - IRG/WP 3395
The treatment of 'green' sapwood and heartwood of Sitka spruce by diffusion methods was investigated. Steam/dip treatment processes gave increased solution uptakes and depths of penetration of copper in comparison with a simple dip treatment. Further investigation is required to reduce diffusion gradients with copper based formulations and to improve the penetration of '...
R J Murphy, D J Dickinson


Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard


Remediation of a site contaminated with creosote and CCA - a case study
1998 - IRG/WP 98-50101-12
Over sixty years of wood preservation activity conducted by ImpregNor at Ilseng, Norway, has caused serious contamination of the soil. High concentrations of creosote have been found at two separate sites, one in connection to the creosote wood preservation plant, and one further downstream were residues from the creosote preservation have been deposited. High levels of chromium, copper and arseni...
T Rødsand, K Hellum, H Lillemaehlum


Do CCA treated support stakes cause increased arsenic level in crops?
2003 - IRG/WP 03-50204
Trial of using CCA-C treated eucalypts stakes for supporting banana plants in Guangdong Province, China, began in 1998 and later it was expanded as a demonstration program of a joint International Tropical Timber Organization–Chinese Government timber preservation project in 2000. The greatest concern was whether the crop would be contaminated by the preservatives, arsenic in particular. Data fr...
Li Zhaobang, Su Haitao, Liang Linqing


Leaching of arsenic, copper and chrome from preservative-treated timber in playground equipment
1984 - IRG/WP 3149
Samples were taken from CCA-treated timber in sand play boxes and other play ground equipment. Sand was also sampled. Sand and wood samples were analysed for copper, chrome and arsenic by AAS. About 20-25% of the arsenic had leached from the timber after 2-4 year's exposure in the playgrounds. Very little of the copper and chrome had been leached. Sand collected in the close vicinity of t...
B Henningsson, B Carlsson


Preliminary evaluation of the answers to the 2nd IRG/WP-questionnaire on the state of pollution control in the field of wood preservation
1982 - IRG/WP 3209
This preliminary evaluation of the answers to the 2nd IRG/WP-Questionnaire only gives a general survey on those questionnaires which the author received until April 30th, 1982. Details, such as correlations between importance of wood preservation and pollution control, as well as a comparison of the answers with those to the first questionnaire (Doc. IRG/WP/369), could not be considered due to lac...
H Willeitner


Soft rot fungi found in copper/chrome/arsenic treated hardwood power transmission poles in Queensland
1978 - IRG/WP 185
In Queensland the effective service life of copper/chrome/arsenic (CCA) treated hardwood telegraph and power transmission poles is being dramatically shortened due to attack by soft rot decay fungi. The Australian Wood Preservation and Pole Industries are funding research into this serious soft rot problem involving C.S.I.R.O. and the University of Queensland. The C.S.I.R.O. is actively engaged wi...
L E Leightley


Environmental consequences of various materials in utility poles - A life cycle analysis
1992 - IRG/WP 92-3726
A model for environmental life cycle analysis, LCA, has been created to compare environmental impact from transmission poles, made alternatively of concrete, steel, aluminium and pine wood treated with CCA type B or creosote. The main pollution sources and energy use are included in the LCA. One pole size, 12 meters long, is presented in the study, a so called "45 kV" pole. Poles of different mate...
M Erlandsson, K Ödeen, M-L Edlund


Intrigue Dust - A new method of eradicating subterranean termite (Isoptera: Rhinotermitidae) colonies
2001 - IRG/WP 01-10396
Arsenic trioxide is used by pest controllers in Australia to eradicate subterranean termite colonies. In 2000 Bayer Australia introduced Intrigue Termite Dust as a more environmentally acceptable alternative. Intrigue, containing 80% triflumuron, a chitin synthesis inhibitor, disrupts the moulting process in termites. Dusted termites return to the nest and pass around triflumuron via mutual groomi...
W Madden


Health and safety regulations on the use of wood preservatives in Switzerland
1980 - IRG/WP 3148
There is not any doubt that the chemical protection of wood (besides the architectional-constructional wood protection) is of utmost importance for the increase of the durability of technically used timber. The toxic properties of wood preservatives make certain legal regulations necessary for the protection of human beings, animals and the environment. Thereby wood preservatives fall under the po...
O Wälchli


Dutch work programme for environmental measures in wood preserving industry
1993 - IRG/WP 93-50001-30
Since the carly eighties, it has emerged that somewhat severe environmental problems exist in a significant number of wood-impregnating plants. Regular, structural emissions of such materials as hydrocarbons, and e.g. substances defined as requiring urgent attention, occur into the air, soil and water, including groundwater. This has been established by various investigations and an orientative in...
P Pasveer, H Militz, W J Homan


Fouling organisms as indicators of the environmental impact of marine preservative-treated wood
1995 - IRG/WP 95-50063
This study evaluates the use of fouling organisms (epibiota) to assess the environmental impact of preservative treated wood. This paper presents initial findings from treated panels exposed for 6 months at Sagres, Algarve, Portugal. Panels were treated with CCA, two copper-containing quaternary ammonium (ACQ) formulations and creosote, with nominal retentions from 10 to 40 kg/m³ (creosote 25 pcf...
R M Albuquerque, S M Cragg


Fouling assemblage development on copper-chromium-arsenic-treated timber submerged in European waters
2002 - IRG/WP 02-50181
The effect of the anti-marine-borer timber preservative CCA on community development of non-target marine fouling animals was investigated. Panels of Scots pine treated to target retentions of 12, 24 and 48 kg CCA per m3 of wood, plus untreated controls were submerged at seven coastal sites (Portsmouth, UK; La Tremblade (2 sites), France; Ria Formosa, Portugal; Sagres, Portugal; Kristineberg, Swed...
C Brown, R J Eaton, S M Cragg, P Goulletquer, A Nicolaidou, M J Bebianno, J Icely, G F Daniel, T Nilsson, A J Pitman, G Sawyer


Effect of compression wood on leaching of chromium, copper, and arsenic from CCA-C treated red pine (Pinus resinosa Ait.)
2000 - IRG/WP 00-30232
In this study, the effect of compression wood formation on the release rate of chromium, copper, and arsenic elements from red pine (Pinus resinosa Ait) was investigated. Wood blocks from red pine containing compression and normal wood portions were treated with a 1.0% CCA-C solution and were then allowed to fix at 23 ± ??2°C (74 ± 4°F) for 0, 6, 24, 48, 96, 192, and 336 hours. After each fixa...
S N Kartal, S T Lebow


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