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Studies on the mobility of arsenic, copper and chromium in CCA-contaminated soil
1990 - IRG/WP 3571
CCA contaminated soils from six Swedish preservation plants were investigated primarily to study the mobility of arsenic but also that of copper and chromium in the soils. The soil samples represented average types with different amounts of clay, organic matter, arsenic, copper, chromium and different pH. The total soluble amounts of the elements were measured. The pH dependent solubility and the ...
J Bergholm


The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs


Plant uptake of CCA components from contaminated soil
1995 - IRG/WP 95-50043
The above ground portions of lettuce and rye grass grown in CCA contaminated soil collected at the base of CCA-C treated poles in service did not absorb appreciable amounts of copper, chromium and arsenic, even at soil concentrations above the recommended levels for soil remediation for agricultural uses. At high soil arsenic levels whole radish plants absorbed more As, but not the other elements....
P A Cooper, E Jasonek, J-P Aucoin


Electrodialytic remediation of a soil from a wood preservation industry polluted by CCA
1998 - IRG/WP 98-50101-14
Soil contamination is often found at wood preservation sites due to spills, dripping of excess preservatives and deposition of sludge associated with dissolved salts of copper, chromium and arsenic (CCA). The electrodialytic process is a promising heavy metal soil remediation technique. It is based on a combination of the electrokinetic movement of ions in soil with the principle of electrodialysi...
A B Ribeiro, A Villumsen, G Bech-Nielsen, A Réfega, J Vieira e Silva


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


A Case Study of Long-term CCA Preservative Leaching from Treated Hardwood Poles in a Humid Tropical Condition
2016 - IRG/WP 16-50324
Chromated copper arsenate (CCA)-treated Malaysian hardwoods have long been used as utility poles, posts, construction piles and motorway fencing in soil contact exposed to the threats of decay fungi and termites. Despite global concerns citing predominantly temperate conditions of long-term leaching of CCA toxic heavy metals from wood into surrounding soils and groundwater since the 1990’s, the ...
A H H Wong, W S M Chin


CCA modifications and their effect on soft rot in hardwoods
1982 - IRG/WP 3201
Decay tests were carried out on wood samples treated with three waterborne compounds all identical in composition but applied in different forms. There were significant differences in the effectiveness of the treatments particularly as regards the control of soft rot....
S M Gray, D J Dickinson


Comparison of the agar-block and soil-block methods used for evaluation of fungitoxic value of QAC and CCA wood preservatives
1994 - IRG/WP 94-20039
The modyfied agar-block and soil-block methods were used for comparing the fungitoxic value of QAC and CCA type preservatives against Coniophora puteana and Coniophora olivacea The mass loss and moisture contents of wood were analysed....
J Wazny, L J Cookson


Cu, Cr and As distribution in soils adjacent to CCA treated utility poles in Eastern Black Sea Region of Turkey
2004 - IRG/WP 04-50214
In this study, the main objective was to asses the distribution of Cu, Cr, and As in soils adjacent to CCA treated utility poles in Eastern Blacksea Region of Turkey (Trabzon, Rize and Artvin ) and determine the influence of soil composition. Surface (0-5cm), subsurface soil samples (30-40cm) were collected near CCA-treated utility poles and control soil samples away from CCA-treated utility pole...
E D Gezer, Ü C Yildiz, A Temiz, S Yildiz, E Dizman


Discussion of diiodomethyl p-tolyl sulfone (Amical® 48) as a fungicide for wood preservatio
1987 - IRG/WP 3425
The effectiveness of diiodomethyl-p-tolyl sulfone (Amical® 48) as a fungicide for preservation of wood is supported by a discussion of results from the literature and current research programs....
J M Stamm, K J Littel, F M H Casati, M B Friedman


Some aspects of laboratory and field testing methods of antitermite wood preservatives
1973 - IRG/WP 235
Various methods for laboratory testing of antitermite activity of wood preservatives are described. The results of simultaneous tests of three water-borne preservatives, according to the various methods are discussed, and comparison is made with results of field tests on the same three preservatives, showing a fairly good accordance between laboratory results and field results....
M Fougerousse


Collaborative soft rot tests: Interim report on PRL tests of Cu/Cr/As preservative using method of Document No: IRG/WP/208
1972 - IRG/WP 211
Preservative: Tanalith CT.106 - Results obtained with beech are given in the table and indicate a toxic limit of 16.7-19.2 kg/m³ - The initial soil moisture content was adjusted to 27.8% (the water holding capacity). Noticeable drying out has occurred in some of the test bottles....
J G Savory


A preliminary study on the feasibility of substituting the soil culture medium in soil block tests
1984 - IRG/WP 2209
In this work the possibility was studied of substituting the soil culture medium in preservative screening methods. The conclusions are that another type of material, Sphagnum moss, can be used with advantages, but that some more information is still needed to give a real idea regarding the differences caused by the substrate tested....
J C Moreschi


Collaborative experiments in testing the toxicity of wood preservatives to soft rot fungi
1970 - IRG/WP 25
Eight Institutes from seven countries, Austria, England, France, Germany, Holland, Sweden and Switzerland have collaborated in an attempt to assess the suitability of various laboratory test procedures for acceptance as standard methods of determining the toxicity of wood preservatives to the cellulose-attacking micro-fungi which cause 'soft rot' of wood. Pure culture methods wit...
J G Savory, A F Bravery


Environmental impact of CCA poles in service
1997 - IRG/WP 97-50087
Soil samples from different depths and distances from CCA treated utility poles in Canada were analyzed for copper, chromium and arsenic content for a number of soil types, two wood species red pine (Pinus resinosa) and jack pine (P. banksiana) and different pole ages in service. A limited number of poles were equipped with water traps to collect rain water that dripped down the poles and where su...
P A Cooper, Y T Ung, J-P Aucoin


The Phase Out of CCA in the United States
2002 - IRG/WP 02-50194
In mid-February, 2002 the Administrator of the United States Environmental Protection Agency, Christine Todd Whitman, announced that the US treated wood industry will have until the end of December 2003 to end residential uses for Chromated Copper Arsenate (CCA). Industrial uses of CCA will still be allowed after the December 2003 date. This paper explores the events that led up to the announcem...
J D Schert


Inorganic wood preservative levels in soil near a noise barrier treated with different preservatives after 8 years in service
2005 - IRG/WP 05-50234
In March 1996 nine test sections of a noise barrier were installed near Stockholm Sweden. The test sections include untreated Scots pine, spruce and larch and Scots pine, treated with different wood preservatives. After 8 years in service, the untreated spruce, pine and larch boards in contact with the soil were significantly decayed, with an estimated service life of about 5-10 years, while the u...
P A Cooper, Y T Ung, M-L Edlund, J Jermer, O Söderström


Collaborative soft rot test: Amended test method
1972 - IRG/WP 208
The initial draft of a standard test method (Document IRG/WP/201) was discussed at the meeting in Brussels in 1971. It was agreed that a revised draft should be prepared and that the Princes Risborough Laboratory (formerly FPRL) should conduct a trial test using the method as a preliminary to the main collaborative test....
J G Savory


Proposal for further work on environmental questions
1988 - IRG/WP 3494
Although very much is known about the environmental and health and safety aspects on various wood preservatives and treated wood knowledge is still lacking on some important issues. Some examples are: - The fate of wood preservatives in the environment, eg by leaching from treated wood and contaminated soil; - How big is the "problem" of pollution, etc from the wood preserving industry in comparis...
J Jermer, M-L Edlund


Copper based water-borne preservatives: The biological performance of wood treated with various formulations
1987 - IRG/WP 3451
Wood samples treated with the various components of CCA preservative singly and in combination were tested against a soft rot organism, a copper tolerant brown rot organism and in soil burial both unleached and after leaching. The results suggest that, of the elements tested, fixed copper is essential for preventing soft rot attack and fixed arsenic is essential for preventing attack by a copper t...
S M Gray, D J Dickinson


A laboratory soil-block decay evaluation of plywoods edge-treated with preservatives
1982 - IRG/WP 2174
Preservative-treated plywood used under conditions or severe decay hazard frequently has its original, or cut edges, protected by the application of a field-cut preservative. This study uses a laboratory test method to compare the efficacy of four commercial preservative treatments against two commonly occurring brown-rot fungi. The results are not meant to indicate the service life of such treate...
R S Smith, A Byrne


Soil-bed studies (Part 3): A cause of failure of multisalt preservatives following soil-bed exposure
1983 - IRG/WP 3261
P Vinden, J F Levy, D J Dickinson


Protection of Ochroma pyramidale from fungal decay with N,N-napthaloylhyroxylamine
1998 - IRG/WP 98-30182
Fungal decay of wood in service results in billions of dollars (U.S.) in losses annually. Recent environmental restrictions, both U.S. and international, are limiting and eliminating the use of broad-spectrum, heavy metal biocides for wood preservation. Restrictions result primarily from problems with disposal. New wood preservatives need to be developed and tested which specifically target key el...
F Green III, T L Highley


Assessment of contamination of soil and water at a CCA treatment plant: A demonstration project
1996 - IRG/WP 96-50067
Soil, sludge, dust and water samples were collected at a copper/chromium/arsenic wood preservation plant. Contamination of soil, sludge, dust and surface water with copper, chromium and arsenic was detected. Levels of contamination were sufficiently high to require remediation. Contamination originated from preservative solution dripping from recently treated wood. Migration of contaminants was vi...
P N Durrant, D C R Sinclair, G M Smith


Results of collaborative work on laboratory soft rot testing
1989 - IRG/WP 2341
S M Gray, D J Dickinson


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