IRG Documents Database and Compendium


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The use of chlorothalonil for protection against mold and sapstain fungi. Part 1: Laboratory evaluation
1989 - IRG/WP 3515
Laboratory screening of chlorothalonil alone and in combination with other fungicides was conducted against six mold and sapstain fungi. The most promising treatments appear to be chlorothalonil supplemented with CCA or copper-8-quinolinolate. Field tests have been implemented....
J A Micales, T L Highley, A L Richter


Assessment of contamination of soil and water at a CCA treatment plant: A demonstration project
1996 - IRG/WP 96-50067
Soil, sludge, dust and water samples were collected at a copper/chromium/arsenic wood preservation plant. Contamination of soil, sludge, dust and surface water with copper, chromium and arsenic was detected. Levels of contamination were sufficiently high to require remediation. Contamination originated from preservative solution dripping from recently treated wood. Migration of contaminants was vi...
P N Durrant, D C R Sinclair, G M Smith


X-ray analysis of selected anatomical structures in copper/chrome/arsenic treated wood
1973 - IRG/WP 320
Application of analytical electron microscopy to problems in wood preservation has been very limited. Indeed, less than ten workers appear to have published their results using the technique, and of these' only two papers deal with energy dispersion procedures in the scanning electron microscope; the others employ the more familiar wavelength dispersive methods of the electron probe....
H Greaves


The effective control of moulds on freshly impregnated wood
2004 - IRG/WP 04-30352
Beside natural timber it is known, that moulds can also groth at the surface of impregnated wood. This material shows “defects” like resistant dark spots or color changes and causes complaints. During the last years, the problem by moulds seems to increase. Laboratory studies were carried out to show the effect of impregnations against moulds. Wood samples (Pinus sylvestris L.) were impregn...
G Cofta, K Lutomski, P Jüngel


Soil-bed studies (Part 3): A cause of failure of multisalt preservatives following soil-bed exposure
1983 - IRG/WP 3261
P Vinden, J F Levy, D J Dickinson


Literature survey on the permanence and distribution of salt-type wood preservatives
1969 - IRG/WP III 1B
The objective of this survey is generally to review some of the more important published work dealing with the distribution and permanence of salt-type waterborne wood preservatives in treated timber. The survey is limited to the major chrome-containing formulations and the classification system proposed by Becker (1964) has been adopted throughout. CK - chromium, copper (copper, chrome); CKA - c...
Anonymous


Migration of Metals from Douglas-fir Lumber Treated with ACZA or Pentachlorophenol Using Best Management Practices: Preliminary Tests
2005 - IRG/WP 05-50224-4
The potential for migration of preservative components from ammoniacal copper zinc arsenate (ACZA) and pentachlorophenol treated Douglas-fir lumber in non-soil contact exposure was assessed in a simulated rainfall device. Metal levels from ACZA treated wood were elevated for the first 30 minutes of rainfall and then declined sharply. Repeated cycles of rainfall led to declines in initial metal l...
J J Morrell, Hua Chen, J Simonsen


Rapid leaching test
1991 - IRG/WP 2367
An accelerated test which is suitable for measuring the extent of metal fixation in both chromium and non chromium containing preservatives is described....
J A Cornfield, M Bacon, A Lyman, C Waldie, M R Gayles


A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


Fungi associated with groundline soft rot decay in copper/chrome/arsenic treated heartwood utility poles of Malaysian hardwoods
1992 - IRG/WP 92-1567
Copper-chrome-arsenic treated heartwood from Malaysian hardwood utility poles in service for 8-23 y at two localities in the wet tropical Peninsula Malaysia were surveyed for soft rot in the ground-contact region. Soft rot decay was detected in all the poles. Isolation studies indicated the ability of a variety of microfungi and basidiomycetes to colonize treated heartwood. Most isolates exhibited...
A H H Wong, R B Pearce, S C Watkinson


Water-borne preservative marine trials in Western Canada
1981 - IRG/WP 470
Red pine boards treated with chromated copper arsenate, ammoniacal copper arsenate, copper zinc arsenic additive, a modified ammoniacal copper arsenate, and zinc arsenic additive, have been installed in a marine field test at West Vancouver, British Columbia. After two and a quarter years exposure, all the test samples are in excellent condition with the exception of those treated with the zinc ar...
J N R Ruddick


Copper binding capacity of modified wood flour
1992 - IRG/WP 92-3709
Wood flour was modified by reaction with oxidising agents and CCA preservative. The copper chromium and arsenic were removed from the CCA treated wood flour by an acid leaching procedure. The modified wood flours were allowed to react with copper acetate solution and the level of copper fixation achieved was determined. The modified wood flours had greater affinity for copper ions present in solut...
N C Milowych, W B Banks, J A Cornfield


Disposal of CCA treated waste wood by combustion - An industrial scale trial
1996 - IRG/WP 96-50068
Totally 272 m³ (62.7 t) of CCA treated utility poles were chipped and incinerated at Jalasjärvi Gasification Plant. In average the whole batch of chips contained 57 kg of elementary copper, 95 kg chromium and 76 kg arsenic. During the 56 h combustion trial the measured arsenic emission to the air was 76 g in total. Copper and chromium emission was less than 1 g. The condensing water from the coo...
A J Nurmi


Recycling of impregnated timber: Part 2: Combustion trial
1999 - IRG/WP 99-50132
Totally 270 m3 (61,3 t) of CCA impregnated wood was chipped and incinerated at the combustion plant of Jalasjärvi. After the normal gas cleaning venture scrubbers were tested. After the trial a metal balance was calculated. Ash was treated at the copper smelter of Outokumpu Harjavalta Metals Oy. Condensate waters were transfered to the Outokumpu's CCA production plant and utilized by the...
L Lindroos


Water-borne wood preservatives against marine borers. Results from NWPC marine trials started in 1972 and 1976
1990 - IRG/WP 4162
The paper presents the results from NWPC (Nordic Wood Preservation Council) marine trials started in 1972 and 1976. The trials are carried out according to the NWPC Standard No. 1.4.2.2./73 "Marine test - a test against marine wood boring organisms in sea water". The test site is Kristineberg Marine Biology Station on the west coast of Sweden. The wood blocks used in the trials were made from sapw...
Ö Bergman, C Lundberg


Copper based water-borne preservatives: The use of a thin section technique to compare the protection of wood by copper based preservatives against soft-rot and bacterial decay
1987 - IRG/WP 2286
This paper describes the techniques developed and gives examples of results obtained for the performance of copper based wood preservatives against both the bacterial and fungal hazards....
A M Wyles, D J Dickinson


Comparison of the effect of different soil sources on the type and rate of decay of CCA-treated pine exposed in a soil-bed
1984 - IRG/WP 2213
The types of decay observed in CCA-treated pine posts in horticultural situations in New Zealand can be reproduced using a soil-bed exposure. Radiata pine stakelets, untreated or treated to 1.4, 2.7, or 5.4 kg/m³ with Tanalith NCA, were exposed to six different soil sources. The local nursery soil used for all standard laboratory tests was found to represent the greatest decay hazard to untreated...
J A Drysdale


Marine performance of preservative treated Southern pine panels. Part 2: Exposure at Mourilyan Harbour, Queensland, Australia
2000 - IRG/WP 00-10337
Southern yellow pine panels treated with ACQ type B, ACQ type A, CCA type C, creosote, and copper naphthenate have been exposed at Mourilyan Harbour, north Queensland, Australia for almost 6 years. These panels have been inspected and rated for fouling and attack by Teredinid, Limnoria, Martesia, and Sphaeroma during this exposure. After 70 months exposure, overall performance of ACQ type B was eq...
A R Zahora, A F Preston, K J Archer, S Kleinschmidt


Leaching of copper, chromium and arsenic from CCA-treated slash pine heartwood
1994 - IRG/WP 94-50020
Drying green slash pine with any of three high temperature drying schedules produced a product in which both the sapwood and the heartwood could be penetrated with CCA using a modified Bethell treatment schedule. Required H3 retentions were achieved in both sapwood and heartwood, from 200 litres per m³ charge uptake. Post-treatment fixation/drying was accomplished by three different regimes, incl...
M J Kennedy, G Palmer


In-ground evaluation of a copper azole wood preservative (Tanalithâ E) at a tropical Australian test site
1996 - IRG/WP 96-30100
A field trial to determine the in-ground termite and decay resistance of Pinus radiata D. Don impregnated with a copper azole formulation, TANALITHâ E, has been established at a tropical site in the Northern Territory of Australia. Four retentions of TANALITHâ E, containing 1.54, 2.08, 2.92 and 4.30 kg/m³ of Cu, are being evaluated. For comparison, Pinus radiata specimens treated to two retenti...
J W Creffield, J A Drysdale, N Chew


The course of fixation of Cu-Cr-As wood preservatives
1972 - IRG/WP 307
Copper-chrome-arsenic (CCA) preservatives in contact with wood result in an instant extensive increase of pH, because of ion-exchange and adsorption reactions with the wood. During precipitation of the active elements the pH continuously increases but reaches a maximum, when all chrome is consumed. Some of the early reaction products are unstable and slowly convert via dissolution into stable comp...
S-E Dahlgren


Chemical analyses of IRG/COIPM INTERNATIONAL MARINE TEST (to determine the effect of timber substrate on the effectiveness of water-borne salt preservatives in sea-water) samples
1987 - IRG/WP 4114
Chemical analysis of CCA and CCB treated timber was carried out after exposure at tropical and temperate marine sites. Results indicated that losses of all elements had occurred. In particular, losses of boron were severe. Arsenic and copper were also lost. The chromium components in both formulations was the most dominant metal remaining. The results suggest that chromium modification was importa...
L E Leightley


Soft rot decay of Eucalyptus maculata Hook. in different soils from Queensland, Australia
1980 - IRG/WP 1113
In the present work, different Queensland soils were chosen and their gross effects on the decay of treated and untreated Eucalyptus maculata examined. The soils were also amended with various levels of phosphate to study the response of the wood decay mycota to an increasing supply of this nutrient. Phosphate amendment was chosen because of the wide-scale use of superphosphate on Queensland soils...
L E Leightley, I W Russell


Retention and distribution of copper/chrome/arsenic (CCA) in pressurised sap-displaced UK grown spruce and pine
1986 - IRG/WP 3366
Increment cores were taken from UK grown Scots pine (Pinus sylvestris L.), Corsican pine (Pinus nigra var. maritima Ait), Sitka Spruce (Picea sitchensis (Bong) Carr), and Norway spruce (Picea abies (L) Karst) distribution poles treated by pressurised sap-displacement using a 1.8% copper, chrome, arsenic (CCA) solution. Each increment core was sectioned radially and the copper, chrome, and arsenic ...
P D Evans, G M Smith, B King


The volatilization of arsenic on burning copper-chrome-arsenic (CCA) treated wood
1978 - IRG/WP 3111
Small scale burning experiments are described involving copper-chrome-arsenic treated wood. Approximately 20 per cent of the arsenic was volatilised when the wood was burned in air but 60 per cent when burned in an oxygen-enriched atmosphere, this increase is attributed to an increase in combustion temperature. Although a small increase in arsenic evolution was found with an increased concentratio...
A-J Dobbs, C Grant


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