IRG Documents Database and Compendium


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Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Field evaluation of CCA movement in sap-displaced copper chrome arsenic treated softwood poles
1989 - IRG/WP 3539
Commercial sap-displaced UK grown Scots and Corsican pine, and Sitka and Norway spruce poles were exposed in a field site at Dundee, Scotland and radial distribution profiles of CCA monitored prior to implantation and after subsequent field exposure. Results show that groundline levels of all preservative elements were higher after 1 and 2 years field exposure compared with those recorded prior to...
S D Hainey, G M Smith, A Bruce, P D Evans, B King, H J Staines


Microwave digestion of preserved wood for the determination of Cu, Cr, As, B and P in quality control
1991 - IRG/WP 2364
A microwave digestion method for the determination of copper, chromium, arsenic, boron and phosphorus in preserved woods is described. Samples were digested with nitric acid in pressure-relief type teflon PFA vessels by microwave heating in a commercial laboratory microwave oven. Fast, efficient and complete digestion was achieved within 29 min for 12 samples. The digestion time compared favourabl...
N Bernth, L B Sheard


Leaching of arsenic, copper and chrome from preservative-treated timber in playground equipment
1984 - IRG/WP 3149
Samples were taken from CCA-treated timber in sand play boxes and other play ground equipment. Sand was also sampled. Sand and wood samples were analysed for copper, chrome and arsenic by AAS. About 20-25% of the arsenic had leached from the timber after 2-4 year's exposure in the playgrounds. Very little of the copper and chrome had been leached. Sand collected in the close vicinity of t...
B Henningsson, B Carlsson


Soft rot fungi found in copper/chrome/arsenic treated hardwood power transmission poles in Queensland
1978 - IRG/WP 185
In Queensland the effective service life of copper/chrome/arsenic (CCA) treated hardwood telegraph and power transmission poles is being dramatically shortened due to attack by soft rot decay fungi. The Australian Wood Preservation and Pole Industries are funding research into this serious soft rot problem involving C.S.I.R.O. and the University of Queensland. The C.S.I.R.O. is actively engaged wi...
L E Leightley


Performance of copper-chrome formulations in ground contact in five test sites in New Zealand
1996 - IRG/WP 96-30113
Copper-chrome-arsenate (CCA), copper-chrome-boron (CCB), copper-chrome-fluoride (CCF) and copper-chrome-phosphate (CCP) have been tested at four retentions each in ground contact (25 x 50 x 500 mm³ radiata pine sapwood stakes) for 16 years in five test sites in New Zealand. Results to date show that test site characteristics have a marked effect on relative performance. In a warm and wet site (an...
M E Hedley, R N Wakeling, J Foster, B E Patterson


A technical note on the limitations of atomic absorption spectrophotometric analysis of copper/chrome/arsenic solutions according to BS 4072 (1974) and BS 5666: Part 3 (1979)
1988 - IRG/WP 2320
British Standards BS 4072 (1974) and BS 5666: Part 3 (1979) detail an atomic absorption spectrophotometric method for the quantitative determination of copper, chrome and arsenic in both preservative solutions and treated timber. Use of this technique during a research programme at Aberdeen has highlighted some potential inaccuracies with this method if these standard specifications are adhered to...
A J Pendlebury, J A Petty


Performance of groundline bandage remedial treatments in western US species transmission poles
1993 - IRG/WP 93-30019
Groundline bandages are an important element in remedial treatment strategies for utility poles in the United States. Several bandages containing new or reformulated components have recently been developed but have not been adequately tested. This paper reports on the degree of diffusion of copper naphthenate, boron, and sodium fluoride from groundline bandages into pressuretreated Douglas-fir, po...
P G Forsyth, J J Morrell


Effect of treatment process on performance of copper-chrome-arsenate. Part 1: Fungus cellar tests
1995 - IRG/WP 95-40045
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation, fungus cellar stakelets, 5 x 10 x 180 mm³ were cut from treated material and after leaching were exposed in unsterile soil beds in ...
M E Hedley, J Anderson, J B Foster, B E Patterson


The growth and metal content of plants grown in soil contaminated by a copper/chrome/arsenic wood preservative
1977 - IRG/WP 3110
Salts of copper, chromium and arsenic are used together in water soluble formulations for the preservation of wood against insect and fungal attack. Copper/chrome/arsenic (CCA) preservatives are of proven efficacy and, used correctly, ensure a useful service life for timber for 30 years or more with little, if any, attendant threat to the environment from the treated wood itself. The preservative ...
C Grant, A J Dobbs


On the use of probit analysis for assessing the toxicity of wood preservatives
1974 - IRG/WP 244
To elucidate the general character of the action of the toxic material on the fungus, it is sufficient to carry out preservative tests using the previously described procedure, but in doing so, it is necessary somewhat to change the number of specimens and their arrangement in jars. Five concentrations of toxic material are tested simultaneously. For the testing of one preservative ten jars should...
D A Belenkov


Leaching of copper-chrome-arsenic treated timber: Simulated rainfall testing
1996 - IRG/WP 96-50074
Six kiln dried radiata pine sapwood packs of timber were preservative treated with copper-chrome-arsenic preservative using a modified Bethell treatment schedule. The packs were then subjected to simulated rain leaching at specified periods after treatment. Higher chromium leachate was obtained when higher volumes of simulated rainfall were applied. Lower chromium leachate was obtained for timber ...
S Walley, P R S Cobham, P Vinden


Microwave modification of Yellow Stringybark (Eucalyptus Muelleriana) posts for impregnation with Copper-Chrom-Arsenic (CCA) preservatives
2000 - IRG/WP 00-40185
Yellow Stringybark posts with diameters ranging from 60-100 mm were microwave conditioned using a 60 kW microwave (MW) generator. A substantial improvement in heartwood penetration of preservatives and relaxation of growth stresses was indicated such that there was no split formation following drying of the posts. High preservative absorption of copper-chrome-arsenic (CCA) was achieved ranging fro...
G Torgovnikov, P Vinden


Investigation of copper fixation in timber by sodium nitrit
1992 - IRG/WP 92-3707
Solutions containing mixtures of water soluble copper salts and sodium nitrite have been shown to be capable of producing leach resistant copper treatments when impregnated into timber. A rapid leaching trial showed that copper fixation levels of 85-90% were possible which compared well with the fixation level obtained with conventional hexavelant chromium containing systems in the same test regim...
C Waldie, J A Cornfield


Soft rot test of copper/chrome/arsenic treated heartwood of three Malaysian timbers by the vermiculite-burial method. (+ correction document of 25 July 1990)
1990 - IRG/WP 2354
Heartwood of copper-chrome-arsenic (CCA) treated kempas (Koompassia malaccensis), tualang (Koompassia excelsa) and keruing (Dipterocarpus spec.) was found to be susceptible to soft rot in recent pole surveys. Standardized heartwood blocks were impregnated with 0 to 6.3% (w/v) CCA and challenged to decay for twelve weeks by a mixed inocula of Chaetomium globosum, Glenospora graphii, Humicula grisea...
R-D Peek, A H H Wong


The effect of copper/chrome/arsenic (CCA) treated timber on soil fungi
1981 - IRG/WP 1131
The aim of this investigation was to study the effect of CCA treated wood on the microflora of soil with particular reference to copper tolerant soft rot fungi. The IRG collaborative field experiment was designed to monitor the performance of a range of preservative treated hardwoods with particular reference to soft rot in CCA treated timber (Dickinson 1976) and site 33 of this experiment was use...
R J Murphy, D J Dickinson


Surface checking of CCA-treated radiata pine decking timber exposed to natural weathering
2000 - IRG/WP 00-40165
A field trial was established at four locations in Australia to assess the effect of CCA and CCA-wax treatment on the checking (cracking) of radiata pine decking timber exposed to natural weathering. Untreated decking timber and timber that had been pressure treated with water acted as controls. After 1 year's exposure the number and sizes of checks occurring in treated timber and control...
P D Evans, P J Beutel, C F Donnelly, R B Cunningham


Studies in an accelerated soil bed facility on the decay susceptibility of U.K. grown spruce and pine poles treated with copper/chrome/arsenic (CCA) by pressurised sap-displacement. Part 1: Setting up of soil beds and initial soft rot results
1990 - IRG/WP 2344
The paper describes the methodology used in the construction and early operation of an accelerated soil bed facility used to examine the decay susceptibility of U.K. grown Scots and Corsican pine and Sitka and Norway spruce treated with C.C.A. by high pressure sap-displacememt. The design and control of the facility as well as the preparation, soil exposure and soft rot decay analysis of quarter p...
A Bruce, S D Hainey, G M Smith, B King, P D Evans


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


Performance of Copper-Chrome-Arsenic (CCA) and Copper-Chrome-Boric (CCB) treated panels of Bombax ceiba and Paraserianthus falcataria against bio-deterioration at Krishnapatnam harbour, east coast of India
2003 - IRG/WP 03-30310
Results of investigations on the durability of light weight timber species (Specific gravity below 0.4) i.e., Bombax ceiba and Paraserianthus falcataria in treated and untreated condition conducted at Krishnapatnam harbour (Lat 13o28’ to 13o59’ N; Long: 80o10’ to 80o16’E) along the east coast of India are reported in the paper. Exposure trails were conducted with panels (Size: 30 x 3.8 x...
B Tarakanadha, N R Raveendra Prasad, K S Rao


An audit of copper chrome arsenic timber treatment plants throughout Queensland
1995 - IRG/WP 95-50047
Thirty seven copper chrome arsenic (CCA) timber treatment plants in Queensland were assessed according to the operational criteria specified in Australian Standard 2843.2 - 1985, Timber Preservation Safety Code - Plant Operation. The criteria have been designed to provide information on the design and operational activities of a CCA plant. Design aspects that have an effect on the environment are ...
J Norton


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


The present status of wooden catamarans of the Indian Coast
1997 - IRG/WP 97-10231
Catamarans (a.k.a. kattumarams) are the most widely used fishing craft in India, and hundreds of thousands of poor, traditional fishermen depend on these vessels for their livelihood that are almost made entirely of wood. In recent years, acute shortages and phenomenal increases in prices of timber species used in catamaran fabrication have been reported, causing great hardship to the user communi...
K S Rao


The micro-distribution of copper/chrome/arsenate in Acer pseudoplatanus and Eucalyptus maculata
1973 - IRG/WP 319
The excellent field performance of copper-chrome-arsenate (CCA) treated timber has been accepted for many years. The preservative loadings used in practice have been based on field trial results, backed by service tests. The performance of treated hardwoods in trials and practice indicated that provided the required loading and penetration could be achieved the performance would be good. Recent un...
D J Dickinson


The effects of pH on leaching of copper-chrome-arsenate (CCA) from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii: Initial findings.
2002 - IRG/WP 02-30298
The effects of pH on leaching of CCA from pressure-treated Kenyan-grown Eucalyptus saligna and Acacia mearnsii were tested under laboratory conditions. Small samples of the two species (100mm x 30mm x 40mm) were smooth sawn from 8-year old trees to represent equal amounts of both sapwood and heartwood, air-dried to 12% moisture content, end-sealed, and pressure-treated at a commercial treatment p...
R Venkatasamy


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