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Effects of hard water, sea water and humic acid on the release of CCA components from treated wood
2005 - IRG/WP 05-50228
Leaching medium is an important factor affecting release of preservative components from treated wood because physical and chemical characteristics of medium increase or decrease the solubility of fixed preservative components. This study evaluated the leaching properties of copper, chromium and arsenic elements from chromated copper arsenate (CCA)-treated wood specimens subjected to laboratory le...
S N Kartal, W J Hwang, Y Imamura


Wood preservation sites polluted by CCA. Is potassium diphosphate incubation a catalyst for the electrodialytic remediation of these soils?
1998 - IRG/WP 98-50106
As part of an evaluation of a newly developed electrodialytic soil remediation technique, we investigated the incubation of a contaminated soil (from a Portuguese wood preservation site polluted with CCA) with potassium diphosphate as a possible catalyst for the removal of heavy metals and metalloids. A chemical sequential extraction scheme (SE) applied to the soil has shown that the potassium dip...
A B Ribeiro, G Bech-Nielsen, A Villumsen, A Réfega, J Vieira e Silva


Above and Below-Ground Depletion of Copper, Chromium and Arsenic from Pinus radiata and Fagus sylvatica at Thirteen Test Sites in New Zealand and Australia
2006 - IRG/WP 06-30402
The objective was to determine the significance of site and wood species on preservative depletion for a copper chrome arsenate preservative (CCA) from 20 x 20 x 500 mm field test stakes after 5.5 and 4.5 years for pine and beech respectively. At least 5 sacrificial stakes were used to produce site means. Site and wood species had a major effect on copper, chromium and arsenic loss from CCA treate...
R Wakeling


Leaching of CCA from Paraserianthus falcataria panels exposed to field conditions at Krishnapatnam harbour, Andhra Pradesh
2006 - IRG/WP 06-50241
This study assessed the leaching of copper, chrome and arsenic (CCA) from Paraserianthus falcataria (=Albizia falcataria) panels exposed to marine condition at Krishnapatnam harbour on the east coast of India. Metal loss was assessed in test panels after 6, 12, 24 and 36 months of exposure using Atomic Absorption spectrophotometer (AAS). The metal loss was found slightly higher in panels treated ...
B Tarakanadha, K S Rao


Durability of timber from exotic species against termite attack in Indian conditions
2007 - IRG/WP 07-10629
Exotic trees species, Acacia mangium Willd. and A. auriculiformis A. Cunn. ex Benth. and their hybrid are widely grown in India for multiple uses including use as timber. It is essential to know the natural durability of timbers against termites for predicting the service life of the timber and deciding on the application of preservatives to enhance the durability. Studies were conducted to test t...
O K Remadevi, R Muthukrishnan


Leachability of Arsenic, Chromium and Copper from Weathered Treated Wood
2008 - IRG/WP 08-50255
The objective of this study was to quantify the loss of arsenic, chromium and copper from weathered treated wood under normal field conditions as most residential structures currently in service in the U.S. have been constructed at least 3 years ago. For comparison, leaching from different retention levels of weathered CCA treated wood (low, medium and high) is compared to leaching from new ACQ tr...
A R Hasan, Ligang Hu, H M Solo-Gabriele, Yong Cai, L A Fieber


Laboratory study of toxicity or tolerance of CCA preservative and heavy metal constituents copper, chromium and arsenic to Malaysian tropical fungi
2011 - IRG/WP 11-30579
CCA preservative and its constituent heavy metal tolerance and toxicity to 3 Malaysian isolates Phialophora fastigiata (soft rot fungus), Paecilomyces variotii (mould fungus) and an unidentified white rot Basidiomycete, was investigated by the modified ‘Strange-Smith’ agar-well-plate technique with 1.6% CCA concentration and the malt-agar-plate bioassay technique with a range of CCA and consti...
A H H Wong, T Mark Venås, N Morsing, C C L Tan, P K F Chong


Leaching Potential of selected Mississippi Soils Contaminated with Pentachlorophenol (PCP) and Chromated Copper Arsenic (CCA)
2013 - IRG/WP 13-50293
Desorption of pentachlorophenol (PCP), and chromated copper arsenic (CCA) from five Mississippi soil regions was studied. The soils tested were Blackland Prairie (Dorman), the Interior Flatwoods (Winston), the Delta, the Coastal Plains (Wiggins) and the Loess soil (Raymond). Soils were contaminated with 500 ppm and 1000ppm PCP and 1000 ppm for CCA respectively. Toxicity Characteristic Leaching Pro...
K Ragon, H Borazjani, S Keshani Langroodi, S Diehl


Review of Leaching Experiments of CCA-Treated Wood and Wood Treated with Copper-based Alternatives
2017 - IRG/WP 17-50330
The objective of this study was to compare leaching rates of various wood preservatives from treated wood and the tests used to gather this information. The preservatives compared included CCA and the copper-based alternatives, MCQ, ACQ, and MCA. The tests compared included AWPA E11, SPLP, TCLP, and environmental leaching tests. Among all of the tests evaluated, environmental tests most closely si...
A Jones, J Marini, H Solo-Gabriele


Preliminary study of the fungicidal and structural variability in copper naphthenates and naphthenic acids
1996 - IRG/WP 96-30114
Copper naphthenates, an oil-borne wood preservative listed by the American Wood-Preservers' Association (AWPA), is manufactured by complexing copper(II) with naphthenic acids. Prior to AWPA listing as a wood preservative, field experiments showed that copper naphthenates generally had good stability and were active against wood-destroying organisms. Recently, however, there have been reports ...
T Schultz, D D Nicholas, L L Ingram Jr, T H Fisher


Sequestration of copper ions by the extracellular mucilaginous material (ECMM) of two wood rotting basidiomycetes
2004 - IRG/WP 04-10533
The radial growth rate of colonies originating from either whole or ECMM-free inocula of Coriolus versicolor was investigated. The presence of ECMM allowed colonies to maintain higher growth rates than those form ECMM-free inocula up to 2 mM CuSO4 in the medium. The ECMM of C. versicolor and G. trabeum was able to reduce the diffusion of copper ions in solution. The ‘raw’ ECMM of both fungi ha...
D Vesentini, D J Dickinson, R J Murphy


Influence of different fixation and ageing procedures on the leaching behaviour of copper from selected wood preservatives in laboratory trials
2003 - IRG/WP 03-20264
The paper focuses on the role of different parameters, such as fixation, sample size, wood species, and leaching in internationally standardized ageing procedures for wood preservatives from Europe, Japan and the United States. The leaching protocols used were EN 84, JIS K 1571 and AWPA E11 protocols. The wood species were Scots pine, Sugi and Southern Yellow Pine respectively. Three types of com...
J Habicht, D Häntzschel, J Wittenzellner


A discussion on causes, effects and remedies of arsenic pollution of groundwater in Bangladesh
1998 - IRG/WP 98-50102
This paper includes possible causes, effects and remedies of arsenic pollution of groundwater in Bangladesh, extracted mostly from the international conference held in Dhaka in 1998. Next possible key steps have been suggested based on scientific principles and experience. The release of arsenic from underground sediment would be due to excessive mechanical forces, geochemical and geobiological re...
A K Lahiry


Types of decay observed in CCA-treated pine posts in horticultural situations in New Zealand
1984 - IRG/WP 1226
The few reported failures of 11-12-year-old horticultural posts in New Zealand in 1982 were caused by brown-rot. A subsequent survey of CCA-treated posts in all the major horticultural areas has revealed decay of many posts. A microscopic examination of these posts has shown decay by brown-rot, white-rot, soft-rot and bacteria. Several types of bacterial decay have been observed....
J A Drysdale, M E Hedley


Field Testing of Copper Carboxylate Preservatives
2003 - IRG/WP 03-30322
This paper details our ongoing experience with field testing of copper naphthenate and other copper carboxylate preservative systems. Results from field stake tests at an AWPA Hazard Zone 4 test site are presented. In general, copper carboxylates made with ‘synthetics’ yielded results equivalent to or only slightly lower than systems with straight nap acids or nap acids amended with syntheti...
H M Barnes, M G Sanders, T L Amburgey


International collaborative laboratory comparison of two wood preservatives against subterranean termites: Third update and first report
1996 - IRG/WP 96-10174
At the 24th annual meeting of IRG in Orlando, USA, in May 1993 an international subterranean termite laboratory bioassay to compare the various preferred termite protocols used by IRG termitologists was initiated. The author was nominated to co-ordinate this comparative laboratory evaluation of two wood preservatives, copper-chrome-arsenic (CCA) and copper naphthenate (Cu-Na) against the subterran...
J R J French


Fungicidal activity of some organic solvents, copper carboxylates and their complexes with 2-aminoethanol
1997 - IRG/WP 97-30136
We evaluated the activity of eight organic solvents against wood - rotting fungus Trametes versicolor in order to choose the most appropriate one for rapid screening tests of some copper(II) carboxylates and their adducts with 2-aminoethanol. Their activity against the selected fungus was classified in the following order: chloroform > N,N-dimethylformamide > acetonitrile > methanol > ...
M Petric, F Pohleven


La rôle de l'expert dans l'évaluation toxicologique
1990 - IRG/WP 3589
C Boudene


The leaching of copper, chrome and arsenate from CCA-impregnated poles stored for ten years in running water
1978 - IRG/WP 3122
There is no evidence to indicate that the chromium and copper components are leached from the outermost 5 mm of sapwood in poles impregnated with Boliden K33 and Tanalith C and stored in running water for ten years. The arsenic component, however, seems to be leached out during the first few months to an extent of about 20% of the initial amount. The leaching time is dependent on the preservative ...
F G Evans


Recent soft-rot research in softwoods and hardwoods
1980 - IRG/WP 1108
The purpose of this paper is to describe briefly the current status of our research on soft-rot fungi. The work to be discussed is still in progress and any results described must be regarded as provisional....
J A Butcher


Light organic solvent preservative treatment of glue-laminated radiata pine
1986 - IRG/WP 3380
The high permeability of radiata pine (Pinus radiata D. Don) is associated with ray-tissue and in particular the cross-field pits linking ray-tissue to tracheids. This pathway is absent in the tangential grain direction, leading to poor preservative penetration when treatment is restricted to the radial face - for example, timber fabricated into glue-laminated beams....
P Vinden


Termite resistance of pine wood treated with chromated copper arsenates
1997 - IRG/WP 97-30128
Two four-week, no-choice laboratory tests were performed with CCA-treated southern yellow pine and radiata pine against Formosan subterranean termites, Coptotermes formosanus. CCA retentions as low as 0.05 kg/m3 (0.03 pcf) provided protection from all but light termite attack (rating of 9 on a 10-point visual scale). Similar and consistent light attack on wafers containing retentions as high as 6....
J K Grace


Problems of fixation of CCA-preservatives in palm-wood
1985 - IRG/WP 3338
Palm-wood may be used for posts and poles where it needs proper treatment for long time use. Based on observations by W. Killmann on low CCA-fixation in palm-wood, samples of Jubaea-palm grown in a Greenhouse at Hamburg, have been treated in two different series with a 4% solution of CCA-type B. After 1-16 weeks of storage the blocks were split into sticks of 1-2 mm² and leached. In all series 50...
H Willeitner, K Brandt


Insect resistance of preservative treated tropical plywood against Lyctus
1990 - IRG/WP 1453
Seven plywood types composed of tropical wood species, vulnerable to Lyctus, were treated with various commercial water-borne and oil-borne preservatives. A wide range of preservative retentions was obtained by treating boards with dip treatment, steeping, double-vacuum and vacuum-pressure impregnations. Selected samples were subsequently tested for their insect resistance against Lyctus africanus...
J Van Acker, M Stevens, M Pallaske


A new concept of oxalic acid biosynthesis in physiology of copper-tolerant brown-rot fungi
2001 - IRG/WP 01-10394
Recently, a wide variety of roles of oxalic acid (oxalate) in wood decay systems have been receiving much attention. Copper tolerance of wood-rotting basidiomycetes has been believed to be due to the detoxification of copper wood preservatives by oxalate produced by these fungi. However, biochemical mechanism of oxalate biosynthesis in relation to physiology of wood-rotting fungi has not been eluc...
E Munir, T Hattori, M Shimada


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