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Health aspects concerning the use of bifluorides in wood
1981 - IRG/WP 3173
An attempt has been made to find a correlation between the quantities F¯ and HF present among other ions in an 'Improsol' solution consisting of NH4F.HF and KF.HF, the quantity absorbed by the wood from this after immersion and the toxicological effects of this treated wood when it is used in rooms destined for the residence of people or animals or for the storage of foodstuffs....
H F M Nijman


Treatment of dried sawn spruce and redwood building timbers with water-borne preservatives under a scheme for the quality control of the preservation and preserved wood in the Netherlands
1978 - IRG/WP 3123
Treatment of dried sawn spruce and redwood Building Timbers with water-borne preservatives under a scheme for the quality control of the preservation and preserved wood in the Netherlands. The aim of this article is to give the reader a modest description of the evaluation of fundamental research in wood preservation into a practical application....
H F M Nijman, N Burgers


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


Fluoride woodpill
1987 - IRG/WP 3431
Decay problems of spruce joinery in the Netherlands in the 1960's and 1970's led to the introduction of preservative treatment. Because of the known penetration difficulties with Spruce, the results of the treatments were not always successful. The fact that the decay was found only in the joints led to development of the philosophy of "local preservation" of the joints in remedi...
J W P T Van der Drift, K J M Bonsen


Risk of pulmonary damage as a result of an evaporation of ca. 50 ppb = 42 mg HF, evaporated from wood treated by difluorides
1987 - IRG/WP 3401
In this review of the literature the effects of fluorides and fluorine on man are described, especially the low level effects of inhaled HF on human beings. The term "fluoride" is used as a general term everywhere, where exact differentiation between ionic and moluecular forms or between gaseous and particulate forms is uncertain or unnecessary. The term covers all combined forms of the element, r...
H F M Nijman


Long term experiments for assessing the diffusion of boric acid and diluorides from local preservative pills in spruce and pine
1996 - IRG/WP 96-40065
For the experimental assessment of the diffusion of boric acid and difluorides over a three year period 2 tests were set up. In a test with large spruce blocks (150 x 150 x 300 mm³) 3 different pill types were exposed to 3 different climates: climate room (20°C, 65% r.h.), wet room (20°C, 95% r.h.), and to outside exposure. In a test with open L-joints without paint, with an alkyd paint and wit...
W J Homan, H Militz


The lasting dehydration of wood treated by bifluorides worked up in Diffusec noticed by a continual drying of the wood
1999 - IRG/WP 99-30196
After an immersion of sound wood in a solution of Diffusec, in which a combination of acid potassium and ammonium bifluorides = FHF- in dissociated form is present, their potassium and ammonium fluoride ions together with the bifluoride ion = (FHF-) diffuse into the wood. They make use of the woodmoisture available as O-H-O bonds directly attached to the cellulose in the wood fibres to attract the...
H F M Nijman


Mechanism of nano metal fluorides against fungi
2018 - IRG/WP 18-30730
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredient in wood preservatives such as copper and boron. Wood specimens treated with fluoride sols of MgF2 and CaF2 have been tested against brown-rot fungi (Coniophora puteana and Rhodonia placenta) in accordance with EN 113 and against termites (...
S M Usmani, K Klutzny, I Stephan, T Hübert, E Kemnitz


Biocidic effect of nano metal fluorides against brown-rot fungi
2019 - IRG/WP 19-30732
Metal fluoride nanoparticles are promising because of their low water solubility, which reduces the need for fixatives required in widely used active ingredients in wood preservatives such as copper and boron. The effectiveness of nano metal fluorides was compared to sodium fluoride treated wood samples. Wood specimens treated with homo-dispersed sols of MgF2 and CaF2 were tested against brown-rot...
S M Usmani, K Klutzny, I Stephan, E Kemnitz


Application of nano metal fluorides against termites
2019 - IRG/WP 19-30733
Recent research has shown that fluorides such as NaF have potential as a wood preservative against termite attack (Pan and Wang, 2015). However, NaF has high leaching susceptibility because of its solubility (40 g/l ) which can reduce its efficacy over long term. Metal fluoride nanoparticles such as MgF2 and CaF2 present a viable alternative to water soluble fluoride-based wood preservatives as th...
S M Usmani, K Klutzny, Y de Laval, R Plarre, D McMahon, I Stephan, T Hübert, E Kemnitz