IRG Documents Database and Compendium


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Leaching of inorganic wood preservatives – Investigating the relationship between leachability, dissociation characteristics and long-term leaching potential
2003 - IRG/WP 03-50199
Estimation of the leaching properties of preservative components is greatly affected by the leaching test method applied since not all methods equally consider the physical components responsible for leaching. These include: wetting of the wood and penetration of water (affected by dimensions, amount of end grain, permeability, duration and nature of water exposure); solution of preservative comp...
L Waldron, Y T Ung, P A Cooper


Preservation of wood composites with zinc borate
1995 - IRG/WP 95-30074
Inorganic borates such as boric acid, borax, disodium octaborate tetrahydrate, and zinc borate can be incorporated into wood composites such as waferboard to impart decay and insect resistance to the final product. Zinc borate is especially well suited for this application due to its efficacy and leach resistance. The paper summarizes the work performed to date in this area. The effects on strengt...
P E Laks, M J Manning


Spruce lumber treatments with ammoniacal solutions of inorganic preservatives
1977 - IRG/WP 391
As a part of our work in the Wood Preservation group at the Eastern Forest Products Laboratory in Ottawa to facilitate exploitation of spruce, which is a large timber resource in Canada, we have been studying the treatability of spruce roundwood. A report on this subject was presented to this group last year. More recently, another commodity - spruce timber - has been rapidly gaining the interest ...
R Rak


Progress towards controlling soft rot of treated hardwood poles in Australia
1977 - IRG/WP 289
H Greaves


Borate thermal treatments
1992 - IRG/WP 92-3715
Green, partially seasoned (air-dried, steam conditioned), or kiln-dried southern pine timbers were treated thermally using 15% disodiumoctaborate tetrahydrate solution. After treatment, sections were stored under non-drying conditions to allow for diffusion. Results showed that effective treatment meeting the AWPA minimum retention (0.17 B203 pcf [2.72 kg/m³] in the outer inch) and penetration (2...
H M Barnes, R W Landers, L H Williams


The long-term performance of boron treated joinery in service - A case study
2000 - IRG/WP 00-20208
Joinery treated with borates 23 years ago and in service in residential flats was surveyed and analysed for boron content. The levels of boron still present were sufficient to prevent decay. None of the windows surveyed showed any decay despite the fact that moisture and sapwood contents were conducive to decay....
D J Dickinson, R J Murphy


Assessment of losses of wood preservatives from treated wood by leaching into the environment
1993 - IRG/WP 93-50001-13
Wood preservative chemicals may be lost from treated timber by leaching into water or soil. The degree to which this might occur and its effect on the environment is difficult to assess quantitatively due to the absence of appropriate test methods. This paper describes work to assess test methodology capable of allowing the rates of loss of wood preservative from treated timber to be quantified. T...
R J Orsler, G E Holland


Discussion of diiodomethyl p-tolyl sulfone (Amical® 48) as a fungicide for wood preservatio
1987 - IRG/WP 3425
The effectiveness of diiodomethyl-p-tolyl sulfone (Amical® 48) as a fungicide for preservation of wood is supported by a discussion of results from the literature and current research programs....
J M Stamm, K J Littel, F M H Casati, M B Friedman


Volatile borates in the treatment of wood and wood based panel products against subterranean termites
1995 - IRG/WP 95-30094
Blocks of pine solid wood, oriented strand board and plywood were treated with trimethyl borate by vapour treatment. It was meant to obtain either a full impregnation of the specimens or a shell treatment of the outer three millimetres. The efficacy of the treatments against subterranean termites (Reticulitermes lucifugus) was evaluated using an European Standard method....
L Nunes, D J Dickinson, R J Murphy


Absorption of inorganic salts solutions. Retentions of inorganic salts. Fire retardants
1990 - IRG/WP 3625
The study aims evaluated the impregnation capacity using fire retardants on woods with differents densities. At the same time, impregnation with several fire retardant salts were carried out in order to obtain their absortion and retention in wood....
A Garcia, J Navarro


Biological performance of gypsum products containing borates
2000 - IRG/WP 00-30237
At suitable retentions borates have biostatic properties enabling them to be used for biodeterioration control in wood. They provide protection against decay fungi, mould, and termites, which are known to also attack gypsum products. Currently, many gypsum products contain added borates, which are used to improve physical and processing characteristics. Work examining the effect of borates at cont...
J L Fogel, J D Lloyd


Movement of boron from fused boron rods implanted in Southern pine, Douglas fir, red oak, and white oak timbers
1995 - IRG/WP 95-30061
This paper reports the distribution of boron from fused boron rods installed into six-inch (15.2 cm) square timbers of Douglas-fir, Southern Pine, red oak and white oak exposed aboveground. The composition and size of rods was: sodium borate and sodium borate-copper oxide (8.5 x 100 mm²); sodium borate-copper, sodium borate and boric oxide-copper oxide (12 x 76 mm²). The boric acid equivalent wa...
T L Highley, L Ferge


Laboratory investigations about the mobility of some inorganic wood preservatives in soils
1998 - IRG/WP 98-50101-22
Wood preservatives and components of wood preservatives leached from impregnated wood can enter the soil and thus contribute to the pollution of the groundwater. However, there is lack of understanding concerning the interacting parameters of wood preservative, leachate, soil and soil solution. To characterise of the behaviour of active ingredients and for the assessment of their environmental imp...
E Melcher, R-D Peek


Austrian field test method for anti-sapstain chemicals
1994 - IRG/WP 94-20020
Although Austria is a small country, the annual consumption of anti-sapstain products ranks to approximately 500 tons annually. In 1994, only three products will be approved by the Austrian Wood Preservation Committee (AWPEC). There is demand for a field test method, which demonstrates the efficacy of an anti-sapstain product and consequently implies the acceptance and approval of product by the A...
R Gründlinger, M Brandstätter, H Melzer, O Janotta


Inorganic wood preservative levels in soil near a noise barrier treated with different preservatives after 8 years in service
2005 - IRG/WP 05-50234
In March 1996 nine test sections of a noise barrier were installed near Stockholm Sweden. The test sections include untreated Scots pine, spruce and larch and Scots pine, treated with different wood preservatives. After 8 years in service, the untreated spruce, pine and larch boards in contact with the soil were significantly decayed, with an estimated service life of about 5-10 years, while the u...
P A Cooper, Y T Ung, M-L Edlund, J Jermer, O Söderström


Borates and their biological applications
1998 - IRG/WP 98-30178
This paper reviews some of the many biological applications of borates. Boron is a ubiquitous element found widely distributed in the environment and is a normal component of a healthy diet. Elemental boron does not exist in nature, but is always found combined with oxygen in compounds called borates. Boron is an essential micronutrient for plants, and there is evidence to suggest that boron is of...
J D Lloyd


Potentialities of protein borates as low-toxic, long-term wood preservatives - Preliminary trials
1999 - IRG/WP 99-30212
Boron compounds are efficient wood preservatives, as well as safe for the mammals and environmentally acceptable. Their natural solubility allows them to treat almost any wood species, but is also the cause of their high depletion from treated timber in outside exposure. In order to reduce this leachability, potentialities of proteinic polymer networks retaining boron within the wood have been inv...
M-F Thévenon, A Pizzi, J P Haluk


Diffusion of bifluorides and borates from preservative rods in laminated beams
1991 - IRG/WP 3644
Laminated beams from spruce, pine and larch were treated with two preservative rods, based on bifluorides and octaborate respectively. After 3 and 6 months placed in different climates (65% r.h., 100% r.h., water) the diffusion of the active ingredient was measured. After the 6 months period, the diffusion of the bifluorides was, in all species, ca. 5 times larger than the diffusion from octaborat...
H Militz


The use of zirconium as an inert fixative for borates in preservation
2001 - IRG/WP 01-30256
Stand-alone borates have been used in internal protected situations as wood preservatives for about 60 years. They have not been deemed acceptable for external situations because of their leaching characteristics. Work carried out to reduce the leachability of borates has been reviewed briefly here, and a specific fixation agent based on zirconium has been tested in standard leaching and decay tes...
J D Lloyd, J L Fogel, A Vizel


Effect of borate on uptake and efficacy of an anti-sapstain treatment
2005 - IRG/WP 05-30380
The potential for using borates to enhance uptake and efficacy of propiconazole-based anti-sapstain chemicals was assessed on ponderosa pine sapwood wafers. Borates had no consistent effect on either net solution absorption or propiconazole distribution in the wood. Even small amounts of borate, however, markedly improved the performance of propiconazole against fungal discoloration. These resul...
Jianju Luo, Hua Chen, J J Morrell


Preliminary evaluation of borate baits and dusts for eastern subterranean termite control
1990 - IRG/WP 1433
Borates are of potential use in the development of baiting systems for subterranean termite control. In the 15-day laboratory assays reported here, the oral toxicity of disodium octaborate tetrahydrate to Reticulitermes flavipes (Kollar) was evaluated under choice and no-choice conditions. These assays suggest a range of 2500 to 5000 ppm to be applicable in developing baits, and that concentration...
J K Grace, A Abdallay, J M Sisson


Visualization of inorganic element distribution in preservative treated wood by SEM-EDXA
2001 - IRG/WP 01-40208
SEM-EDXA was found to be an effective way of visualizing inorganic element distribution in wood as it was possible to examine some inorganic elements at the same time and map the concentration differences in color. Japanese cedar sapwoods were impregnated by vacuum treatment with CuAz or by pressure treatment with CCA preservatives and then distribution of Cu, Cr and As elements in wood were exami...
H Matsunaga, R Matsumura, K Oda


Eastern subterranean termite responses to three soil pesticides
1990 - IRG/WP 1432
In laboratory assays simulating field conditions, tunneling and mortality of Reticulitermes flavipes (Kollar) workers were evaluated in sand treated with aqueous solutions of formulated chlorpyrifos, isofenphos, and disodium octaborate tetrahydrate. Chlopyrifos and isofenphos were evaluated at concentrations of 500 and 1000 ppm (weight of active ingredient / weight of sand), and disodium octaborat...
J K Grace


Effects of boron treatments on partially decayed oak and pitch pine heartwood
1996 - IRG/WP 96-30106
This paper reports results of borate based preservative treatment and leaching experiments on partially decayed oak and pitch pine heartwood. Previous experiments have shown little damage is caused to sound timber of these types when treated with Polybor and Boracol 20 preservatives. This experiment was carried out to assess the suitability of selected borate based preservatives for use in histori...
S McCutcheon, G M Smith, J W Palfreyman, P Durrant


Wood protection by surface treatment of two borate preservatives, TIM-BOR® and BORA-CARE®, for the formosan subterranean termite and eastern subterrean termite
1993 - IRG/WP 93-10044
TIM-BOR® (disodium octaborate tetrahydrate: DOT, Na2B8O134H2O) and BORA-CARE® (40% DOT in ethylene glycol) are two borate products marketed for treating wood in use by brushing or spraying onto the wood surface. The active ingredients presumably diffuse into wood by the 10-15% existing wood moisture. Few data, however, are available to demonstrate the diffusion rate. Su & Scheffrahn (1991) s...
M Toroko, N-Y Su


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