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Observations on the colonization of freshly-felled timber treated with prophylactic chemicals by mould and sapstain fungi
1989 - IRG/WP 1394
Field tests using freshly felled pine sapwood were set up to determine the effectiveness of a range of antisapstain compounds and to study the problems of colonization by mould and sapstain fungi. Differences were recorded both in the overall performance of the compounds and also their selectivity in controlling specific fungal types. These results were found to be useful in gaining a better under...
G R Williams, D A Lewis


Selective adsorption of antisapstain actives from two aqueous suspensions, and movement of actives into wood
1996 - IRG/WP 96-30103
Green-off-saw rough sawn Pinus elliottii (slash pine) boards were dipped in aqueous suspensions of two antisapstain formulations, NeXgenâ and Busanâ Sap Stain Preventative (Busan 1009), at three product concentration levels. Concentrations of active ingredients (NeXgen: CTL (chloro-thalonil) and MTC (methylene bisthiocyanate); Busan 1009: TCMTB (2(thiocyanomethylthio)-benzothiazole) and MTC) wer...
M J Kennedy, T L Woods


Effects of timber surface properties and dipping conditions on uptake of antisapstain actives from two aqueous suspensions, and ultimate effects on efficacy against mould and staining organisms
1995 - IRG/WP 95-30073
Green-off-saw rough sawn Pinus elliottii (slash pine) boards were dipped in aqueous suspensions of two antisapstain formulations, and the resultant surface retentions of active ingredients MTC (methylene bisthiocyanate), CTL (chlorothalonil) or TCMTB (2(thiocyanomethylthio)benzothiazole) were monitored by chemical analysis. Surface retentions increased with suspension concentration and surface rou...
M J Kennedy, T L Woods


A field test with anti-sapstain chemicals on sawn pine timber in Finland
1986 - IRG/WP 3368
Fourteen formulations, each in two concentrations, were tested for effectiveness against sapstain, mould and decay on Scots pine (Pinus sylvestris L.) in a field test in South-Finland. The trial was commenced in June 1985 and finished in October 1985. During the test the boards were infected mainly by mould fungi. In kiln dried boards the protective effects of nine and in green boards of four trea...
L Paajanen


Observations on the penetration of preservatives into green timber
1985 - IRG/WP 3335
Differences in the rate and extent of diffusion of MBT and NaPCP-based preservatives following a short dip treatment were observed. The importance of preservative distribution as well as toxicity to the target organisms in governing the ultimate performance of any anti-sapstain compound is discussed....
G R Williams, R A Eaton, D A Lewis


Effectiveness of Busan 30 treated birch blocks in a soil medium
1987 - IRG/WP 3409
TCMTB based formulation has been anticipated for use in dip-diffusion treatment in Papua New Guinea to replace BFCA Wood preservative. One such formulation is the Penacide (TCMTB + MBT Boron) which is currently being tested against fungi and insects. Accelerated laboratory test in soil exposure was employed to test a related formulation (Busan 30) to determine its effectiveness against soil inhabi...
H C Konabe


Long-term protection of stored lumber against mould, stain, and specifically decay: A comparative field test of fungicidal formulations
1984 - IRG/WP 3281
The problem of decay in packaged, unseasoned lumber stored for many months has become of major importance in recent years. Large financial claims have resulted from decay in Canadian lumber stored at length in seaports and storage yards of distributors. For decades acceptable protection from moulds and sapstain was readily achieved with chlorinated phenols applied at appropriate treating levels. H...
A J Cserjesi, A Byrne, E L Johnson


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


Effect of mobile fungicides on fungal pre-infection in radiata pine billets.
1999 - IRG/WP 99-30191
In New Zealand, fungal infection of logs begins directly after felling and whilst severe degrade can be prevented if antisapstain-treated within 24 hours, such short turn-around times of logs are not always practicable. However, conventional antisapstain formulations in use only provide an envelope of protection on the log surface but are unable to control pre-infections below the surface. The obj...
D R Eden, T Singh, B Kreber


Efficacy of deltamethrin associated with TCMTB and MBT for the temporary protection of timbers immediately following their sawing, in tropical countries
1987 - IRG/WP 1321
K-Othrine bois 2.5 "sciage"Ò containing 2.5 g/l of deltamethrin, 50 g/l of TCMTB and 50 g/l of MBT used at a 6% dilution controls effectively during the drying process of the freshly sawn wood, the insects attacking wet wood, the staining fungi and the rots. The protection lasts 4 months. The efficacy trials carried in 1985 and 1986 in the CTFT ("Centre Technique Forestier Tropical") of Abidjan, ...
J S Duguet, V Dartigues


Sentry®, a new antisapstain formulation for protecting logs and lumber. - Part 2: protection of lumber
1999 - IRG/WP 99-30189
Recent research conducted by Forest Research, Chemcolour Industries (NZ) Ltd. and Fletcher Challenge Forest Ltd. has resulted in the development of antisapstain formulations that meet the efficacy requirements of the New Zealand Forest industry for export logs. One treatment, called Sentry®, is now poised for commercial use in New Zealand for treating export logs, having undergone an extensive su...
R N Wakeling, D R Eden, C M Chittenden, J G Van der Waals, B Carpenter, I Dorset, R Kuluz, J Wakeman


Laboratory and field evaluations of a novel formulation, BAM as an anti-sapstain agent
1991 - IRG/WP 3639
A novel anti-sapstain formulation, BAM, consisting of 2-(thiocyanomethylthio) benzothiazole (TCMTB) and methylene bis thiocyanate (MBT) was evaluated for ist anti-sapstain performance in the laboratory and in the field as well. BAM proved effective in controlling the growth of molds and a sapstaining fungus in the standardized Japan Wood Preserving Association (JWPA) tests. All the test fungi coul...
Y Nomura


Surface retentions of PCP, TCMTB and MTC obtained during a field trial of antisapstain formulations
1993 - IRG/WP 93-20002
Formulations containing NaPCP or TCMTB and MTC were included as reference products in a recent field trial of antisapstain formulations in Queensland. Retentions of these actives on the surface of treated sawn Pinus elliottii were monitored by ultrasonic solvent extraction of excised samples and analytical determination by high performance liquid chromatography. Distribution of actives with depth ...
D E Ferlazzo, M D Needham, M J Kennedy


Characterisations of the mode of action(s) of Methylene bisthiocyanate (MBT) in Ophiostoma floccosum
2005 - IRG/WP 05-10554
Potassium (K+) leakage, oxygen consumption, glucose depletion and level of ATP formation were determined to elucidate the potential target site(s) of MBT on the sapstain fungus O. floccosum. Treatment of O. floccosum with MBT caused an efflux of intracellular K+ ions from the cells, and the rate of leakage increased with increasing MBT concentrations up to a certain value. This observation sugge...
T Singh, B Kreber, A Stewart, M Jaspers


Detoxification of methylene bisthiocyanate by bacteria isolated from freshly felled, anti-sapstain treated timber
1993 - IRG/WP 93-10017
The microbial defacement of freshly-felled timber treated with organic biocides continues to be a major problem in stored lumber. As part of a study to investigate the depletion in chemical activity of methylene-bis-thiocyanate (MBT) in green timber, bacteria were isolated from freshly-felled boards of Corsican pine (Pinus nigra var. maritima Arnold) previously treated with different biocides. The...
R J Wallace, R A Eaton, G R Williams


Evaluation of the insecticidal efficacy of deltamethrin and the fungicidal efficacy of its association with TCMTB + MBT in the field of wood preservation
1986 - IRG/WP 1289 E
Deltamethrin possesses many advantages for the insecticidal protection of wood: relatively low toxicity, very reduced evaporation, very prolonged retention in the wood, very slight leaching after having penetrated the wood, and absence of odour. Its association with other active agents or solvents is being studied with regard to chemical compatibility. Compatibility studies have proved positive fo...
J S Duguet


Sentry®), a new antisapstain formulation for protecting logs and lumber. - Part 1: advances in protection of New Zealand radiata pine logs
1999 - IRG/WP 99-30188
Until recently antisapstain formulations gave approximately 10 weeks protection to radiata pine logs and even within this time frame protection was often not consistent. Industry requires 20 weeks protection. The degree of protection sought by industry is in the order of 90-95%. For example, this equates to a maximum of 5 - 10% surface cover of sapstain in the first whole veneer produced from a pe...
R N Wakeling, D R Eden, C M Chittenden, J G Van der Waals, B Carpenter, I Dorset, R Kuluz, J Wakeman, T Price, B Nairn


Antisapstain field trials of NeXgen in New Zealand
1997 - IRG/WP 97-30145
This document covers the results of summer and winter log trials of NeXgen, an antisapstain formulation containing methylene bis thiocyanate plus chlorothalonil. Log billets (20 - 25cm diameter) were stripped of bark using a commercial maul debarker and antisapstain treated within 8 hours of felling by dip application. Billets were stored in a pole barn and assessed for internal sapstain and decay...
R N Wakeling, T L Woods, D R Eden, C M Chittenden, B Carpenter


Development process of a new anti-sapstain formulation and its present status with the relevant problems
2001 - IRG/WP 01-30257
An anti-sapstain formulation, which contains 2-(thiocyanomethylthio)benzothiazol (TCMTB) and methylene-bis-thiocyanate (MBT) as active ingredients, was developed by a technical agreement with Buckman Laboratories (Memphis, TN, USA) as an alternative to chlorinated phenols for the Japanese market. The formulation was commercialized as BAM 12 years ago. As anti-sapstain treatment is commonly conduct...
K Nobashi, Y Nomura, K Tsunoda


Minimum inhibitory concentration of methylene bisthiocyanate towards selected wood inhabiting fungi in liquid culture and on radiata pine
2001 - IRG/WP 01-30261
The objective of the current study was to determine the minimum inhibitory concentration (MIC) of methylene bisthiocyanate (MBT) towards wood inhabiting fungi common on unseasoned radiata pine (Pinus radiata D. Don). The fungi used were Ophiostoma floccosum, Leptographium procerum, Sphaeropsis sapinea and Trichoderma viride. Fungi were individually inoculated into nutrient media spiked with differ...
T Singh, B Kreber, C Chittenden, R N Wakeling, A Stewart


Decomposition of biocides in aqueous media cases of MTC and TCMTB
1993 - IRG/WP 93-50001-26
Our laboratory is interested in the fate of modern biocide molecules in the environment. Here we present recent work which has been done on the fate of two compounds with fungicidal and bactericidal properties: methylenedithiocyanate (MTC: NCS - CH2 - SCN) and thiocyanomethylthiobenzothiazol (TCMTB). We have studied separately the influence of pH, temperature and ultraviolet irradiation in aqueous...
R Perraud, M Papazian


Field evaluation of anti-sapstain products
1987 - IRG/WP 3402
Product A based on methylenebisthiocyanate, product B based on methylenebisthiocyanate plus 2-thiocyanomethylthio-benzothiazole, product C based on 2-thiocyanomethilthio-benzothiazole and product D based on didecyl dimethil ammonium chloride plus 3-iodo-2 propynil butyl carbarnate were evaluated on Pinus radiata sawn timber as fungicides for sapstain and mould in the Sawmill Division of the Univer...
M C Rose, A Bedoya


Performance of proprietary formulations of anti-sapstain preservatives on Hevea brasiliensis timbers in laboratory tests
1989 - IRG/WP 3532
A total of 10 proprietary and two experimental formulations were assessed for their effectiveness against sap-stain caused by Botryodiplodia theobromae on Rubberwood (Hevea brasiliensis). Sterilized wood samples 5x20x40 mm³ were dipped in the test chemicals for 60 seconds and then inoculated with 0.5 ml of culture filtrate of Botryodiplodia theobromae for incubation in sterile, damp petri dishes....
L T Hong


Laboratory evaluation of anti-sapstain formulations
1989 - IRG/WP 3510
Four formulations were tested for their efficacy in controlling molds and sapstaining fungi on wood according to the Standard-II of Japan Wood Preserving Association (JWPA). Relative efficacy was compared on the basis of visual rating of the fungal growth on the treated and untreated wood surfaces when the wood specimens were exposed to each monoculture of 5 test fungi at 26±2°C and 70-80% for 4...
K Tsunoda


Evaluation de l'efficacité insecticide de la deltaméthrine et fongicide de son association avec le TCMTB+MBT dans le domaine de la préservation des bois
1986 - IRG/WP 1289
La deltaméthrine pour la protection insecticide des bois possède de nombreux avantages: une toxicité relative faible, une évaporation très réduite, une très longue conservation dans la bois, un délavage très faible une fois qu'elle est pénétrée dans le bois, elle n'a pas d'odeur. Son association avec toutes autres matières actives ou solvants sera étudiée ...
J S Duguet


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