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The efficacy of preservatives into the glue-line of plywood
1993 - IRG/WP 93-30002
This research is anti-termite/decay preservatives mixed with resin to produce the plywood. Thereafter, anti-decay/termite plywood were produced by the ordinary methods. To produce suitable plywood in the utilization and certified performance, the preservatives should be 0.3 to 0.4 kg/m³ of Chlorpyrifos; 0.88 and 1.10 kg/m³ of mix preservatives of Chlorpyrifos + IF-1000. Laboratories decay test (...
S Fushiki, T Saito, Y Katuzawa, Y Imamura, S Yusuf, B Subiyanto


Time dependent over-uptake of etherificated melamine resins
1998 - IRG/WP 98-40109
Waterbased methanol-etherificated melamine-formaldehyde resins can increase the fungal resistance of the treated wood though they are known to be non-toxic. Therefore melamine-resins are at the present an object of research activities of European projects and of some companies. The paper highlights the importance of quoting the duration of the diffusion when immersed in the treating solution, as m...
D Lukowsky, R-D Peek


Dimensional stability, biological resistance, and mechanical properties of phenol-resin-treated particleboard
1990 - IRG/WP 3622
Particleboards were treated with a low molecular-weight phenol-formaldehyde (PF) resin and their enhanced properties were evaluated. Besides dipping of particles in aqeous solutions of resin, and spraying of resin solutions before spray of the conventional phenol-formaldehyde resin for adhesive binder, one step treatment by spraying of the mixture of the low molecular-weight resin and the adhesive...
Y Imamura, H Kajita


Biological resistance of phenol-resin treated wood
1990 - IRG/WP 3602
Biological resistance of PF (phenol formaldehyde resin) - treated wood has been tested in relation to the resin properties, wood species and biological factors. When tested using water-soluble PF (mol. wt. 170), ca. 10% RI (resin impregnation) was enough to suppress the decay of Japanese cedar (Cryptomeria japonica) and western hemlock (Tsuga heterophylla) blocks exposed to Tyromyces palustris (br...
M Takahashi, Y Imamura


EELS (Electron Energy Loss Spectroscopy) - a technique for quantification of nitrogen and other light elements in the cell wall
1999 - IRG/WP 99-20163
A literature survey was performed to find progress in techniques for monitoring penetration of synthetic resins in wood cell walls. Electron energy loss spectroscopy (EELS) in combination with transmission electron microscopy (TEM) was successfully applied for the high resolution examination of the distribution of a partly methylated hydroxymethyl melamine resin in Norway spruce (Picea abies Karst...
A O Rapp, H Bestgen, W Adam, R-D Peek


Durability of surface preserved wood particle boards submitted to atmospherical influence
1995 - IRG/WP 95-40039
The worldwide problem of the continuously growing deficit of high quality natural wood material has caused the attempts of many research workers to find effective composites such as wood particle boards (WPBs) for replacing the massive wood for constructive purposes, depending on where the boards are exploited - in the open or under a shed, they are submitted to various climatic factors such as he...
L Valcheva


Curing conditions for a low formaldehyde etherificated melamine resin
1998 - IRG/WP 98-40108
Waterbased methanol etherificated melamine formaldehyde resins have the potential to increase the resistance of impregnated wood against wood destroying fungi. Previous studies indicated that the resin with the lowest formaldehyde content tested showed the best results regarding fungal resistance, dimensional stability and formaldehyde emissions after curing. In the present paper the influence of ...
D Lukowsky, R-D Peek, A O Rapp


In situ testing the influence of melamine resins on the enzymatic activity of basidiomycetes
1999 - IRG/WP 99-30194
Waterbased methanol etherificated melamine formaldehyde resins have the potential to increase the resistance of impregnated wood against wood destroying fungi. The mechanism of the increased wood durability is not clear yet. In the present paper the possible interference of melamine resins with wood degrading enzymes of Coniophora puteana and Trametes versicolor was investigated as a possible cont...
D Lukowsky, F Büschelberger, O Schmidt


Melamine resins as preservatives results of biological testing
1996 - IRG/WP 96-40061
Based on previous work of the authors on resins, the upgrading of wood with a true solution of a methanol etherificated melamine resin in low aqueous concentration was performed. For the relative assessment of the biological resistance against brown and white-rot fungi were used not only untreated controls of pine sapwood (Pinus sylvestris L.), but also heartwood of European larch (Larix decidua M...
A O Rapp, R-D Peek


Leaching performance, decay and termite resistance of wood treated with boron compounds incorporated with phenol-formaldehyde resin
2009 - IRG/WP 09-30503
A resol-type phenol-formaldehyde (PF) resin was synthesized and designed to penetrate wood incorporated with boron compounds in order to immobilize boron in wood. The leaching performance, decay and termite resistance of treated wood was investigated. Three kinds of boron compounds, that is, boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT), were selected to mix with PF and tw...
Liping Yu, Jinzhen Cao


Properties of strand board bonded with ammonium pentaborate (APB) modified phenol formaldehyde resin
2009 - IRG/WP 09-40455
Ammonium pentaborate (APB) is combined with phenol formaldehyde (PF) resin in this study to develop a high-performance wood-based composite. The effect of APB and its combination with polyethylene glycol (PEG) on the physical, mechanical properties as well as formaldehyde emission of strand board were tested and compared with disodium octaborate tetrahydrateand (DOT) and zinc borate (ZB). The resu...
Wei Gao, Jinzhen Cao


Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


Curing kinetics of nano cupric oxide (CuO) modified PF resin as wood adhesive: Effect of surfactant
2013 - IRG/WP 13-40620
The effect of nano cupric oxide (CuO) in combination with surfactants on the curing kinetics of phenol formaldehyde (PF) resin, as well as the bonding strength of plywood prepared using the modified resin were investigated in this study using dynamic and isothermal differential scanning calorimetry (DSC). The result showed that the incorporation of nano CuO along with alkane surfactant made in the...
Wei Gao, Guanben Du


Dynamic mechanical analysis (DMA) of nano cupric oxide (CuO) modified aqueous phenol formaldehyde (PF) resin
2014 - IRG/WP 14-40654
Phenol formaldehyde (PF) resins, modified by nano CuO incorporating alkane surfactant and polyvinyl alcohol (PVA) 17-99, were analyzed by dynamic mechanical analysis (DMA). The mechanical properties of its bonded plywood including tensile strength, modulus of rupture (MOR), modulus of elasticity (MOE) and shear strength under five test conditions were evaluated. Results indicated that the incorpor...
Wei Gao, Guanben Du


Performance of some wood modification treatments against marine borers
2014 - IRG/WP 14-40668
Since some years, new treatment technology to protect wood against wood destroying fungi is introduced. Limited knowledge on their resistance to water organisms is available. Therefore, the resistance of chemically modified wood was assessed in a field test according to the European Standard EN 275 over a period of 3 resp. 5 years at sites in the North Sea and the Baltic Sea. Scots pine (Pinus syl...
A Klüppel, C Mai, H Militz, S Cragg


Penetration of phenol formaldehyde (PF) resin into beech wood studied by light microscopy
2015 - IRG/WP 15-20558
In this study, we examined the distribution and penetration depth of phenol-formaldehyde (PF) resin into wood specimens by light microscopy (LM). Two PF resins from different producers, of concentrations 9, 18 and 27 wt % in water, were vacuum impregnated into European beech wood (Fagus sylvatica) blocks of 15x25x50 mm³. The presence of chemical agent in the wood was carried out by way of their i...
V Biziks, S Bicke, H Militz


Decay resistance of beech wood and plywood treated with different type of phenol-formaldehyde (PF) resins
2016 - IRG/WP 16-40717
In this study treatment of beech and poplar wood veneers with (PF) resin industrial scale and screening tests of nine different phenol-formaldehyde (PF) resins were made. Specifically, the effect of different phenol-formaldehyde (PF) resin types on the resistance of beech wood against brown- and white-rot fungi was evaluated. Criteria for selection of optimal (PF) resin were based on minimum WPG ...
V Biziks, S Bicke, H Militz


Marine Borer Resistance of Acetylated and Furfurylated Wood – Results from up to 16 years of Field Exposure
2016 - IRG/WP 16-40756
Furfurylated and acetylated Scots pine sapwood has been tested since 1999 in a marine field with high marine borer activity. In 2004, two test groups with acetylated southern yellow pine (product later known as Perennial Wood™) were put out and over the whole test period differently furfurylated wood (later marketed as Kebony®) test groups have been started. Furthermore, some combinations of mo...
M Westin, P Larsson Brelid, T Nilsson, A O Rapp, J P Dickerson, S Lande, S Cragg


Lignin-Based Adhesive for Engineered Wood Products
2016 - IRG/WP 16-50319
Lignin as a naturally occurring polyphenolic compound has an excellent potential to replace petroleum-based phenol in formulation of phenol-formaldehyde adhesive that are used in manufacturing of engineered wood products. However, there are three major obstacles in application of polymeric lignin as phenol replacement: 1) low reactivity toward phenol, 2) high molecular weight, and 3) high polydisp...
I Kalami, M Arefmanesh, E Master, M Nejad


Weathering protection of European hardwoods through double modification
2017 - IRG/WP 17-30715
Beech and poplar were thermally modified, treated with melamine resin and both treatments were combined. The weathering performance (cracks and general appearance) of modified beech and poplar was assessed in natural weathering and correlated to material properties such as work in bending (WB) and Brinell hardness. In addition, the equilibrium moisture content after exposure of 12 months and subse...
G Behr, A Gellerich, S Bollmus, H Militz


Dimensional Stability of Melamine Formaldehyde-Treated Southern Pine
2017 - IRG/WP 17-40774
The objective of this preliminary study was to evaluate the influence of different levels of melamine formaldehyde (MF) and curing cycle on the dimensional properties of southern pine. Thirty samples for each combination of treatment and curing regimen plus untreated controls and controls subjected to the same curing regimen were tested. Shrinkage/swelling coefficients showed that up to 60% ASE c...
H M Barnes, L S Sites, T S F A França, M G Sanders, F J N França


Improvement of wood decay and termite durability resulting from combined treatments based on borax/phenol-formaldehyde impregnation followed by thermal modification
2019 - IRG/WP 19-40871
This study determined the factors influencing the boron content after leaching of pine blocks impregnated with aqueous solution of phenol-formaldehyde (PF) resin with or without borax and subjected to heat treatment by response surface methodology. An experimental design permits to analyze the effects of heat treatment temperature (150, 185 and 220°C), curing time (5, 12, 5 and 20 hours), resin c...
S Salman, M-F Thevenon, A Petrissans, S Dumarcay, P Gerardin


Longterm Performance of Treated Timbers in Marine Exposures
2020 - IRG/WP 20-10969
The performance of preservative-treated or modified woods in marine exposures was evaluated at test sites in Newport, Oregon, USA and Brisbane, Queensland, Australia. All samples have exhibited excellent performance at the Newport, Oregon site, while attack was more aggressive at the sub-tropical Brisbane site. Acetylated wood as well as samples treated with 7.3% chromated copper arsenate (CCA-T...
M Konkler, A R Zahora, J Norton, J J Morrell


Performance of resin-treated solid wood and laminated veneer lumber (LVL) under marine conditions
2021 - IRG/WP 21-10973
Wood is a traditional building material in the marine environment, where it is exposed to extremely harsh conditions. Most of the indigenous softwood and hardwood species in Europe are not durable against attack by marine organisms. Recently, wood modification has been considered as an alternative to protect non-durable wood species under use class (UC) 5 (EN 335, 2013) conditions. The present stu...
L Emmerich, C Brischke, S Bicke, H Militz


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