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A study of salt imbalances observed in recycled copper/chrome/arsenic preservative solutions in commercial practice
1987 - IRG/WP 3461
The study reported monitored tank solutions, sludge and other by-products using a standard CCA solution, when recycled. This recycling of the CCA solution is quite usual in between any commercial treatment schedules. Salt imbalances were observed and the possible reasons for such phenomena were studied. The paper discusses the procedure followed, the method of sampling the liquid after the charge ...
V R Sonti, S Sonti, B Chatterjee


Errata to Document No: IRG/WP/3276
1984 - IRG/WP 3285
W E Conradie


Fundamentals on steam fixation of chromated wood preservatives
1988 - IRG/WP 3483
Weathering of treated wood directly after impregnation leaches up to 2% of copper-chromate-containing wood preservatives. Almost total fixation of Cr+6 is achieved by steaming the treated wood at 100°C to 120°C, preferably 110°C. To initiate such spontaneous fixation 85°C to 90°C inside the wood are essential, which requires heating times ranging from 20 to 80 min, depending on timber species...
R-D Peek, H Willeitner


Disproportionate absorption of different constituents of CCA salts
1988 - IRG/WP 3484
Results of preliminary experiments carried out to study selective absorption of different constituents of CCA salts and sludge formation in commercial treatment, using Terminalia myriocarpa and Pinus kesia timbers, are reported in this paper. The objective of these experiments is to evolve simple and practical methods to prevent/minimise sludge formation and differential absorption of the constitu...
V R Sonti, S Sonti, B Chatterjee


Less pollution due to technical approaches on accelerated steam fixation of chromated wood preservatives
1988 - IRG/WP 3487
Steaming of freshly treated wood at 100°C to 120°C initiates a spontaneous fixation of copper-chromate-containing wood preservatives. For the performance, a suitable anticorrosive equipment is necessary. Good results can be achieved using a separate steaming equipment which allows a rapid heating of the wood. While warming-up, in the wood some preservative solution extends and can be partly extr...
H Willeitner, R-D Peek


Experimental variations in the distribution of CCA preservative in lignin and holocellulose as a function of treating conditions (temperature, concentration, pH, species, and time)
1984 - IRG/WP 3277
The exact distributions between lignin and holocellulose and retentions on wood of copper, chromium and arsenic as a function of various sets of conditions in a 3x3x4x2 factorial experiment in which combinations of three temperatures of treatment, three CCA solution concentrations, four pH's of the initial CCA solution and two timber species, namely Pinus radiata and Eucalyptus grandis, a...
A Pizzi, E Orovan, M Singmin, A Jansen, M C Vogel


The susceptibility to sludging of sulfate and oxide CCA
1990 - IRG/WP 3599
Radiata pine sapwood was treated separately with a sulphate CCA-C and an oxide CCA in a pilot scale pressure plant using a full cell process. CCA solutions were recovered from the final vacuum phase, placed in plastic tubes, and their susceptibility to sludging determined by examining changes in solution pH, time required for sludge to form and weight and chemical composition of sludge formed. Sul...
B T Mutandadzi, P D Evans