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TBTO absorption and penetration in pine joinery treated by various processes
1989 - IRG/WP 3523
Matched sections of several White pine (Pinus strobus) and Ponderosa pine (Pinus ponderosa) mouldings were treated with TBTO by Double vacuum, modified empty-cell, 15 second dip and several preheating treatments followed by a 15 s dip treatments. As expected the double vacuum and empty-cell (batch) treatments resulted in much greater retentions and penetrations than the dip treatments. The absorpt...
P A Cooper, Y T Ung


Laboratory experiments on aerial emissions from wood treated with wood stains
1993 - IRG/WP 93-50001-06
Due to the actual environmental interest in wood preservation, a series of experiments was carried out on the emission of biocides from treated wood. The research focussed on the volatilization of 5 biocides from boards treated with wood preservative finishes containing dichlofluanide (DCF) azaconazole (AZA), pentachlorphenol (PCP), iodopropynylbuthylcarbamate (IPCB) and tributhyltinoxide (TBTO). ...
G M F Van Eetvelde, M Stevens


Germination of basidiospores on preservative treated wood after leaching or natural weathering
1981 - IRG/WP 2150
In tests of residual toxic efficacy after leaching or natural weathering, spore germination with Gloeophyllum trabeum has proved to be a less reliable criterion of attack than when used with unaged preservative treatments. Since spores sometimes prove more tolerant than their parent mycelium, their use should be continued....
J K Carey


The influence of formulation on the behaviour of LOSP's during industrial impregnation of spruce
1986 - IRG/WP 3387
Evidence is presented that the comparative behaviour of two LOSP formulations during impregnation treatment of spruce cannot be predicted purely on the basis of their physical characteristics (viscosity, surface tension and contact angle) nor on the extent of their 'passive' penetration into pine sapwood....
L D A Saunders, D M Zuvencko


The variability of preservative distribution in test blocks
1973 - IRG/WP 220
The techniques for the assessment of likely effectiveness of preservative systems have long been the subject of much discussion. The whole field has recently been reviewed by Hilditch and Hamblyn (1971) who described in detail many of the laboratory test procedures used, but who also indicated the deficiencies in many of these techniques. It has long been the view of many associated with the wood ...
F W Brooks, M R Gayles, R W Watson


Water-borne wood preservatives against marine borers. Results from NWPC marine trials started in 1972 and 1976
1990 - IRG/WP 4162
The paper presents the results from NWPC (Nordic Wood Preservation Council) marine trials started in 1972 and 1976. The trials are carried out according to the NWPC Standard No. 1.4.2.2./73 "Marine test - a test against marine wood boring organisms in sea water". The test site is Kristineberg Marine Biology Station on the west coast of Sweden. The wood blocks used in the trials were made from sapw...
Ö Bergman, C Lundberg


Chemical analysis for TBTN in LOSP-treated wood and preservative fluids
1994 - IRG/WP 94-20027
Tributyltin napthenate (TBTN) is being substituted for tributyltin oxide (TBTO) in LOSP preservative formulations because its lower reactivity/better stability allows co-formulation with synthetic pyrethroids. Better stability may reduce molecular degradation both in-service and during analysis. It was considered necessary to check whether TBTO analysis methods were suitable for use on TBTN treate...
D P Wraight, M J Kennedy


Stability and performance of tributyltin compounds
1984 - IRG/WP 3275
Based on the critical examinations of the disputable permanence of tributyltin compounds in wood, this paper deals with a number of examinations of the relative evaporation, thermal stability and oxidation stability of some TBT-compounds. While thermal and oxidative stability is high for all TBT-species, the relative evaporation at elevated temperature is highly variable, and lowest for the TBT-es...
F Imsgard, B Jensen, H A B Landsiedel, H Plum


Remedial treatment of joinery. Comparison of distribution of organic solvent preservative and ammonium bifluoride
1978 - IRG/WP 3115
It is some years since it was recognised in the United Kingdom that there was a problem of premature decay in untreated external joinery. Consequently, recommendations for preservative treatment were made by the Building Research Establishment, Princes Risborough Laboratory. In addition, the National House-Building Council has also included the preservative treatment of external joinery in its req...
J M Taylor


The performance of water repellants on radiata pine exposed to the weather
1989 - IRG/WP 3553
The effectiveness and resistance to weathering of four water repellent treatments, a commercial timber stain, and an oil-based clear finish, was assessed using 20x20x6 mm³ samples of untreated, copper-chrome-arsenic (CCA)-treated, and tributyltin oxide (TBTO)-treated radiata pine exposed to the weather over a four month period. The water repellency of each preservative/water repellent combination...
D V Plackett, F M Cameron


Leaching results of shower test on L-joints with boric acid, bifluoride and TBTO rods
1995 - IRG/WP 95-50051
As part of the EC-project "Improvement of a local preservation process for wood products with reduced environmental impact", TNO has performed a leaching test on L-joints treated with pills with boric acid (Defence corner), bifluorides (Woodpil 55) and TBTO (Woodcap). The L-joints were exposed in an adapted shower test during 10 days, using 70 liters of water per day. The experiment is designed to...
P Esser, M J Boonstra, W L D Suitela, A J Pendlebury


Evaluation of some polyurethanes as protective marine coatings for wood
1985 - IRG/WP 4115
Several polyurethane formulations were evaluated in the marine environment as possible replacements for Irish felt used on U.S. Navy minesweepers as a marine borer barrier between the main wooden hull and an outer, wooden sheathing which covers it. Pine panels coated with the candidate materials were tightly juxtaposed with untreated pine baitwood to simulate the hull/sheathing configuration, the ...
J D Bultman, J E Pinto


Co-operative research project on L-joint testing. Progress report to March 1984
1984 - IRG/WP 2211
Each participant was intended to expose L-joints in the main trial on 1 April 1983 and the first sampling, after 8 months exposure, was to be undertaken on 1 December 1983. Some participants have had to vary this schedule. Results are presented from CTFT (France) and PRL (United Kingdom). These show a greater effectiveness by the double vacuum treatments compared with the 1 minute dip treatments. ...
J K Carey, A F Bravery


Kiln drying of CCA-treated wood - Some safety and environmental considerations
1987 - IRG/WP 3443
Vapours and condensate from a condenser kiln in which CCA-treated wood was being dried have been collected and analysed. The concentrations of arsenic, copper and chromium found in the vapours from the drying process were well below Swedish threshold limit values. The contents of arsenic and chromium were also low in the condensate, although the copper content was fairly high. The latter result wa...
J Jermer, B Lundberg


An evaluation of the potential of ion mobility spectrometry for detection of organic wood preservative components in solutions and treated wood
1994 - IRG/WP 94-20038
For the disposal of wood waste under ecological sound conditions information about its hazardous potential is required. Until now, no highly sensitive rapid analytical methods are available for the detection of wood preservatives under industrial process conditions. Preliminary experiments showed that Ion Mobility Spectrometry (IMS) could be a promising method for rapid detection of organic preser...
A Voss, J N R Ruddick, W J Homan, H Militz, H Willeitner


The chemical nature of bis(tributyltin) oxide in Pinus sylvestris sapwood
1989 - IRG/WP 3508
Tributyltin compounds have been used for many years as wood preservatives. This study has provided, for the first time, an explanation for the previously reported dealkylation and/or volatilisation of the tributyltin species in, and from, Scots pine (Pinus sylvestris) sapwood. Thus, 119 Sn nuclear magnetic resonance studies have shown that, on impregnation into this timber, bis(tributyltin) oxide ...
S J Blunden, R Hill


Chemical and biological studies of organotin treated and painted wood stakes after outdoor exposure
1987 - IRG/WP 3419
Organotin based wood preservatives containing tributyltin oxide (TBTO) or tributyltin naphthenate (TBTN) are used in Sweden mainly for double-vacuum treatments of window joinery of Pinus sylvestris. After impregnation the joinery is painted or stained in different colours. To evaluate this effect (different colours on the degree of degradation of TBTO and TBTN, effected by different temperatures i...
M-L Edlund, B Henningsson


Some data on the activity of alternative fungicides for wood preservation
1985 - IRG/WP 3333
Data from laboratory tests against basidiomycete fungi are presented for 9 alternative fungicides in organic solvent formulations and also in water for one product. Results are compared with data for reference preservatives, tributyltin oxide, copper and zinc naphthenates and pentachlorophenol. Of special interest is the apparently better than additive effect of mixing tributyltin naphthenate and ...
A F Bravery, J K Carey


Volatile losses of wood preservatives
1973 - IRG/WP 236
The purpose of the work we have undertaken so far has been to try to quantify the volatile losses which occur in treated timber, and to examine some of the factors which influence these losses. The preservative compound chosen for the initial part of the programme was the contact insecticide g-BHC. This was attractive for several reasons, not the least of which was that specific and sensitive anal...
J W W Morgan, D F Purslow


A preliminary assessment of the penetration into wood achieved by bodied mayonnaise emulsion wood preservatives
1992 - IRG/WP 92-3725
Five different commercial formulations of bodied mayonnaise emulsions were applied to samples of Scots pine (Pinus sylvestris) sapwood as recommended by the manufacturers. Penetration and loading characteristics were determined by measuring the distribution profiles of the active ingredients after various intervals of time. The changes in the general appearance of the emulsions on the surface of t...
G E Holland, R J Orsler


A technique for assessing the preventive efficacy against decay fungi of preservative treatments applied to wood
1988 - IRG/WP 2309
A method is described in which test blocks with envelope preservative treatments can be challenged by selected test fungi previously established on an untreated feeder block. The progress of the test fungus through the treated zone is monitored using novel baits or sensors inserted in holes drilled into blocks to within predetermined distances of the face being challenged. Preliminary results show...
J K Carey, A F Bravery


Proposals for further co-operative studies on determining toxic values against wood-destroying Basidiomycetes
1985 - IRG/WP 2247
Document IRG/WP/2194 reported the status of the programme of co-operative experiments up to and including December 1982. During discussions at IRG-13 in Turkey members endorsed the decision to complete the programme of tests and conduct repeat tests. At IRG-14 in Brisbane the report was noted but no further action agreed. At IRG-15 in Sweden a number of interested parties in the European/Scandinav...
A F Bravery


The effect of wood preservatives on the relation between the electric resistance and moisture content in scots pine (Pinus sylvestris L.) sapwood
1998 - IRG/WP 98-20142
The effect of two types wood preservatives (TBTO and CuHDO) on moisture content measurements with an electric resistance meter in pine sapwood is assessed. High and low concentration impregnated pine sapwood is climatized at different relative humidities. Once climatized the samples are weighed and the moisture content is measured with an electric resistance meter by fixed stainless steel, isolate...
B W Holleboom, W J Homan


Giftwirkung einiger organischer Zinn-Verbindungen auf Eilarven von Hylotrupes bajulus (L.). [Toxic efficacy of some organic tin compounds against egg larvae of Hylotrupes bajulus (L.)]
1978 - IRG/WP 2120
The toxic values of 12 organic tin compounds towards newly hatched larvae of Hylotrupes bajulus were determined after 4- and 12-week test periods in comparison with bis-tri-n-butyltin oxide (TBTO). Tri-n-butyltin benzoate as well as the 2-, 3- and 4-methyl benzoate of tributyltin oxide were equally effective as TBTO and the latter two were somewhat more effective after a 12-week test period. Almos...
G Becker


Durability of exterior natural wood finishes in Brazil
1985 - IRG/WP 3343
Wood finishes systems were evaluated in natural weathering conditions during 5 (five) years, over "Parana-pine" (Araucaria angustifolia). Test samples results show that: - Semitransparent wood preservative stains, based on polimerized linseed oil, provided very good protection to the wood, compared with the one based on alkyd varnish; - Solid color wood preservative stains provided good durability...
D R Macedo


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