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Weathering of Wood Modified with the N-Methylol Compound 1,3‑dimethylol-4,5-dihydroxyethyleneurea (DMDHEU)
2009 - IRG/WP 09-40467
Scots pine (Pinus sylvestris L.) sapwood boards were treated with a methylated 1,3‑dimethylol-4,5-dihydroxyethyleneurea (mDMDHEU) causing weight gains of approx. 25% and exposed to weathering for 18 months. Compared to untreated boards, treatment with mDMDHEU reduced surface discoloration mainly caused by staining fungi. Boards treated with mDMDHEU exhibited clearly lower moisture content th...
C Mai, Yanjun Xie, A Krause, K Urban, P D Evans, K Richter, H Militz


Synthesis of novelty borate compounds for wood preservatives: Laboratory test of leachability and decay resistance
2010 - IRG/WP 10-30520
A novel series of ammonium tetraphenylborate (ATB) and borate chemical compounds (BBC) were synthesized as wood preservatives. The leaching rates and decay resistance of boron formulations containing ATB and BBC were conducted. The laboratory leaching results showed that boron leaching rate of treated wood by ATB formulations was from 2.1% - 6.7%, while that of BBC formulations from 23.3% -59.0%. ...
Zhiqiang Li, Mingliang Jiang, Xingxia Ma


Developing Analytical Methods for Determination of Quaternary Ammonium Compounds (DDAC) using HPLC and HPLC-MS (Application to treating solution and preservatives treated wood)
2013 - IRG/WP 13-20516
Korea preservative treating industry has mainly used alkaline copper quaternary (ACQ) expected over 80% of market share in Korea. ACQ employs dodecyl dimethyl ammonium chloride (DDAC) and benzyl dimethyl dodecyl ammonium chloride (DBAC) for active ingredient along with copper. The strongly increasing domestic applications for wood preservatives require developing accurate and reproducible analytic...
Sung-Mo Kang, Kwon-Min Kim, Won-Mo Koo, Myeong-Won Cho


Reducing Extractives Stain in Western Red Cedar Sidewall Shingles
2014 - IRG/WP 14-30654
One of the aesthetic challenges that western red cedar shingles face is extractives redistribution stain, particularly in unpainted sidewall applications. Dip and pressure treatments with a mixture of quaternary ammonium compounds and alkyl amine oxides were investigated for their ability to prevent this stain. After nine months of exposure in Vancouver, extractives stain was present on nearly all...
R Stirling


Above ground field testing: results of experiments in Brazil after one year
2015 - IRG/WP 15-30660
After the development of new products they need to be field-tested to assess their efficacy under diverse conditions of climate, comparing them with a preservative with proven efficacy. In some testing sites, decay occurs very slowly. The solution would be to bring these tests to locations that are conducive to biodeterioration, like tropical climates. Tropical sites provide higher temperature and...
M F Natale, J M Vidal


A Green and Novel Technology for Recovering Copper and Wood from Treated Waste - Part I
2015 - IRG/WP 15-50309
Preservative treatment of wood extends its service life. The US consumes about 70 million pounds of copper and produces about 7 billion board feet of treated wood annually. Burning and reusing CCA and copper treated wood wastes are disallowed by US EPA due to health and environmental concerns. Millions of pounds of copper and wood are disposed by landfill annually. The objective of this study was...
S Chen


A Green and Novel Technology for Recovering Copper and Wood from Treated Wood Waste – Part II: Optimization, copper metal recovery, and process design
2017 - IRG/WP 17-50326
The US consumes 70 million pounds of copper and produces 580 million cubic feet treated wood annually. The EPA disallows burning and reusing treated wood waste due to health/environmental concerns. Vast quantities of copper and wood are landfilled. Two safe and low cost extraction systems, citric acid and ammonium citrate, were identified in Part I of this study. In Part II of the study, effects o...
S Chen, R Patel


Bio-preservative properties of technical lignins from South African pulp mills: An investigation towards a conceptualized development of natural compound-based wood preservatives
2018 - IRG/WP 18-30724
The depletion of naturally durable timber and the risk posed by some of the conventional wood preservatives to human health and the environment continue to drive research efforts towards developing new formulations that are benign. Furthermore, the global concept of environmental sustainability aims at optimal use of resources and to comprehensively include conversion of waste to value added produ...
A Alade, L Tyhoda, M Meincken


Comparison of copper leaching from alkaline copper quat and copper compound nanosol-based wood preservative treated wood
2024 - IRG/WP 24-20726
To improve the leaching resistance of copper ion-based wood preservatives, copper compound nanosol-based wood preservatives were developed and its copper leaching characteristics were evaluated. Three types of preservatives (DC1, DC2, DC3) were prepared with different crystallinity and dispersant types of copper compound nanosol, and the copper concentration was adjusted to be the same as that of ...
Y-S Choi, S-M Yoon, J O Kim, J-G Kang, J-G Park


A new wood preservative system based on basic copper compound nanosols
2024 - IRG/WP 24-20728
A bottom-up process was established to synthesize insoluble basic copper compound nanoparticles and simultaneously form a stable nanosol by dropping a neutralizing agent solution into an aqueous solution of a copper compound to which an appropriate dispersant system was added. The main ingredient of MCA (Micronized Copper Azole), the leading copper-based wood preservative in the current world mark...
J O Kim, J-G Kang, Y-S Choi, S-M Yoon, H-M Lee, J-G Park


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