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Performance of treated fence posts after 6 years in five test plots in the State of Sao Paulo - Brazil
1976 - IRG/WP 376
Fence posts treated with creosote, pentachlorophenol and creosote/ pentachlorophenol mixtures showed good performance after 6 years of exposure in five test plots located in the State of Sao Paulo - Brazil. Good results were also achieved with copper sulphate/sodium arsenate and copper sulphate/potassium dichromate mixtures. Fungi and termites were the main destroying agents found attacking the po...
M S Cavalcante


The leaching of copper, chrome and arsenate from CCA-impregnated poles stored for ten years in running water
1978 - IRG/WP 3122
There is no evidence to indicate that the chromium and copper components are leached from the outermost 5 mm of sapwood in poles impregnated with Boliden K33 and Tanalith C and stored in running water for ten years. The arsenic component, however, seems to be leached out during the first few months to an extent of about 20% of the initial amount. The leaching time is dependent on the preservative ...
F G Evans


An introduction to environmental aspects of groundwater arsenic and CCA treated wood poles in Bangladesh
1997 - IRG/WP 97-50081
The environment comprises biosphere, lithosphere, atmosphere and hydrosphere. Therefore, environmental science is a multi-disciplinary study, includes life sciences, physical sciences, chemical sciences, geology, geography, meteorology, forestry, agriculture, soil science, hydrology, ecology, public health, engineering etc. Tremendous industrial and mining activities, deforestation and population ...
A K Lahiry


Performance of chromated copper arsenate-treated aspen fence posts installed in Forintek's Eastern test plot from 1951 to 1963
1984 - IRG/WP 3272
Aspen poplar fence posts were pressure treated by the full cell process using three formulations of copper chrome arsenate wood preservative. A total of one hundred and fifty nine of the posts were installed in service in Forintek's Chalk River post plot from 1951 to 1962. During the 1982 general inspection of the post plot all 159 posts were still in service. A groundline inspection was ...
C D Ralph


A laboratory soil-block decay evaluation of plywoods edge-treated with preservatives
1982 - IRG/WP 2174
Preservative-treated plywood used under conditions or severe decay hazard frequently has its original, or cut edges, protected by the application of a field-cut preservative. This study uses a laboratory test method to compare the efficacy of four commercial preservative treatments against two commonly occurring brown-rot fungi. The results are not meant to indicate the service life of such treate...
R S Smith, A Byrne


Migration of Metals from Douglas-fir Lumber Treated with ACZA or Pentachlorophenol Using Best Management Practices: Preliminary Tests
2005 - IRG/WP 05-50224-4
The potential for migration of preservative components from ammoniacal copper zinc arsenate (ACZA) and pentachlorophenol treated Douglas-fir lumber in non-soil contact exposure was assessed in a simulated rainfall device. Metal levels from ACZA treated wood were elevated for the first 30 minutes of rainfall and then declined sharply. Repeated cycles of rainfall led to declines in initial metal l...
J J Morrell, Hua Chen, J Simonsen


Treatability of Siberian larch and spruce with chromated copper arsenate
1996 - IRG/WP 96-40060
Heartwood of Siberian larch (Larix gmelini) and spruce (Picea jezoensis) was pressure treated with chromated copper arsenate (CCA) Type B using a full cell process. Larch heartwood was somewhat difficult to treat than the spruce, although both species did not meet a minimum requirements of penetration and retention specified by the American Wood Preservers' Association (AWPA) for difficul...
Gyu-Hyeok Kim, Woo-Gue Jee, Jae-Jin Kim


A Soil Bed Test of the Effect of CCA Penetration on the Performance of Hem-fir Plywood
2004 - IRG/WP 04-30332
An accelerated decay test was set up to compare the performance of CCA-treated Western hemlock/amabilis fir plywood treated to meet the preserved wood foundation (PWF) retention standard with various patterns of preservative penetration. Short lengths of treated plywood and comparable untreated material were installed in a soil bed. After eleven years of exposure, the CCA treatments were all sou...
P I Morris, J K Ingram


Fixation of chromated copper arsenate (CCA) wood preservative in Australian hardwoods: A comparison of three Eucalyptus species
1996 - IRG/WP 96-30107
New environmental guidelines for the management of CCA treatment plants were released in Australia in 1995. This has stimulated interest in techniques for controlling or accelerating the fixation of CCA in freshly treated timber products. The ability to understand, then effectively control and/or accelerate fixation of CCA in treated timber products can be an economic, technical and environmental ...
J Holmes


Effect of treatment process on performance of copper-chrome-arsenate. Part 2: Field stake tests
1995 - IRG/WP 95-40046
Pinus radiata sapwood stakes 20 x 20 x 400 mm³ were treated with CCA Type C using a range of concentrations and three treatment processes; Bethell, Lowry and Rueping. Preservative retention was determined by chemical analysis of treated material. Following fixation stakes were installed in a randomised plot in the Whaka graveyard located on the FRI campus. Stakes were inspected at yearly interval...
M E Hedley, J Anderson, J B Foster, B E Patterson


Preliminary studies on cellulase production by selected Basidiomycetes and the effect of copper-chrome-arsenate on these enzymes
1980 - IRG/WP 1122
The growth of wood-destroying fungi on ligno-cellulosic materials depends on the production of many enzymes, of which probably the most important is the multi component cellulase system. Within this system, at least three different kinds of enzym are believed to be involved in crystalline cellulose decomposition. These are endo-1,4-glucanase, exo-1,4-ß glucanase and ß-glucosidase. Most of the re...
O Collett


Wood Preservatives Science Issues: US EPA’s Perspective
2005 - IRG/WP 05-50224-2
The USEPA Office of Pesticide Programs (OPP), Antimicrobials Division (AD), regulates the use of chemicals registered as wood preservatives in the United States. An overview of the registration and re-registration process is presented. The wood preservatives data requirements include toxicological, human exposure, ecological, and environmental fate data. A detailed discussion of wood preservati...
N Elkassabany


Effectiveness of copper/chromium salts as wood preservatives against Limnoria tripunctata Menzies in laboratory tests
1977 - IRG/WP 431
During the last joint meeting of IRG and COIPM a co-operative programme of tests with copper/chromium salts as wood preservatives against marine borers was discussed and agreed. In this connection the results of a laboratory test in the BAM with Limnoria tripunctata Menzies will be of interest. But as the respective paper is written in German (H. Kühne; G. Becker: Laboratoriumsversuche über die ...
H Kühne


Safe application of copper-chrome-arsenate preservatives
1975 - IRG/WP 377
All wood preservatives contain biologically active substances and must, by design, be in some measure toxic to man. There is nothing fundamentally difficult, however, about using a wood preservative with complete safety. It depends on knowing the risks to health and/or the environment, which the preservative may present, and planning application accordingly. In this paper we examine these and othe...
I N Stalker, P B Cornwell


Effects of surfactants and ultrasonic energy on the treatment of wood with chromated copper arsenate
1977 - IRG/WP 3108
Sugar pine stakes 1'' x 1" x 16" were treated by a hot-water bath followed by soaking in cold CCA solution for 10 to 30 minutes. A similar number of stakes were treated by a cold-cold bath. Half of the stakes were subjected to ultrasonic energy during the CCA bath. The mean absorption for stakes given the hot-cold bath was 18.52 pcf (297 kg/m³) and 4.64 pcf (74 kg/m³) for those...
C S Walters


Relative performance of copper/chrome/boron (CCB) and copper/chrome/arsenate (CCA) in ground contact
1992 - IRG/WP 92-3694
The performance of four retentions each of an oxide CCA formulation and a salt formulation of CCB in radiata pine and European beech was compared after 18 years' field exposure. In radiata pine CCA oxide was more effective (4 failures out of 40) than CCB (9 failures out of 40). However, in European beech CCB was substantially more effective (22 failures) than CCA oxide (all failed). Analy...
M E Hedley


Equilibrium distribution of toxic elements in the burning of impregnated wood
2001 - IRG/WP 01-50172
The current work focuses on predicting the behavior of arsenic, chromium, and copper in the burning of impregnated wood. A theoretical method is used to study the chemistry of the system, with special interest directed towards the vaporization tendency of the potentially toxic elements. The core of the study is the global equilibrium analysis that simultaneously takes into consideration all chemic...
K Sandelin, R Backman


Soft-rot control in hardwoods treated with chromated copper arsenate preservatives. Part 3: Influence of wood substrate and copper loadings
1977 - IRG/WP 2100
The hypothesis is proposed that hardwoods need more chromated copper arsenate (CCA) than softwoods to protect them from soft-rot attack mainly because hardwoods are more readily consumed by soft-rot fungi. Simple model systems, using copper-supplemented agar or groundwood pulp treated with CCA showed that fungi tolerated more toxicant (copper) as more available substrate (malt) was provided. Soft-...
M A Hulme, J A Butcher


A survey of the incidence of decay in copper-chrome-arsenate treated trellis support posts used in horticulture in New Zealand
1984 - IRG/WP 1225
Copper-chrom-arsenate treated softwood posts used as trellis support structures in 5 major horticultural districts of New Zealand were systematically examined for presence of decay. Principal crops on properties examined were grapes and kiwifruit; a minority of properties grew hops, boysenberries, and dwarf apples. Occurrence and severity of decay were variable within specific age classes of posts...
M E Hedley, J A Drysdale


Characterization of checks and cracks on the surface of weathered wood
2000 - IRG/WP 00-40153
The surface roughness of unweathered and untreated pine; unweathered copper chromium arsenate type C (CCA) - treated pine; weathered CCA-treated pine; and weathered CCA-plus-water-repellent (WR) - treated pine was evaluated by a stylus tracing method. Surface roughness parameters Ra, Rz, Rmax, Rk, Rpk, and Rvk were measured. Ra, Rpk, and Rvk were the most appropriate parameters for describing modi...
D P Kamdem, Jun Zhang


Performance of Paraserianthus falcataria treated with ACZA, ACQ, CC or CCA and exposed in Krishnapatnam harbour, India
2005 - IRG/WP 05-30382
Paraserianthus falcataria (=Albizia falcataria) treated to two retentions with ammoniacal copper zinc arsenate (ACZA), ammoniacal copper quaternary (ACQ), ammoniacal copper citrate (CC) and chromated copper arsenate (CCA) was assessed over 34 months in a tropical marine waters at Krishnapatnam harbour on the east coast of India. ACZA treatment showed comparatively better resistance than CCA, ACQ a...
B Tarakanadha, K S Rao, J J Morrell


Laboratory studies of CCA-C-leaching: influence of wood and soil properties on extent of arsenic and copper depletion
2002 - IRG/WP 02-50186
The extent which a wood preservative leaches is important for efficacy studies and environmental concerns. However, little information exists on the effect soil properties have on leaching. This study investigated leaching of stakelets which had been cut from five different southern yellow pine (SYP) sapwood boards then treated with CCA-C to a target retention of 6.4 kgm-3 (0.4 pcf). All stakel...
D Crawford, R F Fox, D P Kamden, S T Lebow, D D Nicholas, D Pettry, T Schultz, L Sites, R J Ziobro


Water repellency of wood treated with alkylammonium compounds and chromated copper arsenate
2000 - IRG/WP 00-30231
The comparative water sorption properties of southern pine treated with CCA and several alkylammonium compounds was evaluated for freshly treated wood and for wood after exposure in a fungus cellar. It was found that CCA imparts considerable water repellency to wood which is reduced somewhat after exposure to wet soil. With the exception of a long chain (C20 -C22) compound, the alkylammonium compo...
D D Nicholas, A Kabir, A D Williams, A F Preston


Rapid fixation of Chromated Copper Arsenate (CCA) wood preservatives by microwave treatment
2000 - IRG/WP 00-40184
Rapid microwave heating of freshly chromated copper arsenate (CCA) treated timber indicates that rapid preservative fixation is possible within approximately 40 seconds. The leaching of CCA was evaluated using simulated rainfall. Cost analyses indicates that microwave fixation using an on-line conveyor belt fixation process with an output of 4m3/hour using a microwave power supply of 230 kW costs ...
G Torgovnikov, P Vinden, E Mapanda, P R S Cobham


Diffusion and interaction of components of water-borne preservatives in the wood cell wall
1988 - IRG/WP 3474
This study investigates the rates of diffusion and ultimate distributions of copper and arsenate components of wood preservatives in wood cell walls following vacuum treatment. Adsorption studies of copper on red pine (Pinus resinosa) and trembling aspen (Populus tremuloides) wood confirm the importance of cation exchange reactions on the ultimate distribution of copper in the wood substance and i...
P A Cooper


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