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Laboratory and field trials of novel antisapstain formulations
1997 - IRG/WP 97-30146
This document covers the results of laboratory and field trials of combinations of fungicides formulated using a patented technology (PCT NZ 96/00143). A 3 week laboratory trial that uses radiata pine (Pinus radiata D. Don) branch discs as a substrate was used to determine which combinations possessed a suitable spectrum of fungitoxicity against key sapstain, mould and decay fungi. In particular f...
R N Wakeling, P N Maynard, D R Eden, C M Chittenden, B Carpenter


The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner


Evaluating the resistance of wood-based panel products to fungal attack
1995 - IRG/WP 95-20071
At present there is considerable disagreement among national research institutes within Europe and panel product manufacturers on the most appropriate method of testing and indeed the need for specific biological durability testing. This paper seeks to place before a broader international audience, the issues related to development of a European standard for evaluating the resistance to fungal dec...
R G Lea, R W Berry


Detection of wood decay fungi in wood using a PCR-based analysis
1998 - IRG/WP 98-10279
We have developed a DNA-based assay to reliably detect brown rot and white rot fungi in wood at different stages of decay. DNA, isolated by a series of CTAB and organic extractions, was amplified by the polymerase chain reaction using published universal primers and basidiomycete-specific primers derived from ribosomal DNA sequences. We have surveyed 7 species of brown rot fungi, 7 species of whit...
C Jasalavich, A Ostrofsky, J Jellison


Determination of N-cyclohexyl-diazeniumdioxide (HDO) containing compounds in treated wood using GC-MS
2000 - IRG/WP 00-20201
Beside the biological effectiveness the approval of a chemical wood preservative requires also techniques for the analytical determination of active ingredients in different matrices. Fulfilling of the last requirement is particularly difficult in the case of impregnated timber treated with wood preservatives containing organic compounds. This paper describes a procedure for the determination of t...
P Jüngel, J Wittenzellner, E Melcher


The biological effectiveness of wood modified with heptadecenylsuccinic anhydride against two brown rot fungi: Coniophora puteana and Gloeophyllum trabeum
1992 - IRG/WP 92-3705
A modified soil block test was carried out using wood samples reacted with heptadecenylsuccinic anhydride (ASA). This modification gave good resistance to decay brought about by the brown rot fungi Coniophora puteana and Gloeophyllum trabeum during the twelve week exposure period. Results indicated that there was a good correlation between increased loading of modifying reagent and an increase in ...
C Codd, W B Banks, J A Cornfield, G R Williams


Efficacy of Didecyl Dimethyl Ammonium Chloride (DDAC), Disodium Octaborate Tetrahydrate (DOT), and Chlorothalonil (CTL) against Common Mold Fungi
2004 - IRG/WP 04-30338
The fungitoxic properties of four fungicides, alone and in combination, against four different mold fungi commonly associated with indoor air quality problems were evaluated on two different wood species and sheetrock. The fungicides were chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile) (CTL) in a 40.4% aqueous dispersion, disodium octaborate tetrahydrate (DOT) in two different forms - a ...
J A Micales-Glaeser, J D Lloyd, T L Woods


Alternative technologies for wood wastes recycling - Part A: Supercritical extraction of PAH compounds from wood wastes
1998 - IRG/WP 98-50101-18 a
Alternative technologies have been investigated to detoxify treated wood. Two classes of organic compounds are studied. Creosote-treated wood are classified in France as dangerous wood wastes. A conventional incineration could be provided for these wood wastes but the cost of this elimination could be very high (> 2000 FFR/ton). For these reasons, we have tested two kinds of new processes as al...
L Schrive, C Perre, G Labat


Water-based silicones on wood
1997 - IRG/WP 97-30144
Five waterbased silicones commonly used on masonry where tested as water repellents for wood. The Water Repellent Effectiveness was determined by swellometer-tests and by measuring the water uptake of samples after 24 hours complete immersion and by immersion in a water level of 4 mm for 24 hours. The different methods are compared and discussed. Artificial and natural weathering was performed to ...
D Lukowsky, R D Peek, A O Rapp


Removal of copper, chromium and arsenic from CCA treated wood using boron compounds
2005 - IRG/WP 05-50230
This study evaluates the copper (Cu), chromium (Cr) and arsenic (As) removal from CCA treated wood using boron compounds such as boric acid, borax (sodium tetraborate), and Timbor (DOT, disodium octaborate tetrahydrate) at varying (3 and 5%) concentrations. Remediation processes were taken at 1, 5 and 10 day intervals. Metals in remediated chips or sawdust were then analyzed using ICP and XRF. Res...
B Tarakanadha, T Hata, S N Kartal, W J Hwang, Y Imamura


Tributyltin compounds in wood preservation: Health and safety aspects
1986 - IRG/WP 3396
The toxicity of organotin compounds of the general formula RnSnX(4-n) depends strongly on the type of organic substituent R and on the degree of substitution n. The residues X, not bound through a tin-carbon bond, are however of much smaller influence. Furthermore, there is evidence that hydrolysis of tributyltin esters will occur under environmental as well as under physiological conditions to TB...
H Schweinfurth, P Günzel, H A B Landsiedel, R Lang, R Reimann, C Schöbel, F Siegmund


Influence of carboxylic acids on LEACHING of copper amine based preservatives
2005 - IRG/WP 05-30365
The importance of chromium free preservatives is increasing. Leaching of copper from wood preserved with such solutions is still higher compared to leaching from wood impregnated with copper chromium ones. In order to decrease leaching, different carboxylic acids (octanoic, 2-etilheksanoic, decanoic) were added to copper/amine/boron aqueous solutions. Experiment of leaching of copper from Norway s...
M Humar, P Kalan, F Pohleven


The effectiveness of three tributyltin compounds in beech against soft rot fungi using a soil-bed technique: A preliminary report
1986 - IRG/WP 3390
The effectiveness, towards soft rot fungi, of bis (tributyltin) oxide, tributyltin ethanesulphonate (TBTES) and benzyltributylammonium tributyldichlorostannate in both leached and unleached beech stakes is compared to that of a CCA preservative (Tanalith CT 106), using a soilbed technique. In addition, the effect of test solvent (water or toluene) on the performance of TBTES is evaluated. Total ti...
R Hill, A H Chapman, B Patel, A Samuel, J K Carey


Computer-assisted ranking of potential biocontrol fungi based on data from laboratory screening trials
1993 - IRG/WP 93-10023
Forty two fungal isolates were screened for antibiotic activity. In these sceering tests inhibition of target wood decay fungi was expressed as a series of numerical scores for each isolate. These scores, along with values for 5 other charactetistics, were used to assess the isolates. Using selection indices, isolates were judged on the basis of all the characteristics combined and, ranked in orde...
M W Schoeman, D J Dickinson


Relationship between degradation of wood, cellulose or lignin-related compounds and production of hydroxyl radical or accumulation of oxalic acid in cultures of brown-rot fungi
1994 - IRG/WP 94-10062
The degradation activities of brown rot fungi against wood, cellulose, and lignin-related compounds were measured in cultures containing glucose or wood as a carbon source. Also the activities of one-electron oxidation and hydroxyl radical production and the amount of oxalic acid present in the cultures were measured. The degradation activities of the fungi against wood, crystalline cellulose and ...
S Itakura, T Hirano, H Tanaka, A Enoki


The effect of alternative pre-conditioning procedures on the durability of wood based board materials to decay fungi
1997 - IRG/WP 97-20105
In the biological testing of wood based board materials it has been shown that exposure of boards in a closed vessel system may lead to inaccurate results due to the build up of volatile substances that inhibit the test fungi. It is thought that this is a transitory effect of freshly manufactured boards. In the European standard for testing fungal durability of board materials which is currently u...
S F Curling, R J Murphy, J K Carey


Effectiveness of some microbiocides against the development of molds and sapstain in Pinus elliottii
1981 - IRG/WP 3169
Eleven commercial biocidal formulations were tested in the field to determine their effectiveness in protecting logs and lumber of Pinus elliottii sapwood from sap stain and molds. Among these formulations 2-(thiocyanomethylthio) benzothiazole showed the best performance in controlling both types of fungi. Potassium N-hydroxymethyl-N-methyl dithiocarbamate and the mixture potassium N-methyl dithio...
S Milano


Water repellency of wood treated with alkylammonium compounds and chromated copper arsenate
2000 - IRG/WP 00-30231
The comparative water sorption properties of southern pine treated with CCA and several alkylammonium compounds was evaluated for freshly treated wood and for wood after exposure in a fungus cellar. It was found that CCA imparts considerable water repellency to wood which is reduced somewhat after exposure to wet soil. With the exception of a long chain (C20 -C22) compound, the alkylammonium compo...
D D Nicholas, A Kabir, A D Williams, A F Preston


Antifeedant activities of flavonoids and their related compounds against the subterranean termite, Coptotermes formosanus Shiraki
1999 - IRG/WP 99-10305
Antifeedant activities of some flavonoids and their related compounds against the subterranean termite, Coptotermes formosanus Shiraki were examined with no-choice and two-choice tests. The activities of these compounds were considered in relation to their chemical structures. All flavonoids tested showed antifeedant activities whereas catechinic acid without A-ring and pyran ring in the molecule ...
W Ohmura, S Doi, M Aoyama, S Ohara


Environmental fate of copper-based wood preservatives in different soil substrates - Part 1: Screening of the metal adsorption potential
1998 - IRG/WP 98-50101-21 a
In treatment plants, spillage of wood preservatives onto soil may be of environmental concern. This potential soil contamination served as an objective for a screening study. Three different mineral soils, a mineral substrate and two horticultural substrates are examined for their sorptive potential of copper through mixing with wood preservative solutions. Depending on the soil/substrate charact...
G M F Van Eetvelde, J M Mwangi, F Tack, R Hartmann, M Stevens


The identification of organic compounds in wood using thermal desorption GC-MS - possibilities and limitations
2001 - IRG/WP 01-20224
There is a clear need for the analytical characterisation and identification of organic compounds and their derivatives in different phases especially in timber. In this context the paper describes a rapid and powerful gas chromatographic method for the determination of insecticides, biocides and "other" organic substances in treated and/or modified wood. The main advantage of this procedure is th...
P Jüngel, E Melcher


Preservation of wood-based panels against fungi and insects and and testing its efficiency
1976 - IRG/WP 270
Wood-based panel products which are made of susceptible wood species may be destroyed by fungi under wet conditions and by termites. The glues do not provide sufficient protection unless very high concentrations are applied. Particle boards and fibre boards are not susceptible to beetle infestation, although some species may attack plywood. Various types of preservatives provide sufficient protect...
G Becker, M Gersonde


Applicability of supercritical carbon dioxide to the preservative treatment of wood-based composites
2001 - IRG/WP 01-40199
Treatability of five structural-use wood-based composites (medium density fiberboard, hardwood plywood, softwood plywood, particleboard and oriented strand board) was evaluated when supercritical (SC) carbon dioxide (CO2) was used as a carrier solvent. Treatments were conducted at three temperature 32 levels (25, 35 and 45°C) and two pressure levels [80 kgf/cm2 (7,845 kPa) and 120 kgf/cm2 (11,768...
M Muin, A Adachi, K Tsunoda


Results on field stake tests against termite – Maximum for 8 years examination at Kumamoto in Japan
2003 - IRG/WP 03-10463
Various preservative treated or modified wood and charcoal painting stakes were tested in field, maximum for eight years in Kumamoto, distributed two main termite species, Coptotermes formosanus and Reticulitermes speratus. After two years in field, untreated sapwood of sugi (Cryptomeria japonica) were observed severe attacks by termites, but the preservative treated stakes were observed no signif...
K Suzuki


Effect of point of preservative addition on the mechanical and physical properties of strandboard treated with Tanalith 3485
2000 - IRG/WP 00-40152
Preservative has been added to a PF bonded strandboard at various different stages in the manufacturing cycle and the physical and mechanical properties of the boards have been evaluated (modulus of elasticity, modulus of rupture, thickness swelling, water absorption, internal bond strength, and shear strength). Preservative addition has been examined at five different stages namely green strand d...
G J Goroyias, M D C Hale


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