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Curing Behaviour of Bio-based Phenol Formaldehyde Resin and the Durability Performance of Treated Wood
2025 - IRG/WP 25-20758
The aim of the study is to investigate the curing behaviours of bio-based PF resins treated Japanese Cedar (Cryptomeria japonica). Compared to conventional wood preservatives such as metal-based ACQ, bio-based PF resin was more environmentally-friendly and can store more plant-based carbon inside treated wood. However, all these preservatives have the risk of being leached out. This study conducte...
Y-S Lee, P-Y Kuo


Bio-based thermoset resins for bonding and eco-friendly preservation in the wood industry
2013 - IRG/WP 13-40650
Yellow dextrins and tannins were used in wood adhesives formulation to substitute resins based on formaldehyde. Several formulations were carried out in alkaline aqueous media by varying the weight fraction of two compounds from 10% to 30%. The cross-linking was performed using epichlorohydrin as a reticulant agent. Rheological behaviours and initial adhesion of three liquid formulations, before r...
C Motillon, A Allal, A Visse, F Charrier, B Charrier, A Baldé


Improvement of wood properties by impregnation with liquefied spruce bark based resins
2016 - IRG/WP 16-40761
In this paper, biobased phenolic thermosetting resins are designed to be used as wood stabilization treatment. The originality of the study stands in substituting part of phenol by spruce (picea abies) bark: this is achieved by a liquefaction process in phenol in the presence of sulfuric acid as catalyst. Next, thermosetting resins are synthetized from liquefied bark by condensation on formaldehy...
X Duret, E Fredon, E Masson, P Gérardin


Durability Analysis of Bio-based Phenol-Formaldehyde Resin-Treated Wood
2025 - IRG/WP 25-20753
The aim of this study is to explore the application of bio-based materials in outdoor construction. Enhancing the durability of wood products effectively extends their carbon storage lifespan, making it essential to investigate their long-term durability. The study used commercial resin (CPF) and laboratory-synthesised petro-based phenolic resin (LPF) as control groups. Japanese cedar specimens we...
T-H Lin, P-Y Kuo


Developing a Novel Bio-based PF Resin as Wood Preservative and Explore its Synthesis Route Using RSM Methodology
2025 - IRG/WP 25-41046
Phenol-formaldehyde (PF) resin treatment has long been recognized as one of the most effective and widely used wood preservation methods, offering exceptional durability, dimensional stability, and resistance against biological degradation. However, traditional PF synthesis relies heavily on petroleum-derived phenol, raising concerns about environmental impact and resource sustainability. To date,...
H-C Ye, Y-C Wu, T-H Lin, P-Y Kuo


Effects of acetylation on the dimensional stability and decay resistance of kenaf (Hibiscus cannabinus L.) fiberboard
1996 - IRG/WP 96-40059
The objective of this study was to investigate the influence of the acetylation treated kenaf fiber, Phenol formaldehyde resin content level, and three fungi species on the dimensional stability and decay resistance of high density non wood composition boards. A standard ASTM method was used to evaluate weight loss and thickness change. The linear shrinkage and expansion of each species were also ...
P Chow, T Harp, R Meimban, J A Youngquist, R M Rowell


Laboratory evaluation of phoxim in plywood
2001 - IRG/WP 01-30264
Two types of phoxim treated plywood bonded by phenolic resin glue and urea resin glue were challenged with termites of Coptotermes formosanus Shiraki in laboratory. It was found that the sawdust of phoxim treated plywood bonded by phenolic resin glue was not active or did not kill termites of Coptotermes formosanus Shiraki within the test period. Moreover, the phoxim treated plywood bonded by phen...
Zhong Junhong, Lin Liling, Huang Hong


Dimensional stability, biological resistance, and mechanical properties of phenol-resin-treated particleboard
1990 - IRG/WP 3622
Particleboards were treated with a low molecular-weight phenol-formaldehyde (PF) resin and their enhanced properties were evaluated. Besides dipping of particles in aqeous solutions of resin, and spraying of resin solutions before spray of the conventional phenol-formaldehyde resin for adhesive binder, one step treatment by spraying of the mixture of the low molecular-weight resin and the adhesive...
Y Imamura, H Kajita


Biological resistance of phenol-resin treated wood
1990 - IRG/WP 3602
Biological resistance of PF (phenol formaldehyde resin) - treated wood has been tested in relation to the resin properties, wood species and biological factors. When tested using water-soluble PF (mol. wt. 170), ca. 10% RI (resin impregnation) was enough to suppress the decay of Japanese cedar (Cryptomeria japonica) and western hemlock (Tsuga heterophylla) blocks exposed to Tyromyces palustris (br...
M Takahashi, Y Imamura


Biodegradation of acetylated southern pine and aspen composition boards
1994 - IRG/WP 94-40020
This objective of this study was to investigate the influence of the acetylation treated wood fiber, Phenol-formaldehyde resin content level, two wood fiber species, three fungi species on the dimensional stability and decay resistence of high density composition boards. A standard ASTM method was used to evaluate weight loss and thickness change. The linear shrinkage and expansion of each species...
P Chow, T Harp, R Meimban, J A Youngquist, R M Powell


Effect of alkaline phenolic resin adhesive on the stability of preservatives incorporated into the glue-line of plywood
1991 - IRG/WP 3650
Stability of preservatives was determined by gaschromatographic analysis when they were applied to glue-line treatment of plywoods. Among organophosphorous insecticides, emulsified forms of chlorpyrifos, dichlofention and diazinon were more stable than others. Fenitrothion, pyridafenthion and phoxim were not practically acceptable as emulsifieable forms due to the relatively low recovery rates aft...
S Fushiki, Y Katuzawa


The effects of preservative treatment and exposure to wood degrading fungi on fiber reinforced polymer (FRP) materials used for structural wood reinforcement
2001 - IRG/WP 01-40204
Glass fiber reinforced phenolic (GFRP) composite materials are becoming increasingly accepted for use in the construction industry because they combine advantages of both wood and advanced polymeric materials. Addition of only 1-3% FRP in the tension zone, for example, can typically improve the strength of the hybrid system by 200%. As more applications are found for wood/FRP hybrids, (e.g. lamina...
C Tascioglu, B Goodell


Biological and physical properties of phenolic-resin treated wood before and after natural weathering
1999 - IRG/WP 99-40132
Biological and physical properties of phenolic resin-treated particleboards, which were made from fast growing tress and agrowaste as raw materials, were evaluated before and after natural weathering in tropical climate. The particles were sprayed with a mixture of a low molecular weight phenol-formaldehyde resin (5.0, 7.5 and 10% loading) and the adhesive phenol resin (8% loading). Results with l...
S Yusuf, Y Sudiyani, H Kajita, Y Imamura, M Takahashi


Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon


Glue-line additives for protecting plywood. A review
1978 - IRG/WP 2102
The conclusions of this review are: 1) Insecticidal glue-line additives can be used satisfactorily to protect plywood against insect attack. 2) It is uncertain, in spite of some claims, wether fungicidal glue-line additives can be similarly used to protect plywood against fungi under damp conditiones. There is a need for further work to validate the mycological tests that may be used to investigat...
R Cockcroft


A substantively bonded water repellent treatment based on chromium carboxylates
1985 - IRG/WP 3344
Chromium carboxylates soluble in toluene have been synthesised and applied to Scots pine (Pinus sylvestris) sapwood. Without any further treatment, the compounds may be readily leached from wood surfaces with toluene. After a period of heating however, they become fixed to the cell wall, substantial amounts being resistant to leaching even under reflux conditions for several hours. Treatment of wo...
J K Wright, W B Banks, W J Eilbeck


Eco-Friendly Composites from Bagasse and Soy-based Resin
2009 - IRG/WP 09-40462
In this study, bagasse and soy-based resin were used for producing composite materials. The objective of this study was evaluation of some physical and mechanical properties of boards made of various ratios (100:0, 60:40, 40:60 and 0:100) of bagasse to wood fiber mixtures (wt: wt) with addition of Soy/PF resin at three levels (4, 8 and 10%) and 1.5% wax. All properties were tested according to AST...
G Rassam, B Jamnani


Methods for Studying Penetration Depth of Wood Protection Products
2010 - IRG/WP 10-20432
EN 152 is an accepted standard in Europe for measuring how deep a wood protection product penetrates into the surface of treated pine wood. The method has provided consumers with a wide assortment of products that meet the specifications outlined in the standard. Because the test takes 8 or more months to carry out, artificial ageing procedures have evolved in order to standardize and speed up the...
K Hansen, L Sites, D D Nicholas


Effects of intumescent formulation of vinyl acetate-based coating on flame-retardancy of thin painted red lauan (Parashorea spp.) plywood
2011 - IRG/WP 10-40537
Using intumescent coatings on wood-based materials is an effective method for fire safety. The intumescent coatings consist of four major components: (1) binder resin (BR), (2) carbonizing substance (CS), (3) foam producing substance (FPS) and (4) dehydrating agent (DA). Previous studies have demonstrated that the formulation of the four components strongly influences the performance of coatings. ...
Chih-Shen Chuang, Kuang-Chung Tsai, Te-Hsin Yang, Ming-Kuang Wang, Chun-Han Ko


Effect of bio-resin from cashew nut shell liquid (CNSL) on decay resistance properties of wood
2013 - IRG/WP 13-40649
This study assesses the decay resistance properties of bio-resin modified wood against decay fungi of the Basidiomycota according to the EN 113 protocol. A bio-resin system was developed by ozonolysis process from cashew nut shell liquid (CNSL), a naturally occurring mixture of phenolics. Small wood blocks from sapwood of Scots pine (Pinus sylvestris), Obeche (Triplochiton scleroxylon) and Gmelina...
M Ashaduzzaman, M D Hale, V Tverezovskiy, G A Ormondroyd


Applicability of wood durability testing methods to bio-based building materials
2015 - IRG/WP 15-20561
It is well known that organic materials may be susceptible to attack from a range of fungal organisms and any bio-based material used in locations where there is the possibility of microbiological activity must be expected to be able to withstand or prevent such attack. There are a wide range of test methods and standards in place to test susceptibility although most of these test individual compo...
S F Curling, B K Stefanowski, E Mansour, G A Ormondroyd


Performance of bio-based building materials – viewpoints from the first year of COST Action FP1303
2015 - IRG/WP 15-20572
Maintaining and expanding the market potential for bio-based building products in indoor and outdoor construction uses remains a key activity for industries in the forestry and biotechnological sector, particularly in Europe. Whilst there are ongoing activities within IRG for collecting and populating a database on performance on wood, the performance data for many other (i.e. non-wood) "environme...
D Jones


Modelling the performance of bio-based building materials
2016 - IRG/WP 16-20582
The ‘bio-based economy’ represents a growing area of development globally and covers a wide range of building materials including wood and wood-based products. A ‘bio-based’ material is intentionally made from substances derived from living (or once-living) organisms. In this context it means that the materials and products are made from renewable resources, with the criteria that a renewa...
C Brischke


Enhancing wood properties through bio-based and non-biocidal co-polyesters
2016 - IRG/WP 16-40740
The commonly used wood preservation treatments are nowadays facing huge environmental issues, as well as increasing public concern. As regards those concerns, legislation tends to regulate the use of biocidal preservation chemicals. Thus, it does appear crucial to provide alternatives to the use of biocides to allow different outdoor uses of wood such as for, posts, decking, and cladding or even ...
C L’Hostis, M-F Thévenon, E Fredon, P Gérardin


Lignin-Based Adhesive for Engineered Wood Products
2016 - IRG/WP 16-50319
Lignin as a naturally occurring polyphenolic compound has an excellent potential to replace petroleum-based phenol in formulation of phenol-formaldehyde adhesive that are used in manufacturing of engineered wood products. However, there are three major obstacles in application of polymeric lignin as phenol replacement: 1) low reactivity toward phenol, 2) high molecular weight, and 3) high polydisp...
I Kalami, M Arefmanesh, E Master, M Nejad


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