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Quantification of copper and chromium in field stakes after different exposure times: Remaining metal content and distribution
2013 - IRG/WP 13-50291
In order to determine the distribution of copper and chromium as well as their remaining concentration EN 252 specimens and thicker pine sapwood stakes (non standard format) were treated with a commercial CC salt in a vacuum pressure process. The stakes were installed in the test field of the Institute of Wood Research, Hamburg, in August 2010. In all cases three stakes were removed after 4, 8, 12...
T Liese, M Bahmani, E Melcher


Durability of alternatives to CCA-treated wood - Results from field tests after 11 years exposure
2013 - IRG/WP 13-30633
The present study was initiated as a consequence of restrictions against the use of CCA-type wood preservatives in Sweden in the 1990s. New copper-based formulations were introduced on the market and to some extent, also alternatives to preservative-treated wood, such as thermally and chemically modified and linseed oil treated wood as well as heartwood of non-tropical naturally durable wood s...
P Larsson Brelid, M-L Edlund


Protein extraction from wood decay fungus Postia placenta
2014 - IRG/WP 14-10827
Wood decay fungi (often distinguished as white rot and brown rot) belonging to the basidiomycetes, are common inhabitants of forest litter, where they play an important role in carbon cycling. Brown rot fungi are perhaps the most important organism involved in the degradation of wood products, and of considerable economic importance. Brown rotted wood loses strength very early because of the rapid...
A Pilgård, P Arnold, K Richter


The Chelator Mediated Fenton System in the Brown Rot Fungi: Details of the Mechanism, and Reasons Why it has Been Ineffective as a Biomimetic Treatment in some Biomass Applications – a Review
2014 - IRG/WP 14-10828
The chelator-mediated Fenton (CMF) reaction requires the action of two types of chelating compounds. The first chelator, oxalate, solubilizes and then sequesters iron, and the second chelator reduces iron. Iron reduction must be controlled near the fungal hyphae to prevent damaging Fenton chemistry from occurring in that location. Similarly, iron reduction must be promoted within the wood/plant ce...
B S Goodell, M Nakamura, J Jellison


Changes in mechanical and chemical properties of wood exposed outdoors
2014 - IRG/WP 14-20550
The aim of this study was to investigate differences in certain mechanical and chemical properties of three different wood species (common beach (Fagus sylvatica), Norway spruce (Picea abies), and copper-ethanolamine (CuE) impregnated Norway spruce (Picea abies)) that were exposed in use class 3 (CEN, 2006) for periods between 4 and 30 months. The results show, that changes in the investigated me...
N Thaler, C Brischke, D Žlindra, V Vek, M Humar


Scanning Transmission X-ray Microscopy as a tool for examining chemical changes in wood cell walls due to enzymatic activity
2014 - IRG/WP 14-20556
As development of techniques for examining enzymatic activity on solid, complex biological materials, is considered to be an important factor in further development of enzyme applications and for understanding the decay of plant materials, this study explores applicability of Scanning Transmission X-ray Microscope (STXM) for determining chemical changes in enzymatically treated samples at the cell...
D Jeremic, R Goacher, R Yan, C Karunakaran, E R Master


Resistance to Decay Fungi of Scots Pine Impregnated with Natural and Chemical Preservatives
2014 - IRG/WP 14-30650
In this study, heart-wood and sap-wood specimens of the Scots pine which is naturally grown in Turkey were treated with natural (valex) and some chemical preservatives such as CCA - C (Copper / Chrome / Arsenic), CBA - A (Copper / Boron / Azole). The wood protective efficacies of these preservatives were investigated by means of fungi decay test (EN 113). As a result of the study it was found t...
S Yildiz, U B Şimşek


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Effect of silver nanoparticles on the rate of heat transfer to the core of the medium-density fiberboard mat
2014 - IRG/WP 14-40653
Effect of silver nanoparticles on the rate of heat transferred to the core section of medium-density fiberboard (MDF) mat was studied here. A 400 ppm aqueous nanosilver suspension was used at three consumption levels of 100, 150, and 200 mL/kg based on the weight of dry wood fibers; the results were then compared with the control MDF panels. The size range of silver nanoparticles was 30-80 nm. Res...
H Reza Taghiyari, O Schmidt, E Bari, P M Tahir, A Karimi, P Nouri, A Jahangiri


Thermal durability and biodegradation of tannin lignin adhesives
2014 - IRG/WP 14-40657
Mimosa tannins and lignosulfonates were used in wood adhesives formulation to substitute resins based on formaldehyde. Mimosa tannins were mixed with either glyoxalated sodium lignosulfonates or glyoxalated ammonium lignosulfonates. The ratios of mimosa tannins and sodium lignosulfonates varied from 20% tannins to 60% tannins. The thermal durability of the adhesives were analysed by thermogravimet...
L Chupin, B Charrier, A Pizzi, F Charrier


Termite resistance of wood modified with short- and long-chain siloxanes
2014 - IRG/WP 14-40660
Scots pine (Pinus sylvestris L.) sapwood specimens modified with short- and long-chain amino-functional siloxane emulsions were exposed to subterranean termites (Reticulitermes flavipes Kollar). Laboratory choice and no-choice tests following the standard EN 117 (2013) were conducted for 8 weeks in order to evaluate the influence of these silicon-based compounds on the termite resistance of treate...
P Gascón-Garrido, M-F Thévenon, H Militz, C Mai


Performance of some wood modification treatments against marine borers
2014 - IRG/WP 14-40668
Since some years, new treatment technology to protect wood against wood destroying fungi is introduced. Limited knowledge on their resistance to water organisms is available. Therefore, the resistance of chemically modified wood was assessed in a field test according to the European Standard EN 275 over a period of 3 resp. 5 years at sites in the North Sea and the Baltic Sea. Scots pine (Pinus syl...
A Klüppel, C Mai, H Militz, S Cragg


Possible targets of wood modification in brown rot degradation
2014 - IRG/WP 14-40676
Wood modification protects wood from fungal degradation in a non-toxic manner. However, the mechanisms behind the decay resistance in modified wood are currently unknown. The aim of this study was to discuss the i) colonisation, ii) nutrient recognition, iii) transcription, iv) depolymerisation and v) hydrolysis steps in the brown rot degradation progress and explore whether they are inhibited by ...
R Ringman, A Pilgård, G Alfredsen, B Goodell, K Richter


Lignin Modification to Produce Sustainable Polyurethane Resin for Wood Coatings
2014 - IRG/WP 14-40682
The use of lignin as the most abundant aromatic natural polymer has been evaluated for use in the production of lignin-based polyurethane resin for coating applications. Coatings are made of resins (ca. 50%), which today are mainly derived from petroleum-based polymers. This study is focused on the development of an environmentally friendly method of modifying lignin to be used as source of natura...
M Nejad, M Arefmanesh, S Chandra, J Mostaghimi, E Master


Chemical composition of extractives of different wood compartments of Pinus merkusii and their potential implication in wood durability
2015 - IRG/WP 15-10841
Amounts and nature of extractives differ strongly according to the compartment of wood and to the nature of the wood species. Previous studies reported that knotwood of several European Pinus sp. contains extractives contents much higher than stemwood consisting mainly of lignans which may find valuable applications in cosmetic, nutraceutic or pharmaceutic sectors. Different explanations have been...
A Wijayanto, S Dumarçay, R Kartika Sari, W Syafii, P Gérardin, C Gérardin-Charbonnier


Durability of Fence Posts of Four Wood Species After 20 Years in Field Test
2015 - IRG/WP 15-30670
In the past years, wood consumption from native forests has drastically reduced the availability of wood. Fast-growing species such as Pinus and Eucalyptus suitably impregnated with chemicals may show a service life equal or higher than hardwood with high natural durability. The field tests have been an alternative widely used to evaluate the durability of wood and the efficiency of preservatives....
A Florian da Costa, A C Salgado de Freitas, E Meneses Oliveira


A review of the analytical methods used in determining the decay resistance of heat treated wood
2015 - IRG/WP 15-40690
Heat treatment as a wood process is increasingly used because of its non-biocide behaviour and its low environmental impact. This sort of treatment is based on biopolymer chemical degradation by heat transfer. This process improves mainly the dimensional stability and the decay resistance of wood. Wood becomes darker after this type of treatment and thus gives it an aesthetic appearance. These i...
K Candelier, M-F Thévenon, A Pétrissans, S Dumarçay, P Gérardin, M Pétrissans


A novel enzymatic treatment as a new approach for wood protection
2015 - IRG/WP 15-40701
Wood durability is a worldwide concern and most treatments tend to fail with regard to their efficacy along the time. Weather conditions lead to a loss of the treatment substances into the surrounding environment and, in consequence, generate also a public health concern. Recently, the employment of oxidative enzymes, such as laccases, has been proposed as a tool for lignocellulosics modificatio...
C Fernández-Costas, S Palanti, M Ángeles Sanromán, D Moldes


Minimum standards for habitability in emergency housing
2015 - IRG/WP 15-50312
In this study we evaluated the properties of a prefabricated HOUSING prototype based on a 64mm thick "Structural Insulated Panel" (SIP; hereinafter SIP64), built by two OSB panels bonded with a two component polyurethane adhesive to a high density expanded polystyrene core. This panel was manufactured as a main element for walls in the construction of emergency housing. The thermal insulation of t...
R Garay, F Pfenniger, W Figueroa


High-frequency monitoring of mass loss due to brown rot degradation of modified wood
2016 - IRG/WP 16-10862
Fungi growing in liquid culture undergoes three separate phases in which they i) adapt to the new environment, ii) grow unrestrictedly and exponentially, and iii) are inhibited to increase in number/mass due to lack of nutrients etc. Filamentous fungi have been shown to exhibit similar growth phases in a solid food substrate and have been modelled to grow in this way also in solid wood. In modifie...
R Ringman, A Pilgård, K Richter


On the effect of climate and exposure conditions on durability indicators and their potential for service life prediction of wood-based products
2016 - IRG/WP 16-20576
In order to encourage increased use of wood, different user groups need to be better informed regarding the variation in performance between different wood materials and the effect of different use classes. It is also important to provide good empirical data on the service life of wood products as input to for example life cycle assessment studies. In the current study the effect of temperature an...
G Alfredsen, C Brischke, P-O Flæte, M Humar, L Meyer-Veltrup


Characterization of waste from Pinus radiata generated during industrial thermal-treatment
2016 - IRG/WP 16-20586
The thermal-treatment is an established chemical-free process to modify wood, improving the durability and physical properties of wood through its service life. During the hydro-thermolysis several reactions from wood components occur, releasing volatile and non-volatile compounds from wood to the chamber. Once the process is accomplished, solid residues agglomerate below the wood load and gaseous...
R Herrera, D Thomas da Silva, R Llano-Ponte, J Labidi


Wood properties modification by an enzymatic assisted treatment with phenolic extractives
2016 - IRG/WP 16-30696
Extractives of sawdust and bark from P. pinaster and, condensed tannins (CTs) from P. radiata bark were used to treat beech and pine veneers in combination with an oxidative enzyme, in order to stably graft such extractives onto the veneers. First, the antifungal activity of P. pinaster phenolic extractives against wood decay fungi was studied. These extractives were also used to hydrophobize pi...
D Filgueira, C Fernández-Costas, D E García, D Moldes


Increasing the hardness of wood-composite panels by nanosilver
2016 - IRG/WP 16-40715
Effect of silver nanoparticles on hardness in medium-density fiberboard (MDF) was studied here. A 400 ppm aqueous nanosilver suspension was used at three consumption levels of 100, 150, and 200 mL/kg, based on the dry weight of wood fibers; the results were then compared with the control panels. The size range of silver nanoparticles was 30-80 nm. Composite mats were hot-pressed for 6, 8, and 10 m...
H R Taghiyari, J Norton, K Heidarhaee


How intraspecific radial variability of the European Oak’s may influence mild pyrolysis process and durability of the material
2016 - IRG/WP 16-40725
Last decades wood is promoted as building material. Unprotected wood exposed to outdoor conditions undergoes a variety of degradation induced essentially by fungi attacks. Heat treatment of wood by mild pyrolysis (180°C T 240°C under inert atmosphere) is a preservation process with a weak environmental impact, and therefore, is viewed as an interesting alternative to the chemical impregnation me...
J Hamada, A Pétrissans, F Mothe, M Pétrissans, P Gérardin


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