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Kiln drying of CCA-treated wood - Some safety and environmental considerations
1987 - IRG/WP 3443
Vapours and condensate from a condenser kiln in which CCA-treated wood was being dried have been collected and analysed. The concentrations of arsenic, copper and chromium found in the vapours from the drying process were well below Swedish threshold limit values. The contents of arsenic and chromium were also low in the condensate, although the copper content was fairly high. The latter result wa...
J Jermer, B Lundberg


Applications of the shower test. Part B: Results from CC and CCB treated wood: influence of fixation process
1993 - IRG/WP 93-50010
This report outlines the results of shower tests conducted on CC and CCB treated wood. The results indicate the fairly good fixation of chromium and the reasonable fixation of copper in CC and CCB formulations, as judged by the leaching limits within the Environmental Regulations. In general boron leaches to a higher extent than chromium and copper. The shower test has proven to be a useful qualit...
W J Homan, H Militz


Performance of copper-based wood preservatives in above ground and ground contact tests
1994 - IRG/WP 94-30057
The relative performance of a range of copper-based wood preservatives was compared using above ground and ground contact procedures. The data, accumulated after several years' testing, show that on an equivalent active ingredient basis, differences in performance of the preservative systems tested can vary quite markedly. The contribution of co-biocides to the overall performance of thes...
A F Preston, K J Archer, L Jin, W Metzner, D Seepe


Wood Preservatives Science Issues: US EPA’s Perspective
2005 - IRG/WP 05-50224-2
The USEPA Office of Pesticide Programs (OPP), Antimicrobials Division (AD), regulates the use of chemicals registered as wood preservatives in the United States. An overview of the registration and re-registration process is presented. The wood preservatives data requirements include toxicological, human exposure, ecological, and environmental fate data. A detailed discussion of wood preservati...
N Elkassabany


Assessment of the toxicity of some copper-, zinc- and boron-based wood preservatives to the cellar fungus Coniophora cerebella Schröet
1974 - IRG/WP 242
This article reports the use of a method based on the determination of the probability of the protection of timber against destruction by fungi. By converting the probability values to probit values and plotting them as a function of the amount of preservative retained in the timber, curves of the toxic effect are obtained, enabling any timber protection probability to be assessed....
V N Sozonova, D A Belenkov


Effectiveness of copper/chromium salts as wood preservatives against Limnoria tripunctata Menzies in laboratory tests
1977 - IRG/WP 431
During the last joint meeting of IRG and COIPM a co-operative programme of tests with copper/chromium salts as wood preservatives against marine borers was discussed and agreed. In this connection the results of a laboratory test in the BAM with Limnoria tripunctata Menzies will be of interest. But as the respective paper is written in German (H. Kühne; G. Becker: Laboratoriumsversuche über die ...
H Kühne


Experiences with penetration of copper-based wood preservatives
2001 - IRG/WP 01-20233
In the Nordic countries there is a long tradition of result type based specifications for preservative-treated wood. A common Nordic standard for treated pine (Pinus sylvestris) wood was published in 1976. After a revision in 1989 this standard, then named INSTA 140, defined four classes of treated wood: M, A, AB and B. Treaters producing according to this standard had to be affiliated to a qualit...
J Jermer, F G Evans, I Johansson


Susceptibility of CCB treated wood to fungal colonization
2003 - IRG/WP 03-10492
CCB treated wood is generally resistant to all wood decay fungi. However, like CCA impregnated wood, susceptibility of CCB treated wood to copper tolerant fungi have been observed. The ability of various brown rot fungal hyphae to penetrate and overgrow the wood samples was investigated. Samples made of Norway spruce (Picea abies) were impregnated with 5 % CCB solution according to the EN 113 proc...
F Pohleven, U Andoljsek, P Karabegovic, C Tavzes, S A Amartey, M Humar


Report on the burning of wood treated with wood preservatives containing copper, chromium and arsenic
1976 - IRG/WP 379
Mixtures of copper, chromium and arsenic salts are used extensively in the UK to preserve timber. This report is concerned with the fate of these metals when timber treated with these salts is burned. A large percentage of the arsenic present in the timber is shown to be volatilised during combustion and the potential environmental implications of this are assessed by comparison with the release o...
A J Dobbs, C Grant


Some data on the activity of alternative fungicides for wood preservation
1985 - IRG/WP 3333
Data from laboratory tests against basidiomycete fungi are presented for 9 alternative fungicides in organic solvent formulations and also in water for one product. Results are compared with data for reference preservatives, tributyltin oxide, copper and zinc naphthenates and pentachlorophenol. Of special interest is the apparently better than additive effect of mixing tributyltin naphthenate and ...
A F Bravery, J K Carey


Evaluation of the corrosivity of the treated wood - Laboratory vs field test methodologies
2000 - IRG/WP 00-20211
The corrosivity of treated wood to fasteners has been evaluated using laboratory test procedures, including AWPA Standard E12-94. The standard method was modified in order to allow detailed study of commercial metal fasteners in terms of sample types, installation configuration and exposure conditions. Parallel field tests were also performed. The experimental results generated from these tests su...
L Jin, A F Preston


Copper leaching from Kemwood ACQ and Embalit CBC treated wood products
2000 - IRG/WP 00-50150
TNO has performed a study on the leaching of copper from Kemwood ACQ and Embalit CBC treated wood products, further referred to as ACQ and CBC. The sawn dry wood has been impregnated using an industrial vacuum-pressure process with ACQ (with or without Ultrawood 4) or with CBC, under supervision of Flexchemie B.V. After treatment samples have been transported and subjected to leaching tests at TNO...
P Esser, W L D Suitela, H Trompetter


Natural exposure weathering tests: Their role in the assessment of wood preservative efficacy
1993 - IRG/WP 93-20006
Previous work has demonstrated the potential and usefulness of natural ageing procedures in e evaluation of wood preservative efficacy. This results from the combination of physico-chemical influences and microbiological interactions with both substrate and wood preservative. In this paper, results are presented for a range of biocide types. Discussions are centred on the value of natural exposure...
G R Williams, J Brown


Evaluating the natural durability of native and tropical wood species against Reticulitermes flavip
2004 - IRG/WP 04-10539
Environmental pressures to eliminate arsenate from wood preservatives has resulted in voluntary removal of CCA for residential applications in the United States. A new generation of copper organic preservatives has been formulated to replace CCA for decking and in-ground applications but there is no guarantee that these preservatives represent a permanent solution to all related problems. There...
R A Arango, F Green III, K Hintz, R B Miller


Effects of surfactants and ultrasonic energy on the treatment of wood with chromated copper arsenate
1977 - IRG/WP 3108
Sugar pine stakes 1'' x 1" x 16" were treated by a hot-water bath followed by soaking in cold CCA solution for 10 to 30 minutes. A similar number of stakes were treated by a cold-cold bath. Half of the stakes were subjected to ultrasonic energy during the CCA bath. The mean absorption for stakes given the hot-cold bath was 18.52 pcf (297 kg/m³) and 4.64 pcf (74 kg/m³) for those...
C S Walters


Laboratory evaluation of metallic naphthenates as wood preservatives
1991 - IRG/WP 3654
Fungicidal and termiticidal efficacy of copper and zinc naphthenates was appraised according to Japanese standardized laboratory testing methods. Copper and zinc naphthenates succeeded in protecting wood from decay fungi at retentions of 0.5 and 1.0 kg/m³ as metal, respectively. [JIS A 9302 (1976)] when they were applied to vacuum/soak impregnation [JIS A 9301 (1976)]. With respect to the fungici...
K Tsunoda, M Sakurai


The influence of copper (II) chemicals on the weathering of treated wood. Part 1: ACQ treatment of wood on its weathering
1994 - IRG/WP 94-30040
Wood weathering can be accelerated by alkylammonium compound (AAC) treatment, and slowed by ammoniacal copper quat (ACQ) treatment. This study aims at investigating the influence of ACQ treatment of wood, especially the present of copper (II), on its weathering. ACQ, CCA and DDAC treated microtomed sections of southern yellow pine earlywood were prepared and naturally weathered for five periods, t...
Ruiying Liu, J N R Ruddick, L Jin


Inorganic preservatives in wood dust - Cause of nasal cancer?
1997 - IRG/WP 97-50085
Since 1985 dust particles from beech and oak trees have been classified by the Senate Commission of the German Research Council (DFG) as being ,,working materials which are definitely carcinogenic to humans". All other wood dusts, including those from softwoods, are classified as being materials ,,with reasonable suspicion of carcinogenic potential". The carcinogenic principle of action continues ...
A O Rapp, K Brandt, R-D Peek, U Schmitt


Determination of absorption, accumulation and transport of copper in mycelium of some wood decay fungi
1999 - IRG/WP 99-10323
Copper compounds are common wood preservatives. However, tolerance of some wood decay fungi to copper compounds has been observed recently. Therefore, we tried to elucidate possible causes of this phenomenon. We investigated uptake, accumulation and secretion of copper in the mycelium of potentially copper tolerant fungi (Antrodia sp.) and non tolerant fungus Trametes versicolor. We observed that ...
F Pohleven, S Breznikar, P Kalan, M Petric


Serpula lacrymans, The Dry Rot Fungus and its Tolerance towards Copper-based Wood Preservatives
2005 - IRG/WP 05-10555
Serpula lacrymans (Wulfen : Fries) Schröter, the dry rot fungus, is considered the most economically important wood decay fungus in temperate regions of the world i.e. northern Europe, Japan and Australia. Previously copper based wood preservatives were the most commonly used preservatives for pressure treatment of wood for building constructions. Because of a suspicion about tolerance toward cop...
A C Steenkjær Hastrup, F Green III, C A Clausen, B Jensen


Ability of chitosans to limit wood decay under laboratory conditions.
2004 - IRG/WP 04-30339
Chitosans have recently been explored for controlling a number of plant pathogenic fungi and have shown some promise for controlling stain fungi on wood. The potential for using chitosans either alone or in combination with copper sulfate to protect wood from fungal decay was explored using maple veneers. Chitosan treatment reduce weight losses caused by two brown rot and one white rot fungi, howe...
M Maoz, J J Morrell


Observations on the performance of copper-based wood preservatives in fungal cellar (soil-bed) tests
1994 - IRG/WP 94-20047
Fungal cellar (soil-bed) tests are considered to be an important tool for the evaluation of the performance of ground contact wood preservatives. Facilities of this type have been established world wide although caution has been exercised in their introduction into standard testing methods for the approval of wood preservatives. This is the result of concerns over the variability in the biological...
G R Williams, D Rudolph, M E Hedley, J A Drysdale, R F Fox


Description of a trial with wood preservatives against marine wood boring organisms
1975 - IRG/WP 412
Wood situated in sea water along the Atlantic coasts of the Nordic countries is attacked by marine wood boring organisms. Timber constructions in these waters therefore must be preservative treated. In order to evaluate the effect of various preservatives against marine wood borers, the Nordic Wood Preservation Council (NWPC) organized a rather extensive trial in 1972. In the absence of and while ...
E Norman, B Henningsson


A comparison of the leaching resistance of diammine-copper complexes and copper carbonate precipitated in wood
1997 - IRG/WP 97-30158
Previous studies have shown that during treatment of wood with ammoniacal copper solutions, both simple copper precipitates and diammine-copper complexes are formed. The objective of the present study is to determine the relative importance of both forms of copper, on such aspects as preservative leachability and biological performance. In the current experiment, the leachability of copper carbona...
Xiao Jiang, J N R Ruddick


Equilibrium distribution of toxic elements in the burning of impregnated wood
2001 - IRG/WP 01-50172
The current work focuses on predicting the behavior of arsenic, chromium, and copper in the burning of impregnated wood. A theoretical method is used to study the chemistry of the system, with special interest directed towards the vaporization tendency of the potentially toxic elements. The core of the study is the global equilibrium analysis that simultaneously takes into consideration all chemic...
K Sandelin, R Backman


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