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Long-term effectiveness of fumigants in controlling decay in Douglas fir waterfront timbers
1986 - IRG/WP 3364
The persistence, movement, and effectiveness of chloropicrin and Vapam (sodium N-methyl dithiocarbamate) in large, horizontal Douglas fir timbers were evaluated 7 years after fumigation. Chloropicrin prevented reestablishment of decay fungi; reinvasion occurred in some Vapam-treated timbers. Residual fungistatic effect was detected up to 1.2 m from the fumigation site in chloropicrintreated timber...
T L Highley


Preservatives treatment and field test monitoring of spruce pole stock: CCA and fumigant treatments
1990 - IRG/WP 3619
The fumigants trichloronitromethane (chloropicrin) and sodium N-methyldithiocarbamate (SNMDC) were used to treat red spruce pole stock, either CCA treated or untreated, through holes bored through the pole's center. The poles were analyzed for the presence of microorganisms immediately before ground installation and again after installation at a pole test site. Monitoring of fumigant move...
A J Pendlebury, B Goodell


Methods for testing fumigant efficacies against termites
1986 - IRG/WP 1297
Methodologies for testing fumigants against termites are reviewed and factors needed to be taken under consideration for standardization listed. Toxicity should be defined by both direct exposure to the gas and under more practical "barrier" conditions which include test enclosures simulating abiotic surroundings of the termites, i.e. wood, nest material, etc. To observe latent effects, mortality ...
N-Y Su, R H Scheffrahn


The effect of selective additives and conditions on the decomposition of Basamid in Douglas fir heartwood
1992 - IRG/WP 92-3698
Basamid is a solid, powdered chemical used as an agricultural soil fumigant. Decomposition of Basamid isothiocyanate, hydrogen sulfide, methyl amine, and formaldehyde. Basamid has some potential as a wood fumigant, but it decomposes too slowly to be effective. Various additives and conditions were tested for their ability to enhance Basamid decomposition in Douglas-fir heartwood. Higher MC&apo...
P G Forsyth, J J Morrell


Chemical Analysis of Southern Pine Pole Stubs Thirty-Nine Months Following Treatment with Three Methylisothiocyanate-Based Fumigants
2004 - IRG/WP 04-30349
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC-based fumigants, liquid metham sodi...
R J Ziobro, J Fomenko, D J Herdman, J Guzzetta, T Pope


Performance if internal remedial treatments to arrest fungal attack in poles and large timbers
2018 - IRG/WP 18-40834
Internal remedial treatments have been used to arrest internal fungal attack in utility poles and other large timbers. Water diffusible systems and volatile fumigants have both been used for this purpose. While both work, it is important to understand the performance attributes of each system. This paper reviews the literature on both systems and makes recommendations for future research....
J J Morrell


Movement and persistence of Dazomet and pellected methylisothiocyanate in wrapped Douglas fir and southern pine timbers
1991 - IRG/WP 1496
The movement and persistence of Dazomet (tetrahydro-3,5-dimethyl-2 H-1,3,5 thiadiazine-6-thione) and pelleted methylisothiocyanate (MIT) was evaluated in wrapped Douglas-fir and Southern Pine timbers. MIT pellets did not impart a fungistatic effect to any of the timbers. Failure of MIT was probably due to loss of MIT from pellets prior to application. Fungistatic effect of Dazomet was consistently...
T L Highley


The influence of wood moisture content on the fungitoxicity of methylisothiocyanate in Douglas fir heartwood
1987 - IRG/WP 3430
The fumigant methylisothiocyanate (MIT) effectively controls decay fungi in large wood structures, but the influence of environmental factors on its performance are not well understood. Experiments found wood moisture content to greatly influence the fungitoxicity and sorption of MIT in Douglas fir heartwood. At constant, low MIT vapor concentrations (less than 1 µg/cc air), wood at 10% MC bound ...
A R Zahora, J J Morrell


A laboratory evaluation of the fumigant, sulfuryl fluoride (VikaneR), against the Formosan termite Coptotermes formosanus Shiraki
1982 - IRG/WP 1164
A series of laboratory experiments showed that the fumigant sulfuryl fluoride (VikaneR) was effective against small groups of Coptotermes formosanus Shiraki exposed to the gas directly at temperatures from 20-40°C. At 10°C fumigations failed regardless of initial gas concentration. Very high or total mortality was observed at concentrations of 0.79 cc/L or higher. A second series of experiments ...
J P La Fage, M Jones, T Lawrence


Effect of fumigant residue in aerated wood blocks on the spore germination of decay fungi
1991 - IRG/WP 2382
Fumigants are increasingly used in several countries for remedial treatments of transmission poles to increase the service life. The present study was initiated primarily to test the remaining toxic effects of spruce (Picea rubra) wood, fumigated with chloropicrin (trichloronitro methane) or MIT (Methyl isothiocyanate) after long period of aeration, on the spore germination of decay fungi. This st...
J Bjurman, B Goodell


Preliminary modelling of methylisothiocyanate movement through Douglas fir transmission poles
1988 - IRG/WP 3466
Methylisothiocyanate is a volatile solid that is the active ingredient of several registered and experimental wood fumigants. Information on the sorption and diffusion of this chemical in Douglas-fir heartwood and sapwood was used to develop a two-dimensional model of fumigant movement within a single horizontal cross-section of a transmission pole. The model indicated that dry wood (14% MC) stron...
A R Zahora, P E Humphrey, J J Morrell


Effect of wood species on decomposition efficiency of metham sodium
1992 - IRG/WP 92-3699
The effect of wood species and temperature on efficiency of metham sodium (32.1% sodium N-methyldithiocarbamate) decomposition to methylisothiocyanate (MITC) was investigated on 10 hardwoods and 9 conifers over a 144 hour period. Gas chromatographic analyses of headspace samples and ethyl acetate extracts of the wood revealed that decomposition never approached the theoretical decomposition effici...
J J Morrell


On the effectiveness of fumigants against wood-destroying insects and fungi in wooden cultural property
1993 - IRG/WP 93-10030
Based on a survey of the history of the use of fumigants the actual agents are mentioned in relation to their biogenic effect on wood-destroying insects and fungi as well as their corrosive behavior on cultural property. Furthermore the conditions for the use of reactive fumigants in buildings are discussed. Trials to control wood-destroying insects and fungi by nitrogen and bromomethane are the m...
W Unger, A Unger


Ability of chloropicrin, Vorlex, or methylisothiocyante to prevent marine borer attack of Douglas fir piling
1989 - IRG/WP 4153
The preservative-treated shell around Douglas-fir piling is an excellent barrier to attack by marine borers; however, damage to this shell can permit marine borer attack. The feasibility of using fumigants to enhance piling performance was examined by exposing fumigant-treated Douglas-fir sections in marine waters off Newport, OR, or Port Hueneme, CA. The piling were inspected annually and increme...
M A Newbill, J J Morrell


Cell wall microdistribution of chloropicrin and methylisothiocyanate in treated spruce
1989 - IRG/WP 3548
Chloropicrin and methylisothiocyanate (MIT) residues were observed using SEM/EDXA and TEM/EDXA in treated spruce wafers that had been exposed to the vapors of the two fumigant preservatives. Chlorinated residues from chloropicrin were found throughout the wood cell wall, even in acetone extracted material. The residues were most heavily concentrated in extractive materials in the rays, but unlike ...
G F Daniel, B Goodell


Efficacy of fumigants in the eradication of decay fungi implanted in southern pine timbers
1986 - IRG/WP 3365
Southern pine timbers (15.2 cm x 15.2 cm x 4.26 m) were fumigated at midlength to evaluate the effectiveness of the fumigants chloropicrin, Vapam, Diazomet, Busan 40, Vanicide 51, Vanicide TH, sodium bisulfite, and ethanolamine in eradication of decay fungi. The fumigants were introduced into 2.54 cm holes which were closed immediately with rubber stoppers. Movement and persistence of lethal conce...
T L Highley, W E Eslyn


Chemical Analysis of Southern Pine Pole Stubs Thirteen Months Following Treatment with Three Methylisothiocyanate Based Commercial Fumigants
2002 - IRG/WP 02-30294
Agricultural fumigants have been commercially used in the United States for over 20 years to control internal decay in utility poles and other wooden structures. Of the four fumigants which are currently used in the remedial treatment of utility poles, three are based on methylisothiocyanate (MITC) as being the principal fungitoxic component. Two of these MITC based fumigants, liquid metham sodi...
R J Ziobro, T C Anderson, D J Herdman, J Guzzetta, T Pope


Protection of pile tops using combinations of internal treatments and water shedding caps
1993 - IRG/WP 93-30020
Preservative treatment produces an excellent barrier against fungal, insect, and marine borer attack; however, fabricators often disrupt this barrier during construction, creating avenues for entry of decay agents. This problem is particularly acute in marinas along the coastal United States. Standards recommend the application of a water-shedding cap at the time of installation to prevent pile to...
P Schnieder, M A Newbill, J J Morrell


Effect of wrapping on movement of chloropicrin, Vapam, and Vanicide TH in southern pine timbers
1987 - IRG/WP 3411
Important fungi that decay wood protucts were "inoculated" into nonpressure-treated southern pine timbers as vapor-sensing agents to evaluate the effect of wrapping on the movement and persistence of fungitoxic concentrations of chloropicrin, Vapam, and Vanicide TH in the timbers. Fumigant movement and persistence in the timbers was enhanced by wrapping the timbers in polyethylene after fumigation...
T L Highley


The use of fumigants for controlling decay of wood: a review of their efficacy and safety
1989 - IRG/WP 3525
Volatile agricultural chemicals (fumigants) such as chloropicrin (trichloronitromethane) and sodium n-methyldithiocarbamate have been used in the United States for controlling internal decay of large dimension wood products for over 20 years. This usage has been concentrated in the electric utility industry, but fumigants are increasingly applied to protect bridge timbers, marine piling, and even ...
J J Morrell


Gelatin encapsulated fumigants for wood fumigations: Current research status
1985 - IRG/WP 3336
The fumigants chloropicrin (trichloronitromethane) and methylisothiocyanate (MIT) were encapsulated in gelatin as an alternative to liquid fumigant treatments for control of decay fungi in wooden utility poles. Gelatin-encapsulated MIT was stored for over 2 years under dry conditions without significant fumigant leakage. Gelatin encapsulated MIT and chloropicrin were released from capsules when pl...
A R Zahora, M E Corden, J J Morrell


Selecting fumigants for treatment of internal decay in wood
1986 - IRG/WP 3370
A number of potential fumigants were screened with respect to their toxicity to decay fungi, (Poria carbonica, and Lentinus lepideus) and their sorption characteristics on Douglas Fir (Pseudotsuga menziesii Mirb. Franco) wood. Wafers of infected wood were exposed to different fumigant concentrations for various times then cultured to determine viability. The lethal concentration X time (ct) factor...
P A Cooper


Movement of chloropicrin, Vapam, and methylisothiocyanate in southern pine and Douglas fir timbers
1987 - IRG/WP 3410
Douglas fir and southern pine timbers, 15.2 x 15.2 x 426 cm³ (6-in x 6-in x 14-ft), were "inoculated" with brown-rot and white-rot fungi as vapor-sensing agents to evaluate the movement and distribution of fungitoxic concentrations of chloropicrin, Vapam, and methylisothiocyanate (MIT) over a 20-week period. Residual fumigant in timbers was determined by a bioassay with Gloeophyllum trabeum. The ...
T L Highley


Use of Internal Remedial Treatment to Extend Wood Life at the Fort Vancouver National Historic Site
2010 - IRG/WP 10-30525
The condition of wood in a reconstructed fur trading fort was assessed over a 30 year period. Poor initial treatment had resulted in the development of extensive early decay. While supplemental treatment with chloropicrin and methylisothiocyanate had arrested the attack, the results suggested that remedial treatments were unable to completely overcome the initial problems associated with treatmen...
C S Love, C Freitag, J J Morrell


Screening method to test efficacy of fumigants against fungi and preliminary data on the efficacy of sulfuryl fluoride
2014 - IRG/WP 14-20551
Methyl bromide is being phased out and there is an urgent need to find a suitable replacement that is effective in reducing exotic pest establishments via trade in wood products. Efficacy data for established phytosanitary fumigants were mostly developed for arthropods and nematodes, and limited information exists for plant pathogens. Increased interest in developing a fast screening process for f...
A Uzunovic, A Mukherjee, R Mack, P Elder, S Myers


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