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Non-enzymatic Gloeophyllum trabeum decay mechanisms: Further study
2001 - IRG/WP 01-10395
Information will be presented on the mechanisms involved in, and potential application of, non-enzymatic wood decay by brown rot decay fungi. Specifically, the hypothesized role of low molecular weight phenolate derivatives will be discussed in relation to non-enzymatic degradation of wood. The mechanism of binding of iron by cellulose, and binding and reduction of iron by fungal derivatives and m...
B Goodell, J Jellison


The effect of low molecular weight chelators on iron chelation and free radical generation as studied by ESR measurement
2000 - IRG/WP 00-10367
The focus of this work was to improve our current knowledge of the non-enzymatic mechanisms involved in brown-rot decay. Electron Spin Resonance (ESR), also known as Electron Paramagnetic Resonance (EPR), is an attractive technique for the identification and study of chemical species containing unpaired electrons (such as radicals and certain transition metal species). ESR spin-trapping techniques...
Yuhui Qian, B Goodell


Chelator-Mediated Fenton Chemistry in Wood Degraded by Fungi
2007 - IRG/WP 07-10618
Wood specimens were colonized by individual isolates of brown rot, white rot, soft rot and blue (sap) stain fungi. Ethyl acetate extracts of the ground wood were analyzed for their iron-reducing capabilities using a ferrozine-based assay. Extracts from wood colonized by brown rot fungi showed a significantly greater iron-reducing capability than extracts from wood colonized by white rot fungi or n...
B Goodell, G Daniel, J Jellison, Yuhui Qian


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Iron promotes decay capacity of Serpula lacrymans
1993 - IRG/WP 93-10008
The influence of iron and iron compounds on the decay capacity of Serpula lacrymans was studied. Mass losses of pine wood caused by dry rot fungus were increased when FeSO4 was added into the culture medium or when there were iron nails or stone wool on the culture medium. This supports the hypothesis that iron in stone-based building materials is one reason for the increased decay capacity of Ser...
L Paajanen


A discussion of current theories concerning CCA fixation
1983 - IRG/WP 3238
The understanding of the fixation mechanism of CCA and related preservatives in wood has been greatly improved by a significant series of recent scientific papers. In view of recent concerns in New Zealand regarding the long-term efficacy of CCA in high decay-hazard situations, it was considered appropriate to review this recent work and to contrast it with theories presented by previous workers....
D V Plackett


Prevention of brown-rot decay by chelators
1992 - IRG/WP 92-1540
In this work the brown-rot decay was shown to be prevented by chelating the endogenous metals existing in wood by using organic or inorganic chelators or iron-binding siderophores. The fungal growth and decaying ability were significantly decreased by the chelating treatments of the solid wood-based culture medium and pine wood pieces, respectively. The transition metals existing in native wood ar...
L Viikari, A-C Ritschkoff


Research on the effects of wood preservatives on the physical and mechanical properties of Iranian beech (Fagus orientalis Lipsky)
1985 - IRG/WP 3351
This research work was conducted with the aim of using preservatives such as Basilit and Wolman Salts with Iranian beech and to study any physical and mechanical changes these might have on the beech species of Iran. Samples were divided into three groups; one group were used as untreated controls, the second group was treated with Basilit and the third group was treated with Wolmanit. Results obt...
P Niloufari


Elimination of alternative explanations for the effect of iron on treated wood
1993 - IRG/WP 93-30006
Amounts of iron which had previously been found in stakes removed from ground contact reduced decay of untreated wood by four brown-rot fungi. This suggested that the effect of iron may be on the preservative. Analysis of the leachates from CCA- and ACA-treated wood blocks first exposed to rusting iron, then to a brown-rot fungus, showed that the increased decay found in the laboratory for wood ex...
P I Morris, J K Ingram, D L Gent


A short note on the subject of pretreatment decay in wood
1984 - IRG/WP 1245
The paper reviews five national standards for wood utility poles and some literature that concerns the problems of pretreatment decay. Finally it is proposed to form a new sub-group to study that problem....
J A Taylor


Disposal of treated wood - Canada
1990 - IRG/WP 3563
It is estimated that treated wood removed from service each year in Canada contains about 16,000 tonnes of creosote, 1000 tonnes of pentachlorophenol and 245 tonnes of CCA or ACA. The amount of CCA treated wood for disposal is expected to increase more than ten-fold by the year 2020. At present, most treated wood is disposed of in landfills, burned (creosote only) or recycled as other products. Ot...
P A Cooper


Metal carboxylates for wood pest control
1996 - IRG/WP 96-30109
Metal carboxylates have been used as wood preservatives for more than fifty years. Predominantly salts of naphtenic acids have been commercially applied so far. They have water repellent as well as fungicidal and insecticidal properties. In the last years, metal carboxylates of saturated fatty acids were introduced. Fatty acids with 7-10 carbon atoms already have fungicidal activity by themselves....
F Pohleven, M Petric


Penetration of deltamethrin in micro-emulsion formulation after injection in wood
1996 - IRG/WP 96-40068
In the Netherlands (and some other European Countries) the remedial treatment of death watch beetle is still a problem. This is because the larvae of this insect penetrate the central heartwood of mainly large oak beams. The heartwood is difficult to treat. The preventive treatment of wood boring insects has only recently been permitted in the Netherlands. Since 1989 injection of insecticides is r...
P Esser, W L D Suitela


Methods of assessing decay in poles in service with the Pilodyn wood tester
1978 - IRG/WP 2107 A
H Friis-Hansen


Available iron promotes brown rot of treated wood
1992 - IRG/WP 92-1526
Exposure of treated wood blocks to rusting iron increased the toxic threshold of chromated copper arsenate and ammoniacal copper arsenate to a brown-rot fungus Leucogyrophana sp. This supports the hypothesis that the movement of iron ions into wood contributes to the unexpectedly high decay rate of treated wood at the stake test site at Westham Island BC. To what extent this phenomenon may occur e...
P I Morris


Wood degradation mechanisms by the brown rot fungus Gloeophyllum trabeum
1997 - IRG/WP 97-10229
A mechanism for the degradation of wood by the brown rot fungus Gloeophyllum trabeum is outlined. The mechanism includes the function of redox-cycling, low molecular weight phenolic derivatives which sequester and reduce iron in acidic environments. The role of oxalate for the sequestration of iron (hydr)oxides and the pH dependent transfer of iron to the G. trabeum phenolic chelators, as well as ...
B Goodell, J Jellison


Iron in stone wool - one reason for the increased growth and decay capacity of Serpula lacrymans
1992 - IRG/WP 92-1537
The chemical compositions of stone wool and glass wool were analysed. There was more iron in the stone wool than in the glass wool. It was found that iron present in stone wool was easily dissolved by oxalic acid that Serpula lacrymans is able to produce. The stone wool promoted the decay of pine wood by Serpula lacrymans. The glass wool had no effect on the decay capacity of Serpula Iacrymans. Th...
L Paajanen, A-C Ritschkoff


Risk reduction from curative treatments, restoration and maintenance of building and individual housing - simple precautions that make the difference
2005 - IRG/WP 05-50224-15
This document explores the potentialities of risk reduction, from activities of remediation in construction, developped at small scale by professionals or individuals on targets like moulds, rots, termites and other wood destroying insects, with products distributed for professional or do-it-yourself purposes. At the first stage, an inventory of the type / interest of products / processes is carri...
G Ozanne


Leaching of Arsenic from Mulch Made from Recycled Construction and Demolition Wood
2005 - IRG/WP 05-50232
Mulch made from recycled construction and demolition (C&D) wood has been reported to contain chromated copper arsenate (CCA)-treated wood and potentially release arsenic in the leachate by rainfall. Such recycled wood mulch is commonly masked with iron-oxide colorant, which is known to combine with arsenic. The objective of this study was to evaluate the levels of arsenic leaching from C&...
T Shibata, H M Solo-Gabriele, T G Townsend, B Dubey


Paper for discussion - Incising of spruce to improve preservative penetration
1973 - IRG/WP 318
Large quantities of whitewood or Norway spruce (Picea abies) are regularly imported into the United Kingdom from continental Europe. In addition, increasing amounts of Sitka spruce (Picea sitchensis) are likely to become available over the next decade from the Forestry Commission. In many ways spruce is a good structural timber, eg it is relatively cheap and easily available, it has adequate stren...
W B Banks


Strength properties of preservative treated pine and spruce wood after super-heated steaming
1984 - IRG/WP 3313
Possible changes of strength properties of CCF pressure impregnated pine and spruce with subsequent steaming at 110°C respective 120°C for 30 min were examined. For spruce analysis of variance indicated that none of the processes had a significant effect on bending strength, compression strength and the corresponding modulus of elasticity as well as on impact bending strength and shear strength ...
R-D Peek


Penetration of surface applied deltamethrin micro-emulsion formulations in four European timber species
1994 - IRG/WP 94-20030
The Netherland's Government, in line with many other European Governments initiated a programme (KWS2000) aimed at significantly reducing the emission of volatile organic compounds by the year 2000. As part of this programme a research project is currently underway to evaluate the potential for replacing organic solvent based remedial treatments with micro-emulsion formulations of the sam...
P Esser, W L D Suitela, A J Pendlebury


Oxalic acid quantification, oxaloacetase assay and ESI localization of P, C, and Fe from the brown rot fungus Postia placenta
1994 - IRG/WP 94-10063
The mechanism by which brown-rot fungi initiate depolymerization of holocellulose in wood remains unknown. Recently, oxalic acid (OA) has received considerable attention in cellulose breakdown by brown-rot fungi. The OA could serve as a proton donor for hydrolytic or an electron donor for oxidative (Fenton's reaction-H2O2/Fe2+) cleavages of cellulose. The acid may originate via oxaloaceta...
C R Jordan, W V Dashek, T L Highley


Construction of dhows in Kuwait
1981 - IRG/WP 465
To most people Kuwait means oil and the opulence associated with it, but to the seafarer, Kuwait means Dhows. There are as early references to the Kuwaiti Dhows as the 17th century. The Danish explorer Nebuhr in 1756 described Kuwait as having a work power of 10,000 people and 800 wooden boats involved in fishing, pearl diving, and trade. Dhows might well have been the original carriers of "The Pe...
A S Zainal, M A Ghannoum


Siderophore production by Trichoderma spp. and its importance in the biological control of wood decay fungi
1994 - IRG/WP 94-10070
Competition for iron as well as other micro-nutrients is an essential component of the microbial ecology of many ecosystems. A wide range of micro-organisms including fungi and bacteria have been shown to increase their ability to efficiently capture iron through the production of specialised iron chelating compounds called siderophores. Since iron is in low supply in wood and has been implicated ...
U Srinivasan, A Bruce, T L Highley


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