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Curing conditions for a low formaldehyde etherificated melamine resin
1998 - IRG/WP 98-40108
Waterbased methanol etherificated melamine formaldehyde resins have the potential to increase the resistance of impregnated wood against wood destroying fungi. Previous studies indicated that the resin with the lowest formaldehyde content tested showed the best results regarding fungal resistance, dimensional stability and formaldehyde emissions after curing. In the present paper the influence of ...
D Lukowsky, R-D Peek, A O Rapp


In situ testing the influence of melamine resins on the enzymatic activity of basidiomycetes
1999 - IRG/WP 99-30194
Waterbased methanol etherificated melamine formaldehyde resins have the potential to increase the resistance of impregnated wood against wood destroying fungi. The mechanism of the increased wood durability is not clear yet. In the present paper the possible interference of melamine resins with wood degrading enzymes of Coniophora puteana and Trametes versicolor was investigated as a possible cont...
D Lukowsky, F Büschelberger, O Schmidt


Dimensional Stability of Melamine Formaldehyde-Treated Southern Pine
2017 - IRG/WP 17-40774
The objective of this preliminary study was to evaluate the influence of different levels of melamine formaldehyde (MF) and curing cycle on the dimensional properties of southern pine. Thirty samples for each combination of treatment and curing regimen plus untreated controls and controls subjected to the same curing regimen were tested. Shrinkage/swelling coefficients showed that up to 60% ASE c...
H M Barnes, L S Sites, T S F A França, M G Sanders, F J N França


Time dependent over-uptake of etherificated melamine resins
1998 - IRG/WP 98-40109
Waterbased methanol-etherificated melamine-formaldehyde resins can increase the fungal resistance of the treated wood though they are known to be non-toxic. Therefore melamine-resins are at the present an object of research activities of European projects and of some companies. The paper highlights the importance of quoting the duration of the diffusion when immersed in the treating solution, as m...
D Lukowsky, R-D Peek


Oxygen index levels and thermal analysis of wood treated with melamine-formaldehyde-boron combinations
1997 - IRG/WP 97-30135
Melamine formaldehyde (MF) resin was impregnated into scots pine (Pinus sylvestris L.) specimens with aqueous solutions of 5, 10 and 20% concs. Boric acid (BA) and borax (BX) was added to MF resin at the concentration levels of 0.25, 1.00 and 4.70% to each level of resin concs. BA and BX mixture was prepared at the 5:1 (w/w) ratio considering resultant pH of solutions and better fire resistance. U...
M K Yalinkilic, W-Y Su, Z Demirci, E Baysal, M Takahashi, S Ishihara


EELS (Electron Energy Loss Spectroscopy) - a technique for quantification of nitrogen and other light elements in the cell wall
1999 - IRG/WP 99-20163
A literature survey was performed to find progress in techniques for monitoring penetration of synthetic resins in wood cell walls. Electron energy loss spectroscopy (EELS) in combination with transmission electron microscopy (TEM) was successfully applied for the high resolution examination of the distribution of a partly methylated hydroxymethyl melamine resin in Norway spruce (Picea abies Karst...
A O Rapp, H Bestgen, W Adam, R-D Peek


Durability of surface preserved wood particle boards submitted to atmospherical influence
1995 - IRG/WP 95-40039
The worldwide problem of the continuously growing deficit of high quality natural wood material has caused the attempts of many research workers to find effective composites such as wood particle boards (WPBs) for replacing the massive wood for constructive purposes, depending on where the boards are exploited - in the open or under a shed, they are submitted to various climatic factors such as he...
L Valcheva


Biological resistance of wood treated with waterbased resins and drying oils in a mini-block test
1998 - IRG/WP 98-40107
In recent years it was found that the resistance of wood against fungal degradation could be increased by impregnation with an etherificated melamine formaldehyde resin. Using this resin as a reference, a waterbased fatty acid modificated alkyd-resin and two drying-oils were assessed for their biological performance in a mini-block laboratory test. Although drying-oils, like linseed-oil, are often...
M Sailer, A O Rapp, R-D Peek


The efficacy of preservatives into the glue-line of plywood
1993 - IRG/WP 93-30002
This research is anti-termite/decay preservatives mixed with resin to produce the plywood. Thereafter, anti-decay/termite plywood were produced by the ordinary methods. To produce suitable plywood in the utilization and certified performance, the preservatives should be 0.3 to 0.4 kg/m³ of Chlorpyrifos; 0.88 and 1.10 kg/m³ of mix preservatives of Chlorpyrifos + IF-1000. Laboratories decay test (...
S Fushiki, T Saito, Y Katuzawa, Y Imamura, S Yusuf, B Subiyanto


Melamine resins as preservatives results of biological testing
1996 - IRG/WP 96-40061
Based on previous work of the authors on resins, the upgrading of wood with a true solution of a methanol etherificated melamine resin in low aqueous concentration was performed. For the relative assessment of the biological resistance against brown and white-rot fungi were used not only untreated controls of pine sapwood (Pinus sylvestris L.), but also heartwood of European larch (Larix decidua M...
A O Rapp, R-D Peek


Leaching performance, decay and termite resistance of wood treated with boron compounds incorporated with phenol-formaldehyde resin
2009 - IRG/WP 09-30503
A resol-type phenol-formaldehyde (PF) resin was synthesized and designed to penetrate wood incorporated with boron compounds in order to immobilize boron in wood. The leaching performance, decay and termite resistance of treated wood was investigated. Three kinds of boron compounds, that is, boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT), were selected to mix with PF and tw...
Liping Yu, Jinzhen Cao


Properties of strand board bonded with ammonium pentaborate (APB) modified phenol formaldehyde resin
2009 - IRG/WP 09-40455
Ammonium pentaborate (APB) is combined with phenol formaldehyde (PF) resin in this study to develop a high-performance wood-based composite. The effect of APB and its combination with polyethylene glycol (PEG) on the physical, mechanical properties as well as formaldehyde emission of strand board were tested and compared with disodium octaborate tetrahydrateand (DOT) and zinc borate (ZB). The resu...
Wei Gao, Jinzhen Cao


The Effects of Some Fire Retardant Chemicals on the Decay Resistance of Medium Density Fiberboard (MDF)
2010 - IRG/WP 10-30536
The objective of this study was to determine the decay resistance of Medium Density Fiberboard (MDF) treated with 5% and 10% concentration of various fire retardant (FR) chemicals. Experimental panels were produced using by melamine-urea-formaldehyde (MUF) resins having 10%, 15% and 20% of melamine content. MDF specimens were subjected to decay resistance test performed according to modified EN 11...
D Ustaömer, M Usta, Ü C Yildiz, S Yildiz, E D Tomak


Effect of 4 Preservatives on Physical, Mechanical and Mold-Resistant Properties of Bamboo Oriented Strand Boards
2010 - IRG/WP 10-40483
This study investigated the effects of 4 preservative systems on physical, mechanical and mold-resistant properties of bamboo oriented strand board (OSB) panels bonded with urea formaldehyde resin. Preservative A (Zinc Borate), B (IPBC), C (AAC+Borate) and D (carbendazim + prochloraz) were incorporated with strands during blending at three loading levels. The results showed that the mechanical and...
Juwan Jin, Daochun Qin, Wanshu Wei, Kuan Fan


Effect of P/F ratio, PF concentration and treating method on boron leaching from wood treated with PF modified boron compounds
2011 - IRG/WP 11-30559
In order to immobilize boron in wood, three kinds of resol-type phenol-formaldehyde (PF) resin with different P/F ratios were synthesized in laboratory and incorporated with three types of boron compounds to treat wood. The used boron compounds included boric acid (BA), borax (BX) and disodium octaborate tetrahydrate (DOT). The leaching test of boron from wood blocks was performed according to the...
Liping Yu, Jinzhen Cao


Preliminary laboratory bioassay to evaluate engineered Fibre-boards against subterranean termites C. acinaciformis (Isoptera: Rhinotermitidae)
2012 - IRG/WP 12-10768
In Australia, laboratory bioassays with subterranean termites typically contain groups of workers and soldiers in a substrate of moist mound material. This termite substrate may affect termite consumption, and the test materials create a favorable termite condition for the test. The main purpose of this test is to examine the effect of a melamine formaldehyde treatment of wood panels to evaluate t...
B M Ahmed (Shiday), H Militz, B Ozarska, I Ali, L Kloeser


Termite resistance of wood impregnated with phenol-formaldehyde (PF) modified boron compounds
2012 - IRG/WP 12-30604
In order to investigate the effect of phenol-formaldehyde (PF) modified boron compounds on termite resistance of two main plantation-grown wood species, namely, Masson pine (Pinus massoniana Lamb.) and Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.), laboratory termite tests and field tests were carried out according to AWPA standard E1-97 and AWPC protocols/2007. Different concentrations of b...
Jinzhen CAO, Liping YU, Xuexiang HE


Curing kinetics of nano cupric oxide (CuO) modified PF resin as wood adhesive: Effect of surfactant
2013 - IRG/WP 13-40620
The effect of nano cupric oxide (CuO) in combination with surfactants on the curing kinetics of phenol formaldehyde (PF) resin, as well as the bonding strength of plywood prepared using the modified resin were investigated in this study using dynamic and isothermal differential scanning calorimetry (DSC). The result showed that the incorporation of nano CuO along with alkane surfactant made in the...
Wei Gao, Guanben Du


Dynamic mechanical analysis (DMA) of nano cupric oxide (CuO) modified aqueous phenol formaldehyde (PF) resin
2014 - IRG/WP 14-40654
Phenol formaldehyde (PF) resins, modified by nano CuO incorporating alkane surfactant and polyvinyl alcohol (PVA) 17-99, were analyzed by dynamic mechanical analysis (DMA). The mechanical properties of its bonded plywood including tensile strength, modulus of rupture (MOR), modulus of elasticity (MOE) and shear strength under five test conditions were evaluated. Results indicated that the incorpor...
Wei Gao, Guanben Du


Penetration of phenol formaldehyde (PF) resin into beech wood studied by light microscopy
2015 - IRG/WP 15-20558
In this study, we examined the distribution and penetration depth of phenol-formaldehyde (PF) resin into wood specimens by light microscopy (LM). Two PF resins from different producers, of concentrations 9, 18 and 27 wt % in water, were vacuum impregnated into European beech wood (Fagus sylvatica) blocks of 15x25x50 mm³. The presence of chemical agent in the wood was carried out by way of their i...
V Biziks, S Bicke, H Militz


Decay resistance of beech wood and plywood treated with different type of phenol-formaldehyde (PF) resins
2016 - IRG/WP 16-40717
In this study treatment of beech and poplar wood veneers with (PF) resin industrial scale and screening tests of nine different phenol-formaldehyde (PF) resins were made. Specifically, the effect of different phenol-formaldehyde (PF) resin types on the resistance of beech wood against brown- and white-rot fungi was evaluated. Criteria for selection of optimal (PF) resin were based on minimum WPG ...
V Biziks, S Bicke, H Militz


Fabrication and characterization of MicroPCMs filled wood-plastic composites: Effects of polyethylene glycol on melamine–formaldehyde shell material
2016 - IRG/WP 16-40728
Microencapsulated phase change materials (MicroPCMs) containing dodecanol were fabricated using melamine-formaldehyde (MF) or polyethylene glycol 200 modified melamine-formaldehyde (PMF) resin as the shell materials by in situ polymerization. Wood flour/high-density polyethylene (WF/HDPE) composites with MF shell MicroPCMs (MF-MicroPCMs) or PMF shell MicroPCMs (PMF-MicroPCMs) were prepared, respec...
Xi Guo, Jinzhen Cao


Marine Borer Resistance of Acetylated and Furfurylated Wood – Results from up to 16 years of Field Exposure
2016 - IRG/WP 16-40756
Furfurylated and acetylated Scots pine sapwood has been tested since 1999 in a marine field with high marine borer activity. In 2004, two test groups with acetylated southern yellow pine (product later known as Perennial Wood™) were put out and over the whole test period differently furfurylated wood (later marketed as Kebony®) test groups have been started. Furthermore, some combinations of mo...
M Westin, P Larsson Brelid, T Nilsson, A O Rapp, J P Dickerson, S Lande, S Cragg


Lignin-Based Adhesive for Engineered Wood Products
2016 - IRG/WP 16-50319
Lignin as a naturally occurring polyphenolic compound has an excellent potential to replace petroleum-based phenol in formulation of phenol-formaldehyde adhesive that are used in manufacturing of engineered wood products. However, there are three major obstacles in application of polymeric lignin as phenol replacement: 1) low reactivity toward phenol, 2) high molecular weight, and 3) high polydisp...
I Kalami, M Arefmanesh, E Master, M Nejad


Weathering protection of European hardwoods through double modification
2017 - IRG/WP 17-30715
Beech and poplar were thermally modified, treated with melamine resin and both treatments were combined. The weathering performance (cracks and general appearance) of modified beech and poplar was assessed in natural weathering and correlated to material properties such as work in bending (WB) and Brinell hardness. In addition, the equilibrium moisture content after exposure of 12 months and subse...
G Behr, A Gellerich, S Bollmus, H Militz


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