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Biological efficacy of micronized copper systems
2008 - IRG/WP 08-30485
Soil block, fungal cellar and field stake test data will be presented for micronized copper systems. The copper portion of the formulations is present as a fine dispersion of "micro" particulates while the co-biocide is present as either a soluble quat or an azole containing emulsion. This testing generally used the amine based counterpart as the control preservative system and the micronized fo...
C R McIntyre, M H Freeman


Removal of nano- and micronized-copper from treated wood by chelating agents
2013 - IRG/WP 13-50294
Micronized and nano-copper (Cu)-based and arsenic and chromium-free systems have received much attention for wood protection in recent years. Because they have different fixation, and micro-distribution properties, such copper systems may be more or less subject to release using known remediation methods than soluble forms of Cu. This study evaluated Cu recovery from wood treated with micronized- ...
S N Kartal, E Terzi, B Woodward, C A Clausen, S T Lebow


Evaluation of color and gloss in decorative applied to cases of Pinus radiata wood impregnated (D. Don) copper type C azole micronized
2015 - IRG/WP 15-20571
Six treatments (one control and five decoration coatings) were applied to radiata pine wood treated with micronized copper azole (uCA-C), for outdoor use (R3) at a rate of 3.08 kg/m3 retention (T2). One decoration coating was applied before impregnation treatment: Prestain P (T3), and two, were applied in mixture with the uCA-C preservative Black Cylinder (T5) and Red Cylinder (T4). Two varnish we...
R Garay, M Inostroza


Field Performance of Refractory Species Treated with MCA
2017 - IRG/WP 17-30706
Micronized copper azole (MCA) has been used extensively over the past decade to preserve southern pine, and other wide sapwood species. Treatment of refractory species is less common, in part due to concerns about treatability and resulting efficacy. To address these concerns, white spruce and Pacific silver fir stakes, and lodgepole pine and red pine posts, were pressure-treated with multiple ret...
R Stirling, J K Ingram, P I Morris


In-ground evaluation of a copper azole wood preservative (Tanalithâ E) at a tropical Australian test site
1996 - IRG/WP 96-30100
A field trial to determine the in-ground termite and decay resistance of Pinus radiata D. Don impregnated with a copper azole formulation, TANALITHâ E, has been established at a tropical site in the Northern Territory of Australia. Four retentions of TANALITHâ E, containing 1.54, 2.08, 2.92 and 4.30 kg/m³ of Cu, are being evaluated. For comparison, Pinus radiata specimens treated to two retenti...
J W Creffield, J A Drysdale, N Chew


A study of decay type variability in variously treated Fagus sylvatica and Pinus radiata field test stakes exposed at a vineyard for 30 - 45 months
1998 - IRG/WP 98-10271
Pinus radiata test stakes were treated with 10 kg/m3 of CCA plus 4 lower retentions in a geometric series of 1.5. Fagus sylvatica was treated with 15 kg/m3 and 2 lower retentions. Both timber species were also treated with equivalent retentions of various new generation preservatives (P. radiata was also treated with creosote). Whilst these stakes were exposed at 11 sites in New Zealand (NZ) and 2...
R N Wakeling, A P Singh


Fungus cellar testing as an evaluation method for performance of treated timber in ground contact
2001 - IRG/WP 01-20227
A fungus cellar method for the accelerated evaluation of performance of treated wood in ground contact is described. The test soil comprised of sandy loam, vermiculite and Japanese horticulture soil "Kanumatsuchi" in a ratio of 6:2:2 by volume. The soil was inoculated with the dominant test fungus isolated with selective medium from decayed wood samples. Pairs of treated and untreated wood specime...
Y Nagano


Natural exposure weathering tests: Their role in the assessment of wood preservative efficacy
1993 - IRG/WP 93-20006
Previous work has demonstrated the potential and usefulness of natural ageing procedures in e evaluation of wood preservative efficacy. This results from the combination of physico-chemical influences and microbiological interactions with both substrate and wood preservative. In this paper, results are presented for a range of biocide types. Discussions are centred on the value of natural exposure...
G R Williams, J Brown


Laboratory termite testing of copper boron tebuconazole
2000 - IRG/WP 00-20192
The American Wood Preservers' Association laboratory choice and no choice termite test (AWPA E1-97) was performed on a formulation of copper azole, which is comprised of copper, boric acid, and tebuconazole. The formulation tested has a ratio of copper:boric acid:tebuconazole of 25:25:1. So as to examine the impact of leaching, the southern yellow pine wafers were treated with and without...
R F Fox, E A Pasek, J Patel


Laboratory evaluation of the termiticidal effectiveness of TanalithÒ 3485
1995 - IRG/WP 95-10109
The termiticidal effectiveness of the copper azole TANALITH 3485 was evaluated with the benchmark preservative TANALITH C in a laboratory bioassay using two species of subterranean termites, Mastotermes darwiniensis Froggatt and Coptotermes acinaciformis (Froggatt). Retentions of TANALITH 3485 tested were 0.15, 0.24, 0.285 and 0.40% m/m Cu and for TANALITH C 0.025, 0.05, 0.08 and 0.095% m/m Cu. Un...
J W Creffield, J A Drysdale, N Chew, N-K Nguyen


Leaching of preservative components from pine decking treated with CCA and copper azole, and interactions of leachates with soils
2001 - IRG/WP 01-50171
Radiata pine decking was treated with CCA and copper azole preservatives to Australian H3 retention using conventional and modified Bethel schedules, and air-dried. Treated decking boards and durable hardwood controls were subjected to leaching in weather-exposed decks, and matching 19mm cubes were leached in extended AWPA E11-97 lab tests. Deck runoff and E11 leachate water was analysed after rai...
M J Kennedy, P A Collins


Efficacy of copper:propiconazole and copper:citrate systems in ground contact exposure at a site with copper tolerant fungi
2003 - IRG/WP 03-30305
Southern yellow pine (SYP) sapwood field stakes were treated with copper alone (ammoniacal copper carbonate, ACC) at four levels, or three levels of copper (1.6, 3.2, or 6.4 kgm-3, as CuO), air-dried, then re-treated with propiconazole in a light organic solvent at 0.07, 0.3, or 0.7 kgm-3 retentions. In a separate study, SYP field stakes were treated with three levels of ACC to give 6.7, 13.4 or ...
D D Nicholas, T Schultz


Diffusion modeling of inorganic wood preservative leaching in service
2005 - IRG/WP 05-50224-5
To evaluate the potential environmental and health implications of leaching of inorganic wood preservatives in service under different conditions, there is a need for a predictive model that provides estimates of the rate and extent of leaching over a wide range of product dimensions and exposure conditions. In this paper, we show that the leaching behavior of inorganic preservative components fr...
L Waldron, P A Cooper, Y T Ung


Occupational exposure risk assessment at a commercial treatment plant using copper azole preservative
1998 - IRG/WP 98-50101-15
Experience with traditional water-based preservatives such as chromated copper arsenate (CCA) applied in closed system vacuum pressure impregnation plants has shown that operator atmospheric exposure is low during normal operation. TANALITH E is a commercially available copper azole wood preservative introduced as a chrome and arsenic-free alternative to CCA based on the actives copper, tebuconaz...
A S Hughes, M Connell


Impact of leachates from CCA- and copper azole-treated pine decking on soil-dwelling invertebrates
2002 - IRG/WP 02-50183
This study assessed the short-term effects on non-target soil invertebrates of leachates from a naturally durable hardwood and timber treated with two copper-based wood preservatives. Natural rainwater leachates from kwila decking, and radiata pine-decking treated with CCA or copper-azole, were collected and applied on mown lawn soil in Brisbane, Queensland. The soil study consisted of 5 treatment...
N Crumière, A House, M J Kennedy


Comparative performance of copper azole and copper-chrome-arsenate treated rubber wood in Australian, Malaysian and New Zealand tests sites
2000 - IRG/WP 00-30213
Rubberwood (Hevea brasiliensis) has been used for non-structural products where appearance is important. It has rarely been used for structural uses where preservative treatment is required. In order to evaluate the in-ground durability of preservative-treated rubberwood, test stakes (20 x 20 x 500 mm3) were treated to four retentions of CCA and copper azole (Tanalith® E) and installed in test si...
J A Drysdale, M E Hedley, E Loh, L T Hong


A comparison of analytical and visual techniques used for assessment of weathering properties of chromium and copper azole treated timber
1994 - IRG/WP 94-20023
The weathering properties of preservative treated timber were studied by measuring surface lignin loss and by microscopic examination after weathering, and results were related to qualitative assessments of visual appearance after weathering. Measurement of relative rates of delignification of untreated and preservative treated timber obtained by FTIR analysis, and weight loss determined on thin v...
J A Cornfield, M D C Hale, G Fettis


Is Field Test Data from 20 x 20mm Stakes Reliable? Effects of Decay Hazard, Decay Type and Preservative Depletion Hazard
2006 - IRG/WP 06-20327
Effects of decay hazard, decay type and preservative depletion hazard on the performance of variously preservative treated 20 x 20 x 500 mm Radiata pine and Fagus sylvatica test stakes across 13 field test sites in New Zealand and Queensland Australia were determined. Radiata pine treated with an ammoniacal copper quaternary preservative (ACQ) (1.56% m/m a.i.) and copper chrome arsenate (CCA) (...
R Wakeling


Effects of sodium hypochlorite on compression strength and copper retention of spruce wood treated with copper azole and alkaline copper quat
2007 - IRG/WP 07-40362
This work investigates the effects of sodium hypochlorite on compression strength values and copper retention ratios of refractory spruce wood (Picea oriental L.) treated with the waterborne preservative Copper Azole, (CBA-A, Tanalith-E 3492) and alkaline copper quat (ACQ-2200). Before the copper azole and alkaline copper quat treatment, the samples were immersed in 500 ml of sodium hypochlorite s...
S Yildiz, E Dizman, A Temiz, Ü C Yildiz


The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston


Field Trial of Copper Treated Moso Bamboo in Southern China
2008 - IRG/WP 08-30455
The field trial of moso bamboo treated by 9 copper preservatives for 5 years in Guangzhou was conducted in the paper. The result shown that: two ammonia based copper azole formulations F17/F18 and 1 amine copper formulation with boron F10, as well as 2 ammonia based ACQ, at the copper retention of 3.2 kg/m3 or above, have good resistant for decay and fine resistant for termites after 5 year field ...
Mingliang Jiang


Field Stake Tests with Copper-based Preservatives
2008 - IRG/WP 08-30459
The performance of field test stakes derived from commercially produced ground contact retention copper quat preservatives based on either soluble copper complexed with ethanolamine, or from a water-based suspension of particulate micronized copper compounds, as well as untreated southern yellow pine controls, is compared at two decay test sites. After less than one year in field test some of t...
A Preston, L Jin, D Nicholas, A Zahora, P Walcheski, K Archer, T Schultz


Above and Below-Ground Copper-Azole and Copper, Chrome Arsenate Depletion from Pinus radiata and Fagus sylvatica at Thirteen New Zealand & Australian Sites
2008 - IRG/WP 08-30460
The objective was to determine the significance of site on preservative depletion from Pinus radiata D. Don and Fagus sylvatica L. 20 x 20 x 500 mm field test stakes treated with a ground contact retention of copper amine plus tebuconazole (CuAz) and copper chrome arsenate (CCA) after approximately 5 years exposure to widely different soil and climate conditions. Site, wood species and their inter...
R Wakeling


Formation and Structure of Metal Azole Complexes
2008 - IRG/WP 08-30469
Divalent copper and zinc complexes with metal:azole ratio 1:2 were readily formed at room temperature with the fungicides tebuconazole and propiconazole. The structure of copper and zinc tebuconazole acetate and zinc cis-propiconazole chloride were examined by X-ray crystallography. In copper tebuconazole acetate, the copper atom lies on a crystallographic inversion centre and is coordinated to tw...
P D Evans, K J Schmalzl, C M Forsyth, G D Fallon, S Schmid, B Bendixen, S Heimdal


Micro-Distribution of Micronized Copper in Southern Pine
2008 - IRG/WP 08-30479
For copper-based preservatives to be used in ground contact, penetration of copper into the cell wall is believed to be important to protect the wood from soft rot fungi. Preservatives containing soluble copper are known to do this. It is not known whether preservatives containing particulate copper will also migrate into the cell wall in sufficient quantities to control soft rot decay. An AWPA st...
R Stirling, J Drummond, Jun Zhang, R J Ziobro


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