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The development of a new boron-based wood preservative
1995 - IRG/WP 95-30085
The paper describes a new boron based wood preservative for the treatment of green timber. The product offers many benefits over conventional boron diffusion treatment including: 1. high viscosity, high concentration formulation; 2. permits dip treatment of a wide range of sawn board and pole sizes at ambient temperatures; 3. permits full cross section diffusion of borates without block stacking a...
P Turner, D Conradie


Treatment of wood with boron esters
1995 - IRG/WP 95-30087
The treatment of wood and wood products with boron esters is reviewed. The physical and chemical characteristics of boron esters affecting the treatability of wood are discussed, in particular thermal decomposition and rates of hydrolysis. The uses and methods applying boron esters as wood preservatives include: (i) Solutions of boron esters for remedial and diffusible treatment of wood; (ii) soli...
J Romero, P Vinden, J A Drysdale


The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie


Environmental characterisation of retification process by-products (liquid and gaseous wastes)
2005 - IRG/WP 05-50224-10
In order to reduce environmental risks during the service life of the treated wood and to find new alternative developments on the durability of wood, some research and technology development have been made on thermal treatment. The retification process is one of these processes. The retification process induces chemical modification of the lignin and cellulosic components and modifies the intrins...
G Labat, E Bucket, S Legay, C Yriex, P Marchal, E Raphalen, M Vernois, R Guyonnet, H Besset, E Fredon), G Vilarem, L Rigal, C Raynaud


A technique for measuring preservative loss or redistribution during leaching
1983 - IRG/WP 2199
Radiata pine sapwood stakes were treated with benzalkonium chloride (AAC) or copper-chrome-arsenate (CCA). After fixation and drying the outer 2 mm and 2-4 mm layers were removed from one radial longitudinal face. The planed face was coated with a waterproof coating and AAC-treated stakes were leached for 6, 12 or 18 weeks; 12 weeks for the CCA-treated stakes. After airdrying three 2 mm layers (0-...
J A Drysdale


Characteristics of thermally modified wood in vacuum
2004 - IRG/WP 04-40287
In commercial thermal wood modification processes nitrogen, steam or oil has been used for the reduction of oxygen content in the reactor atmosphere. In present study no special heating medium, but an initial vacuuming step has been used for this purpose. Mass loss, resistance to fungal decay, dimensional stability, bending strength and modulus of elasticity of heat treated wood were evaluated and...
G Rep, F Pohleven, B Bucar


Preservation of coppice wood for the fabrication of glued beams or panels
1987 - IRG/WP 3427
In this survey we will examine the specific problems concerning the conservation and the preservation of timber (issued from trunks of small diameter corresponding to products of clearings or coppices) destined for the fabrication of solid reconstituted elements. Thus for six metropolitan species of wood, we first characterized the biological deteriorations which occur after felling and their kine...
G R Y Déon, R Schwartz


Performance of preservative-treated rubberwood (Hevea brasiliensis) in Goa and Kochi waters (west coast of India).
1997 - IRG/WP 97-20104
Performance of rubberwood (Hevea brasiliensis) against biodeterioration, when pressure-treated with Copper-Chrome-Arsenic (CCA) and Copper-Chrome-Boric (CCB) and exposed in Mandovi estuary (Goa) and in Kochi waters for a period of 32 months and 9 months respectively, has been discussed. The control panels were completely destroyed within a period of 4 to 6 months at both the localities. The resist...
L N Santhakumaran, M V Rao


Internal pressure development within Oriented Strand Board during supercritical fluid impregnation
2000 - IRG/WP 00-40175
Supercritical fluids (SCF) offer an attractive alternative to conventional treatment processes for delivering material into wood, but there are many unanswered questions concerning the technology. One major concern is the potential for the development of excessive pressure gradients in the wood that might exceed the material properties and lead to crushing or other pressure-induced damage. Previou...
G Oberdorfer, P E Humphrey, R J Leichti, J J Morrell


Copper based wood preservative - A new approach using fixation with resin acids of rosin
2000 - IRG/WP 00-30249
Copper soaps with carboxylic acid groups of resin acids of rosin were shown to be potential long-term wood preservatives. The principle involved is the attachment of copper to the network formed by the inorganic part of the preservative (rosin) through the -COOH groups. The mechanisms of fixation have been studied, and it has been shown that this association could be obtained : (1) by forming the ...
C Roussel, J P Haluk, A Pizzi, M-F Thévenon


A technique for determining the efficacy of water diffusible preservative plugs for implanting in joinery in service
1987 - IRG/WP 2291
A technique is described for determining the efficacy of soluble, diffusible preservative plugs for eradicating decay in joinery. It uses blocks of Scots pine sapwood or heartwood adjusted to known moisture contents prior to the establishment of the test fungus Coniophora puteana, from a single longitudinal dowel and the subsequent introduction of the preservative plugs. Prevention of decay, eradi...
J K Carey, A F Bravery


Wood protecting chemicals for the 21st century
1993 - IRG/WP 93-30018
After assessing the past research with protection chemicals, this paper proposes future avenues for research and development in wood protection. Three scenarios are put forward for consideration. First, more is not better and future systems will emphasize combination formulations which enhance properties while providing biological efficacy. Second, current systems, especially those based on copper...
H M Barnes


A comparison of analytical and visual techniques used for assessment of weathering properties of chromium and copper azole treated timber
1994 - IRG/WP 94-20023
The weathering properties of preservative treated timber were studied by measuring surface lignin loss and by microscopic examination after weathering, and results were related to qualitative assessments of visual appearance after weathering. Measurement of relative rates of delignification of untreated and preservative treated timber obtained by FTIR analysis, and weight loss determined on thin v...
J A Cornfield, M D C Hale, G Fettis


Performance of Copper-Chrome-Arsenic (CCA) and Copper-Chrome-Boric (CCB) treated panels of Bombax ceiba and Paraserianthus falcataria against bio-deterioration at Krishnapatnam harbour, east coast of India
2003 - IRG/WP 03-30310
Results of investigations on the durability of light weight timber species (Specific gravity below 0.4) i.e., Bombax ceiba and Paraserianthus falcataria in treated and untreated condition conducted at Krishnapatnam harbour (Lat 13o28’ to 13o59’ N; Long: 80o10’ to 80o16’E) along the east coast of India are reported in the paper. Exposure trails were conducted with panels (Size: 30 x 3.8 x...
B Tarakanadha, N R Raveendra Prasad, K S Rao


Permatek IM 30 as a termiticide treatment for veneer-based wood products
2003 - IRG/WP 03-30325
Permatek IM 30 is a termiticide designed for incorporation into wood products during manufacture. Whereas existing approved products in Australia are based predominantly on synthetic pyrethroids carried in solvents, Permatek IM 30 is based on imidacloprid, a neonicotinoid insecticide. The formulation has very low mammalian toxicity, is free of VOCs, and has been successfully tested as a glueline ...
J Doyle, K Webb, W R Rae, A F Siraa, J Malcolm-Black


The gaseous environment of Coptotermes lacteus mound colonies before and after mirex treatment
1989 - IRG/WP 1396
While monitoring the halocarbon and hydrocarbon emissions from a dry sclerophyll eucalypt forest in central Gippsland, similar emissions were collected from within several Coptotermes lacteus mound colonies. Samples of the gases (hydrocarbons) from within the mounds were collected before, during and after treatment with mirex-treated wood-decay blocks. All the mirex-treated mounds died within two ...
J R J French, R A Rasmussen, D M Ewart, M A K Khalil


Fluoride and chromium concentrations in soil adjacent to remedially treated distribution poles
1996 - IRG/WP 96-50066
Soils adjacent to Rentex treated 'on-line' distribution poles were analysed for total fluoride and chromium content for comparison with background values of these elements. Soil samples 6 cm and 25 cm downslope of selected poles were recovered at 1 week, 1 month, 6 and 12 months after treatment. Background soil samples were taken 50 m from the poles at sampling times. Fourteen po...
D C R Sinclair, G M Smith, A Bruce, H J Staines, P Durrant


Examination of preservative-treated Pinus sylvestris using electron paramagnetic resonance
1992 - IRG/WP 92-3710
EPR is currently being used to help elucidate the nature and extent of the chemical reactions occurring between wood and copper based timber preservatives. In the work reported here treated Scots pine samples were examined at room temperature and in the frozen state. Plots of the electronic parameters A|| vs. g|| were found to be a useful index of the electronic properties of the various formulati...
A S Hughes, R J Murphy, J F Gibson, A J Cornfield


An audit of copper chrome arsenic timber treatment plants throughout Queensland
1995 - IRG/WP 95-50047
Thirty seven copper chrome arsenic (CCA) timber treatment plants in Queensland were assessed according to the operational criteria specified in Australian Standard 2843.2 - 1985, Timber Preservation Safety Code - Plant Operation. The criteria have been designed to provide information on the design and operational activities of a CCA plant. Design aspects that have an effect on the environment are ...
J Norton


Application of oscillating pressure to improve treatability of refractory species
1987 - IRG/WP 3449
Under practical conditions a minimum moisture content of 80% demande by the German quality standard RAL-RG 411 can not be guaranteed throughout the year. Storage of logs with bark prolonges the drying process; a storage without bark must be avoided. A sufficient penetration according the standard can be achieved at least with a moisture content of 60%, optimal conditions may prevail between 100% a...
R-D Peek


Shorter-term biological control of wood decay in pre-seasoning pine roundwood as an alternative to chemical methods
1992 - IRG/WP 92-1555
Previous studies on the long-term control of decay in creosoted transmission poles, using Trichoderma and other antagonistic moulds, have met with limited success. However, it is possible biological control is more suited to control of decay on shorter time scales. An earlier study, focusing on pre-seasoning treatment of transmission poles showed that favourable porosity increases could be brought...
M W Schoeman, D J Dickinson


The biocidal efficacy of sulphates against basidiomycetes
1999 - IRG/WP 99-30192
Copper sulphate is used for the preservation of wood since decades. However, if copper sulphate is not combined with a compound it can be leached up to 50% and more from the treated wood. Previous results for leached wood indicated that the loss of biological efficacy against soft rot corresponds to leaching of copper. For basidiomycetes, however, the effectiveness decreases much more rapidly. The...
H Leithoff, E Melcher


The use of low cost X-ray fluorescence instruments in the determination of copper chromium and arsenic in preservative treated wood
1987 - IRG/WP 2278
Internal quality control in timber treatment plants can be pursued by analysis of preservative treatment solutions and treated timber. Treaters must proceed with costly and lengthy analyses through analytical laboratories. An alternative approach for the timber treater, is to use low cost analysers (L.C.A.'s) based upon x-ray fluorescence. Detailed comparisons have been made between stand...
J Norton, L E Leightley


Preservative leaching from copper-chrome-arsenic treated timber: Towards an international standard for environmental monitoring
1996 - IRG/WP 96-50076
A review of standards and legislative requirements around the world relating to environmental contamination from copper-chrome-arsenic wood preservative indicates a plethora of methodologies for expressing and determining contamination levels. The imposition of arbitrary quarantine periods for treated timber, or special fixation processes, appear to be applied without a rational analysis of what l...
S Walley, P R S Cobham, P Vinden


LCA examination of preservative treated timber products and alternatives; initial results
1995 - IRG/WP 95-50040-04
Co-operative development of an LCA methodology suitable for application to preservative treated products has been carried out, based on scoping assessments of two products, CCA treated fenceposts and creosote treated distribution poles. The general results of these scoping exercices are described, based on the CCA case study. These include the identification of critical stages in the life-cycle on...
W Hillier, R J Murphy, D J Dickinson, J N B Bell


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