Your search resulted in 55 documents. Displaying 25 entries per page.
Laboratory and field trials of novel antisapstain formulations
1997 - IRG/WP 97-30146
This document covers the results of laboratory and field trials of combinations of fungicides formulated using a patented technology (PCT NZ 96/00143). A 3 week laboratory trial that uses radiata pine (Pinus radiata D. Don) branch discs as a substrate was used to determine which combinations possessed a suitable spectrum of fungitoxicity against key sapstain, mould and decay fungi. In particular f...
R N Wakeling, P N Maynard, D R Eden, C M Chittenden, B Carpenter
The quantitative determination of quaternary ammonium compounds in treated timber – results of an extended ring test
2002 - IRG/WP 02-20240
The determination of quaternary ammonium compounds (QAC) by means of a 2-phase-titration or photometry is a well established procedure for the quantification of cationic detergents in aqueous solutions. It is known that this analytical principle can also be used for the measurement of QAC extracted from treated timber. However only few information are available concerning the reproducibility or th...
E Melcher, C Bornkessel, J Gunschera, R Hamberg, H Härtner, H-N Marx, U Schoknecht, J Wittenzellner
Performance of Paraserianthus falcataria treated with ACZA, ACQ, CC or CCA and exposed in Krishnapatnam harbour, India
2005 - IRG/WP 05-30382
Paraserianthus falcataria (=Albizia falcataria) treated to two retentions with ammoniacal copper zinc arsenate (ACZA), ammoniacal copper quaternary (ACQ), ammoniacal copper citrate (CC) and chromated copper arsenate (CCA) was assessed over 34 months in a tropical marine waters at Krishnapatnam harbour on the east coast of India. ACZA treatment showed comparatively better resistance than CCA, ACQ a...
B Tarakanadha, K S Rao, J J Morrell
Efficacy of Didecyl Dimethyl Ammonium Chloride (DDAC), Disodium Octaborate Tetrahydrate (DOT), and Chlorothalonil (CTL) against Common Mold Fungi
2004 - IRG/WP 04-30338
The fungitoxic properties of four fungicides, alone and in combination, against four different mold fungi commonly associated with indoor air quality problems were evaluated on two different wood species and sheetrock. The fungicides were chlorothalonil (2,4,5,6-tetrachloroisophthalonitrile) (CTL)
in a 40.4% aqueous dispersion, disodium octaborate tetrahydrate (DOT) in two different forms - a ...
J A Micales-Glaeser, J D Lloyd, T L Woods
Effectiveness of some microbiocides against the development of molds and sapstain in Pinus elliottii
1981 - IRG/WP 3169
Eleven commercial biocidal formulations were tested in the field to determine their effectiveness in protecting logs and lumber of Pinus elliottii sapwood from sap stain and molds. Among these formulations 2-(thiocyanomethylthio) benzothiazole showed the best performance in controlling both types of fungi. Potassium N-hydroxymethyl-N-methyl dithiocarbamate and the mixture potassium N-methyl dithio...
S Milano
Preservative treatment of wood by diffusion processes - Simulation of commercial treatment processes
1988 - IRG/WP 3498
Spruce (Picea abies), Scots pine (Pinus sylvestris) and birch (Betula pendula) were preservative treated by diffusion with mixtures of copper sulphate and arsenic pentoxide. The preservative was fixed after a suitable diffusion storage period by soaking in ammonia solution. A high standard of treatment could be achieved in spruce sapwood. This was attributed to its low wood density, and high wood ...
P Vinden
Determination methods of phytotoxic effect of wood preservatives
1990 - IRG/WP 2349
The phytotoxic effect of wood preservatives so widely used plays a considerable role in the protection of natural environment. A review was made of the existing methods with which to assess the phytotoxicity of the above chemicals and some suggestions were given concerning the methods most appropriate for their unification. Two areas of research are proposed: 1) estimating the direct effect on ind...
A Kundzewicz, J Wazny
Movement of water through quaternary ammonium treated wood
1987 - IRG/WP 3440
Radiata pine sapwood stakes were treated with didodecyl methyl 1, 3 dichloropropenyl ammonium chloride and distearyl dimethyl ammonium chloride. Various ratios of these two chemicals were, tested to determine the extent of water movement through the treated wood. Measurements were taken of the amount of water moved through the wood, degree of wetting of various sectors of the stakes, and the distr...
P J Hayward, J Duff
Fungitoxic effect of the quaternary ammonium compounds wood preservatives against the Ascomycetes and Deuteromycetes
1997 - IRG/WP 97-30138
Results of investigation on fungitoxic value of the three formulations of wood preservatives based on the quaternary ammonium compounds (lauryldimethylbenzylammonium chloride, lauryldimethylbenzylammonium bromide, alkylbenzyldimethylammonium chloride) in relation to the surface wood colouring (moulds) and soft-rot fungi have been presented. The agar-plate (screening) and agar-wood plate for mouldi...
J Wazny, P Rudniewski
Effect of test site location on in-ground preservative performance after 6 years
2001 - IRG/WP 01-20231
Pinus radiata test stakes were treated with 4.1 kg/m3 of CCA and Fagus sylvatica with 6.1 kg/m3 of CCA. Both wood species were also treated with a copper plus triazole preservative (3 kg/m3 of copper) and chlorothalonil plus chlorpyriphos in oil (4.8 kg/m3 chlorothalonil). Furthermore, P. radiata was treated with ammoniacal copper plus a quaternary ammonium compound (2.6 kg/m3 copper) and a 60/40 ...
R N Wakeling
The effect of soil pre-exposure on the results of laboratory Basidiomycete testing
1991 - IRG/WP 2385
Scots pine sapwood blocks were treated with several concentrations of copper chrome arsenic (CCA), copper chrome boron (CCB) and a copper modified quaternary ammonium compound (CMAAC). Leached and unleached samples were exposed in a basidiomycete monoculture test using Coniophora puteana, a copper tolerant brown rot. Prior to testing half of the blocks were buried in unsterile soil for 4 weeks. Th...
S M Gray
Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar
Performance of proprietary formulations of anti-sapstain preservatives on Hevea brasiliensis timbers in laboratory tests
1989 - IRG/WP 3532
A total of 10 proprietary and two experimental formulations were assessed for their effectiveness against sap-stain caused by Botryodiplodia theobromae on Rubberwood (Hevea brasiliensis). Sterilized wood samples 5x20x40 mm³ were dipped in the test chemicals for 60 seconds and then inoculated with 0.5 ml of culture filtrate of Botryodiplodia theobromae for incubation in sterile, damp petri dishes....
L T Hong
Chemically modified tannin and tannin-copper complexes as preservatives for wood
2001 - IRG/WP 01-30271
The efficacy of Mimosa tannin, chemically modified tannin, and tannin-copper complexes as wood preservatives was studied. When the tannin-ammonia-CuCl2 solutions were impregnated into wood specimens in a one-step procedure, a large quantity of the tannin-copper complex was fixed in the specimens. Little of the complex was leached from specimens by a weathering treatment, and these specimens showed...
H Yamaguchi
The fixation of copper in Pinus sylvestris using the sodium salts of two polyhydroxycarboxylic acids
1992 - IRG/WP 92-3706
As part of the research concerned with the development of fixed, copper based preservatives, the salts of polyhydroxycarboxyIic acids, have been used in copper sequestration studies and fixation trials in Pinus sylvestris splinters. Selected compounds have been shown to be effective sequestrants at low concentrations allowing alkaline solutions to be formulated. Leaching trials following a 48 hour...
M Bacon, J A Cornfield
The influence of timber species and preservative treatment on spore germination of some wood-destroying Basidiomycetes
1988 - IRG/WP 2300
Basidiospores from six wood decay fungi exhibited varying germination rates on untreated softwood and hardwood blocks. Germination inhibition of all test fungi was recorded on pine sapwood. No preference for a certain timber species by a particular fungus was evident. Whereas almost complete inhibition of germination occurred on wood treated with a quarternary-ammonium based wood preservative, mos...
B M Hegarty, G Buchwald
Measurement of electrokinetic potential to evaluate adsorption of quaternary ammonium salt
1991 - IRG/WP 3672
Measurement of z-potential in the wood treated with preservatives is suggested as a method for determination of the adsorption of preservative to wood. It has been found that measurement of z-potential of wood treated with quaternary ammonium salt type preservatives can be a useful method to determine the adsorptives phenomena of preservatives and by which there is a remarkable differences in the ...
Yeong Suk Kim
The effect of stack height on the performance of preservatives used for the prevention of sapstain on seasoning wood
1997 - IRG/WP 97-10192
The performance of three anti-sapstain preservatives was investigated under field conditions in south east England. The preservatives under test were: copper-8-quinolinolate (Mitrol PQ8) trimethylalkylammoniumchloride and sodium hexanoate (Sinesto B) and chlorothalonil (Tuff Brite). The preservatives were tested on Corsican Pine grown in south east England. The field trial was set up to investigat...
J R Williams, D J Dickinson, J F Webber
A novel technique for comparative toxicity studies of potential insecticidal wood preservatives
1983 - IRG/WP 2198
For some years now a device has been under development at the New Zealand Forest Research Institute, the purpose of which is to study the effects of sub-lethal amounts of stomach poisons (but also of fumigants and contact active materials) on the co-ordinative abilities of a cerambycid larva. This insect is Prionoplus reticularis - indigenous to New Zealand its larvae feed in decaying logs and are...
D J Cross
The effect of additives on copper losses from alkaline copper treated wood
2007 - IRG/WP 07-50246
The replacement of chromated copper arsenate (CCA) by alkaline copper compounds has heightened awareness of the potential impact of copper losses on aquatic organisms. While there remains a healthy debate concerning the actual risk of copper leaching from wood preservatives into aquatic ecosystems, it is clear that reducing these losses will be necessary to avoid continued regulatory actions aga...
J Mitsuhashi, J J Morrell, L Jin, A F Preston
Polymeric Betaine as a Wood Preservative
2008 - IRG/WP 08-30487
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. This paper summarizes the properties of DPAB as a wood preservative. Unique properties related to the betaine nature of DPAB are discussed in terms of the structure-property relationship. Physical properties of D...
H Härtner, S Schmitt, Futong Cui, H M Barnes
Impact of an Antioxidant on the Efficacy of Quaternary Ammonium Compounds (Quats) and Triazoles – Seven Year Above-Ground Study
2009 - IRG/WP 09-30504
It has been reported that antioxidants have great potential for use with organic biocides in the area of wood protection. This paper demonstrates the impact of a low level of the antioxidant butylated hydroxytoluene (BHT) on the efficacy of quat-based and triazole-based formulations. A seven year lap joint test revealed a positive effect of BHT on the efficacy of quat-based formulations, especiall...
Xiao Jiang, D Biro, W Holcombe
Micronized Copper Preservative Systems: Observations on the Release of Cupric ion (Cu2+) from Treated Wood and Performance against Wood Decay Fungi
2009 - IRG/WP 09-30519
In an attempt to address the mechanism of action of micronized copper preservatives, a 20-week continuous water leaching study was conducted. The leaching results indicated that, once impregnated in wood, micronized copper preservatives continuously release cupric ion, and the levels of cupric ion released from micronized copper treated wood are higher than those released from CCA treated wood, a...
J Zhang, R Ziobro
Adsorption of ACQ components in wood
2010 - IRG/WP 10-30522
To investigate the chemical adsorption capacity of copper-monoethanolamine (Cu-Mea) components on wood, the Na+ cation exchange capacity (CEC) of red pine (Pinus resinosa Ait.) was determined and compared to the adsorption capacity of free Mea and Cu-Mea complexes. The CEC increased with increasing pH. Free Mea adsorption as a function of pH followed the sodium adsorption curve except at pH over 9...
Myung Jae Lee, P Cooper
Distribution and availability of preservative components in ACQ treated wood - effects of coatings and weathering
2010 - IRG/WP 10-30537
Copper and quaternary ammonium compound (quat) distributions across lumber (gradients) and availability, as measured by amount removed by intensive leaching of wood flour, were measured in ACQ treated southern pine lumber. Samples were evaluated just after treatment and stabilization, or after 3 years of laboratory storage, or after 3 years of natural weathering exposure. The objective was to in...
T Ung, M Nejad, P Cooper