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Enhancing Our Understanding of Brown Rot Mechanisms through Catalytic Pretreatment and Cellulase Cocktail
2018 - IRG/WP 18-10909
A catalytic mechanism, described as the “chelator-mediated Fenton” (CMF) mechanism, is proposed to mimic the non-enzymatic action of brown rot fungi. A CMF treatment was used together with an enzymatic cocktail to study how wood was deconstructed and solubilized. This was done in-part to determine if the treatment mimicked the action of brown rot fungi, but also to explore improved treatment p...
S Tabor, L Orjuela, D Contreras, G Alfredsen, J Jellison, S Renneckar, B Goodell


An examination of the potential for the use of the Maillard reaction to modify wood
2018 - IRG/WP 18-40829
Finding efficient ways to decrease wood decay caused by fungi and increasing its dimensional stability is an important issue in the timber construction. A possible way to avoid wood decay by fungi is by reducing the water content of wood, since water is a primary condition for fungal growth. Bulking of the wood cell wall by chemical reagents occupies the space where water normally occurs. At the s...
K Peeters, E Larnøy, A Kutnar, Č Tavzes, C A S Hill


Non-stochiometric oxidation and ROS generation promoted by guaiacol lignin structures and lignocelluose surfaces may be a component of brown rot fungal degradation mechanisms
2019 - IRG/WP 19-10937
Model guaiacol compounds representing lignin monomers, as well as DHP-lignin and wood flour of controlled particle size were used to assess iron reduction at the pH of the natural wood cell wall. All compounds functioned as electron donors for ferric iron, with the lignin monomers demonstrating capacity for non-stochiometric reduction of iron with multiple moles of ferric ion reduced per mole of l...
Y Tamarua, M Yoshidaa, L D Eltisb, B Goodell


The use of bicine and tricine as possible Maillard reagents in a combined thermal/chemical modification of beech
2019 - IRG/WP 19-40852
The effects of thermal modification have been well established, particularly in terms of reductions in mechanical performance. In recent years, there has been an increase in studies related to the Maillard reaction. More commonly associated with food chemistry, it involves the reaction of amines and reducing sugars during cooking procedures. This paper has attempted to combine the use of amines an...
D Jones, C-M Popescu, D Krzisnik, M Hocevar, M Humar, M-C Popescu


Antifouling wood matrix with natural water transfer and micro reaction channels for water treatment
2019 - IRG/WP 19-40853
Wood with abundant nutrition transport channels could be considered as a kind of natural water purifier due to quick and effective passages for separation. Nevertheless, microporosity as main porous structure of initial wood are not enough to effectively separate small molecular, such as organic dye pollutants. Meanwhile, like most filters the fouling resulting in blocking and poor water flux will...
G Liu, D Xu, S Chang, J Hu, Xianjun Li5, Y Liu


Using X-ray scattering to elucidate the mechanisms behind the moisture and fungal decay resistance of epoxybutene modified wood
2019 - IRG/WP 19-40854
Chemical modification of the hydroxyl groups of wood can improve the properties of wood by providing moisture and biological resistance, as well as dimensional stability. Southern pine solid wood was chemically modified to various weight percentage gains (WPG) with epoxybutene (EpB, 8%-38% WPG). After modification, specimens were extracted with a toluene: ethanol (2:1) solution for 2 hours or wate...
R E Ibach, N Plaza


The iron reduction by chemical components of wood blocks decayed by wood rotting fungi
2021 - IRG/WP 21-10979
Brown-rot fungi, a group of wood rotting fungi, is well known to be one of major microorganisms that cause the deterioration of wooden buildings in Japan and have been considered to use chelator-mediated Fenton (CMF) reaction in concert with hydrolytic and redox enzymes for degradation of wood cell wall. CMF can be described as a non-enzymatic degradation system that utilizes hydroxyl radicals pro...
R R Kondo, Y Horikawa, K Ando, B Goodell, M Yoshida


Green approach in wood mineralization for improvement of fire properties
2022 - IRG/WP 22-30769
Various treatments have been developed in order to improve fire properties of wood. Because the use of some flame retardants can release toxic compounds in the event of a fire, leading to poisoning or even death of people from smoke inhalation, the use of no-toxic and more ecologically acceptable flame retardants is preferable. Mineralization of wood with the incorporation of carbonates has proven...
A Pondelak, R Repič, L Škrlep, N Knez, F Knez, A S Škapin


How the biochemical activities of polyphenols may be effective for the protection of wood deterioration by termites?
2023 - IRG/WP 23-30789
In spite of the remarkable mechanical characteristics of wood for building construction and furniture industry, this material is prone to biodeterioration by xylophagous organisms. This compromises its durability and performances during storage and services, and results in considerable economical losses estimated by the billions. Protection against fungi, termites and other wood biodegrading organ...
J-P Joseleau, D Messaoudi, K Ruel


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