Your search resulted in 18 documents.
Non-destructive evaluation of wood decay
2011 - IRG/WP 11-20479
Evaluation of wood decay is often prone to subjective assessment. Standard rating scales are based on human perception of decay, often in addition to weight loss measurements. Especially the assessment of graveyard specimens or other long term testing material that has to be monitored regularly on a non-destructive basis, is challenging. In this paper two techniques are presented that can deliver ...
J Van den Bulcke, I De Windt, N Defoirdt, J Van Acker
The effect of low molecular weight chelators on iron chelation and free radical generation as studied by ESR measurement
2000 - IRG/WP 00-10367
The focus of this work was to improve our current knowledge of the non-enzymatic mechanisms involved in brown-rot decay. Electron Spin Resonance (ESR), also known as Electron Paramagnetic Resonance (EPR), is an attractive technique for the identification and study of chemical species containing unpaired electrons (such as radicals and certain transition metal species). ESR spin-trapping techniques...
Yuhui Qian, B Goodell
An investigation of organotin compounds in treated wood using Mössbauer spectroscopy
1983 - IRG/WP 3249
The influence of sample preparation on the 119mSn Mössbauer spectrum of tributyltin chloride in ponderosa pine was investigated. Initial studies with sawdust and compressed discs concluded that the latter were clearly superior. Further studies showed that compressed discs prepared from 0.4 g of treated wood and 0.1 g of cellulose were robust and gave excellent Mössbauer spectra. The possibility ...
J N R Ruddick, J K Ingram
An electron spin resonance study of manganese changes in wood decayed by the brown-rot fungus, Postia placenta
1988 - IRG/WP 1359
Electron spin resonance (ESR) spectrometry was used to examine wood decay by the brown-rot fungus, Postia placenta. Wood slivers of Douglas-fir, white fir, redwood, sweetgum and yellow poplar were incubated for 4 weeks in custom-made quartz ESR tubes with or without Postia placenta. In all wood species without fungus, a weak partially resolved signal (about g=2, presumably due to manganese) was de...
B Illman, D C Meinholtz, T L Highley
The compatability of tributyltin fungicides and synthetic pyrethroid insecticides as wood preservatives
1987 - IRG/WP 3414
The stability of three synthetic pyrethroids, cypermethrin, deltamethrin and permethrin, to selected tributyltin compounds, Bu3SnX {where X = OSnBu3, Cl, 02CC6H5, O2C (Naphthenyl), OSO2Et}, (Bu3SnO)3PO and {NBu4} {Bu3SnCl2}, in toluene solution was investigated by infra-red spectroscopy over a six month period. It was found that only (Bu3Sn)2O reacted with the pyrethroids and that their order of r...
S J Blunden, R Hill
The influence of the location of a wood defect on the modulus of elasticity determination in wood durability testing
2004 - IRG/WP 04-20287
This study investigates the influence of the location of a wood failure in stakes upon elastic changes observed in beech specimens with the resonance vibration technique. Natural failures were simulated by artificially created defects at different locations of the test stake. The results indicate that the location of an attack in a stake is important for the measurement outcome. When the attack is...
L Machek, H Militz
The effect of a chelator mediated fenton system on activation of TMP fibres and decolorization of synthesized dyes
2004 - IRG/WP 04-50223
The purpose of this work is to improve our current knowledge of the non-enzymatic mechanisms involved in the brown rot degradation of wood, but also to study the potential applications of a chelator-mediated Fenton system in activation of wood fibers and decolorization of synthesized dyes. In this work, Electron Spin Resonance (ESR) spin-trapping techniques were used to study the generation of hyd...
Yuhui Qian, B Goodell, J Jellison
NMR T1 relaxation time as a non-destructive method for the study of decay in wood
1992 - IRG/WP 92-2406
The NMR spectroscopic technique of measuring the T1 spin-lattice relaxation times has been investigated for its potential in the detection of microbial decay in wood. The T1 NMR analyses were carried out on samples of Scots pine and European beech that had been exposed to decay and non-decay fungi representing each of the important groups colonising wood. Decay in the test material was also assess...
P W McCormack, A E G Cass, R J Murphy
Studies of the mechanism of chromated-copper preservative. Fixation using electron spin resonance
1992 - IRG/WP 92-3701
Two softwoods and one hardwood species were treated with chromium trioxide, copper sulphate, chromated-copper wood preservative (CCA). The treated wood samples were analyzed during fixation by electron spin resonance (ESR). ESR spectra indicated that more than one Cr(V) species was generated from Cr(VI) soon after CCA treatment. The Cr(V) signal became strong within increased several hours followe...
K Yamamoto, J N R Ruddick
Biological test, AAS and EPR study of copper monoethanolamine complex with quaternary ammonium compounds as a wood preservative
2003 - IRG/WP 03-30321
Experiments were carried out on the wood preservative with a strong fungicidal activity based on Cu(II) carbonate, 2-aminoethanol (monoethanolamine) and quaternary ammonium compound (QAC). The object of the performed investigations was sapwood of Scots pine (Pinus sylvestris L.) treated with Cu-EA-QAC formulation. Mycological investigations were carried out according to EN 113 and EN 84 standards....
B Mazela, I Polus, S K Hoffmann, J Goslar
The examination of preservative-treated radiata pine using electron spin resonance spectroscopy
1987 - IRG/WP 3423
Electron spin resonance spectroscopy (ESR) may be used to characterise the molecular environment of chemical species containing unpaired electrons. These species include free radicals, bi-radicals, point defects in solids, localised crystal imperfections and many transition metal ions. ESR has previously been applied to the examination of wood weathering or wood pyrolysis and now FRI and Massey Un...
D V Plackett, E W Ainscough, A M Brodie
Examination of preservative-treated Pinus sylvestris using electron paramagnetic resonance
1992 - IRG/WP 92-3710
EPR is currently being used to help elucidate the nature and extent of the chemical reactions occurring between wood and copper based timber preservatives. In the work reported here treated Scots pine samples were examined at room temperature and in the frozen state. Plots of the electronic parameters A|| vs. g|| were found to be a useful index of the electronic properties of the various formulati...
A S Hughes, R J Murphy, J F Gibson, A J Cornfield
Direct estimation of the durability of high-pressure steam modified wood by ESR-spectroscopy
2010 - IRG/WP 10-40508
Heat generated persistent free radicals have been detected by electron spin resonance measurement of thermally modified wood, prepared by high pressure superheated steam treatment. The specific density of these radicals have been correlated with the durability against basidiomycetes, as measured by the European standard EN113 test. In the lower range of specific radical densities, the found correl...
W Willems, A Tausch, H Militz
Modern Instrumental Methods to Investigate the Mechanism of Biological Decay in Wood Plastic Composites
2014 - IRG/WP 14-40674
Various instrumental techniques were used to study the fungal decay process in wood plastic composite (WPC) boards. Commercial boards exposed near Hilo, Hawaii (HI) for eight years in both sun and shadow locations were inspected and tested periodically. After eight years of exposure, both boards were evaluated using magnetic resonance imaging (MRI), while a selected area of the board exposed in sh...
G Sun, R Ibach, M Gnatowski, J Glaeser, M Leung, J Haight
Measurement of Cell Wall Moisture in Acetylated Radiata Pine Using Low-Field Nuclear Magnetic Resonance
2016 - IRG/WP 16-20583
Understanding the interaction of water with acetylated wood is necessary to explain how the protective mechanism of acetylation functions. Low-field nuclear magnetic resonance is one technique for assessing water in wood. Pinus radiata earlywood sapwood samples were acetylated to various weight percentage gains and then analysed with this method. Increased levels of acetylation showed significantl...
H G Beck, C A S Hill
Distribution and penetration of the tung oil in wood studied by high-resolution magnetic resonance imaging
2016 - IRG/WP 16-20593
Water repellents as environment-friendly treatments are gaining their popularity as non-biocidal solutions for wood protection. One of the most important water repellents for wood besides waxes and organosilicon compounds are drying oils. Tung oil is one of the best performing oil. However, tung oil, similarly as other oils, does not penetrate deeply into wood, due to its high viscosity. In order...
M Žlahtič, U Mikac, I Serša, M Merela, M Humar
Effect of Particle Size on Wax Distribution in Paraffin Wax Emulsion Impregnated Wood
2017 - IRG/WP 17-40779
Paraffin wax emulsion impregnation has been a common eco-friendly approach for improving water repellency of wood. In this study, southern pine (Pinus spp.) and Scots pine (Pinus sylvesteris L.) samples were impregnated with paraffin wax emulsions of different solid contents and particle sizes, and then the time domain nuclear magnetic resonance (TD-NMR) was used to elucidate the influence of part...
Wang Wang, Jinzhen Cao, Yiheng Huang
Recent findings clarifying the mechanism of brown-rot decay protection in acetylated wood
2018 - IRG/WP 18-40827
This paper summarizes the findings obtained during my PhD research over the past three years. The results provide insights which help to understand the enhanced brown-rot decay resistance of acetylated wood with particular emphasis on the role of water. The protection acetylation provides is derived from moisture exclusion within the acetylated cell wall, but the exact mechanism by which water is ...
G Beck