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Migration of copper from copper naphthenate treated Douglas-fir poles during storage
2014 - IRG/WP 14-50302
Preservative migration from treated wood products has raised concerns among regulators, especially when the biocides move into surface waters. In most cases, chemical levels are well below the acceptable minimum level, but can become a concern if large quantities of treated wood are stored in one location. One such case would be a location where utility poles are stored for use in emergency repai...
C S Love, C M Freitag, J J Morrell


Influence of Exposure Direction on Leaching of a Biocide from Painted Wood Surfaces
2014 - IRG/WP 14-50303
The objective of this project was to investigate the influence different exposure directions – North, East, South and West on the cumulative quantity of a biocide leached from painted wood surfaces due to rainfall and the consequences for the risk assessment. The study included a solvent-borne primer without biocides and a topcoat protected with a biocidal active substance. Both products were a...
M Klamer


Hydroponic Phytoremediation of Chromated Copper Arsenate (CCA) and Copper Contaminated Water
2014 - IRG/WP 14-50304
The removal of selected metals by duckweed (Lemna minor) and parrotfeather (Myriophyllum aquaticum) from a simulated aqueous environment contaminated with Chromated Copper Arsenate (CCA) and copper sulfate was studied in a controlled laboratory experiment. The duckweed and parrotfeather’s tissues were analyzed to evaluate the removal of copper (Cu), chromium (Cr), and arsenic (As) from CCA cont...
C Keith, H Borazjani, S Diehl, Y Su, Fengxian Han, B Baldwin


Practical extraction of metals from CCA-treated wood
2014 - IRG/WP 14-50305
The extraction effects of acid concentration, reaction time and temperature in a microwave reactor on recovery of chromated copper arsenate (CCA)-treated wood were evaluated. Extraction of copper, chromium, and arsenic metals from CCA-treated southern pine wood samples with three different wood particle sizes (i.e., (1) 0.5 cm3, (2) 0.5x05x1.0 cm, and (3) 0.5x0.5x1.5 cm) was investigated using a m...
Bin Yu, Chung Y Hse, T F Shupe


VOC-free remedial treatment agent on organic solvent basis with surface cleaning by photocatalysis using titanium dioxide
2014 - IRG/WP 14-40651
Due to the EU Regulations according to the harmonisation of the European market of biocidal products and the EU Regulations regarding emissions of volatile organic compounds in residential properties a new VOC free yet organic solvent based remedial treatment agent is introduced including a potential method to clean up the wooden surface of remaining biocides after a remedial treatment using photo...
H Ahl, J Fromm, P Jüngel, E Melcher, M Pallaske


Nano-Zycosil in MDF. Part I: Gas and Liquid Permeability
2014 - IRG/WP 14-40652
Effects were studied of zycosil nanoparticles, with size range from 20 to 80 nm, on liquid and gas permeability of medium density fiberboard. Nanozycosil was used at four consumption levels of 0, 50, 100, and 150 g/kg dry wood fibers. Density of all treatments was kept constant at 0.67 g/cm3. The obtained results indicated that the addition of zycosil to the mat resulted in a significant increase...
H Reza Taghiyari, A Karimi, P M D Tahir, O Schmidt, E Bari, P Nouri , A Jahangiri


Effect of silver nanoparticles on the rate of heat transfer to the core of the medium-density fiberboard mat
2014 - IRG/WP 14-40653
Effect of silver nanoparticles on the rate of heat transferred to the core section of medium-density fiberboard (MDF) mat was studied here. A 400 ppm aqueous nanosilver suspension was used at three consumption levels of 100, 150, and 200 mL/kg based on the weight of dry wood fibers; the results were then compared with the control MDF panels. The size range of silver nanoparticles was 30-80 nm. Res...
H Reza Taghiyari, O Schmidt, E Bari, P M Tahir, A Karimi, P Nouri, A Jahangiri


Dynamic mechanical analysis (DMA) of nano cupric oxide (CuO) modified aqueous phenol formaldehyde (PF) resin
2014 - IRG/WP 14-40654
Phenol formaldehyde (PF) resins, modified by nano CuO incorporating alkane surfactant and polyvinyl alcohol (PVA) 17-99, were analyzed by dynamic mechanical analysis (DMA). The mechanical properties of its bonded plywood including tensile strength, modulus of rupture (MOR), modulus of elasticity (MOE) and shear strength under five test conditions were evaluated. Results indicated that the incorpor...
Wei Gao, Guanben Du


Decay resistance of wood-plastic composites reinforced with extracted or delignified wood flour
2014 - IRG/WP 14-40655
The moisture and decay resistance of wood-plastic composites (WPCs) reinforced with extracted or delignified wood flour (WF) was investigated. Three different extractions were preformed: toluene/ethanol (TE), acetone/water (AW), and hot water (HW). Delignification (DL) was performed using a sodium chlorite/acetic acid solution. All WPCs specimens were made with 50% by weight HDPE and WF, first com...
R E Ibach, Yao Chen, N M Stark, M A Tshabalala, Yongming Fan, Jianmin Gao


Evaluation of vessel features on physical and mechanical properties of wood of Common black poplar (Populus nigra L.) grown at different elevations in the region with a continental climate
2014 - IRG/WP 14-40656
This study essentially examined the effect of elevation on the anatomical structure, and the physical and mechanical properties of Common black poplar (Populus nigra L.) wood. The scope of the study was to observe the variability of vessel element features on physical and mechanical properties of Common black poplar (Populus nigra L.) in relation to habitat at different elevations. For this purpos...
I Usta


Thermal durability and biodegradation of tannin lignin adhesives
2014 - IRG/WP 14-40657
Mimosa tannins and lignosulfonates were used in wood adhesives formulation to substitute resins based on formaldehyde. Mimosa tannins were mixed with either glyoxalated sodium lignosulfonates or glyoxalated ammonium lignosulfonates. The ratios of mimosa tannins and sodium lignosulfonates varied from 20% tannins to 60% tannins. The thermal durability of the adhesives were analysed by thermogravimet...
L Chupin, B Charrier, A Pizzi, F Charrier


The resistance of Accoya® and Tricoya® to attack by wood-destroying fungi and termites
2014 - IRG/WP 14-40658
The resistance of high acetyl WPG solid timber (Accoya®) and medium density fibreboard (Tricoya®) to attack by wood-destroying fungi and termites was investigated under both laboratory and field conditions. Laboratory decay studies were conducted in Australia and New Zealand. Field studies were conducted in Australia, Japan, New Zealand, Thailand and USA. The results of the laboratory and field ...
J Alexander, J Hague, F Bongers, Y Imamura, M Roberts


Full-scale impregnation of wood with siloxane using supercritical carbon dioxide
2014 - IRG/WP 14-40659
Full-scale impregnation of wood with siloxane was carried out using supercritical carbon dioxide as solvent. A batch of 3530 kg of Scots pine sapwood was impregnated to a retention of approximately 1.3% siloxane. The treatment also consisted of a simultaneous impregnation with organic biocides. The performance of the wood was evaluated in terms of capillary water uptake according to a modified EN ...
A Kjellow, F Imsgard, J Fernandes, R Wagner, J Delis


Termite resistance of wood modified with short- and long-chain siloxanes
2014 - IRG/WP 14-40660
Scots pine (Pinus sylvestris L.) sapwood specimens modified with short- and long-chain amino-functional siloxane emulsions were exposed to subterranean termites (Reticulitermes flavipes Kollar). Laboratory choice and no-choice tests following the standard EN 117 (2013) were conducted for 8 weeks in order to evaluate the influence of these silicon-based compounds on the termite resistance of treate...
P Gascón-Garrido, M-F Thévenon, H Militz, C Mai


The effect of UV irradiation on some technological properties of different polyurethane varnishes coated plywood panels from veneers dried at different temperatures
2014 - IRG/WP 14-40661
In this study, the effect of UV irradiation on some technological properties of three different polyurethane varnishes coated plywood panels produced from Scots pine (Pinus sylvestris L.) and Maritime pine (Pinus pinaster L.) veneers manuactured and dried at different temperatures was studied. Accordingly, 32°C log peeling temperature and three different veneer drying temperatures (110, 140 and ...
Ö Özgenç, C Demirkir, Ü C Yildiz, G Çolakoğlu


Effect of Nano-Wollastonite on Water Absorption in Particleboard
2014 - IRG/WP 14-40662
Effects of wollastonite nanofibers on physical properties of particleboard were studied. Nano-wollastonite (NW) was applied at 5, 10, 15, and 20 g/kg, based on the dry weight of wood-chips, and compared with control specimens. Two application methods of NW were used: surface application (SA), and internal application (IA). Density was kept constant at 0.68 g/cm3 for all treatments. Tests were carr...
S Karimi, H Reza Taghiyari, A Karimi, P M Tahir, J Abdul Halip


Effects of thermal modification on properties of Douglas-fir heartwood
2014 - IRG/WP 14-40663
The flexural properties and mass losses of thermal modified Douglas-fir pretreated with boron or glycerol were examined. Pretreatments were associated with slight, but not significant, reductions in modulus of rupture (MOR) and modulus of elasticity (MOE)of Douglas-fir at different thermal treatment levels. Boron pretreatment had the greatest effect on MOR. MOR of non-pretreated and ...
Li Yan, J J Morrell


Improving dimensional stability of thermally treated wood by secondary modification – potential and limitations
2014 - IRG/WP 14-40664
The potential of treating thermally modified wood with melamine resin to improve the dimensional stabilization is tested in this research. Two different boards of poplar (Populus ssp.) were cut into two halves. One half of each board was thermally modified (T1 and T2) in a commercial process, the other half was used as untreated reference material. The material was thermally modified using the vac...
G Behr, K-C Mahnert, S Bollmus, H Militz


Effect of polyurea coatings on performance of Douglas-fir in tropical above ground exposures
2014 - IRG/WP 14-40665
The potential for using polyurea barriers to limit fungal and termite attack was investigated on Douglas-fir lumber and timbers. Termites were capable of penetrating the barrier to attack non-treated wood as well as wood dip-treated with disodium octaborate. The coatings were also exposed above ground for 48 months in Hilo Hawaii. Samples were dissected to detect internal decay. Coated non-trea...
S Uysal, J J Morrell


Development of new wood treatments combining boron impregnation and thermo modification - Effect on decay and termites durability
2014 - IRG/WP 14-40666
Environmental pressures appeared in most European countries during the last decade has lead to the development of more environmentally acceptable preservation methods. In this context, wood heat treatment has been one of the most investigated alternative methods during the last years. Treated at temperatures ranging between 180 and 220°C, wood components undergo more or less important chemical mo...
S Salman, A Pétrissans, M-F Thévenon, S Dumarçay, B Pollier, P Gérardin


Comparison of gauge and assay retention in crossties treated with copper naphthenate
2014 - IRG/WP 14-40667
Creosote has been the most widely used preservative for wooden railroad crossties or sleepers for over 100 years. Alternative preservatives such as copper naphthenate (CuN) have been shown to provide equivalent performance against decay fungi and wood destroying insects; however, the use and specification of CuN involves an education process for treaters and railroad customers alike. One differe...
J Brient, H Tomlinson, J Hughes


Performance of some wood modification treatments against marine borers
2014 - IRG/WP 14-40668
Since some years, new treatment technology to protect wood against wood destroying fungi is introduced. Limited knowledge on their resistance to water organisms is available. Therefore, the resistance of chemically modified wood was assessed in a field test according to the European Standard EN 275 over a period of 3 resp. 5 years at sites in the North Sea and the Baltic Sea. Scots pine (Pinus syl...
A Klüppel, C Mai, H Militz, S Cragg


A guideline for sorting easy to impregnate Scots pine sapwood based on three treatability studies from Northern Europe
2014 - IRG/WP 14-40669
Scots pine sapwood is generally considered an easy to impregnate wood species, though it reportedly faces challenges towards a homogeneous impregnation and large variations in treatability are reported for the material. This study comprises the results of three treatability tests that were performed on Scots pine (Pinus sylvestris) sapwood. The material impregnated was originated from a large ...
K Zimmer, E Larnøy, A Treu


Encapsulation Systems Combined with DOT Borate Treatments – The Future of Treated Crossties
2014 - IRG/WP 14-40670
Borates have been utilized in wood protection systems for many decades but only recently have been used in North America to treat crossties. This colorless, ordorless and very effective wood protection chemical has the ability to arrest and prevent the colonization of wood by both basidiomycete decay fungi and insects such as beetles and termites while ties are air seasoning or in service. Since ...
S C Kitchens, T L Amburgey


Comparison of untreated plywood and untreated LVL in a field trial against Coptotermes acinaciformis and in laboratory trials against Tyromyces palustris and Coniophora puteana
2014 - IRG/WP 14-40671
In Australasia, efficacy data obtained on plywood is generally acceptable for laminated veneer lumber (LVL) and vice versa. This is particularly the case with glueline treatment approvals. The rationale is that the two wood products have predominately the same basic structure with the key difference being orientation of the veneer. LVL typically has all veneers in parallel while plywood typical...
A Siraa, K Day, S Millward, P Lobb


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