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Copper naphthenate-treated Southern Pine pole stubs in field exposure. -Part 2: Chemical characterization of full size pole stubs 12 years after treatment
2000 - IRG/WP 00-30246
This study examines the influence of pre-treatment and post-treatment steaming on the character and physio-chemical nature of copper naphthenate in hydrocarbon solvent treated pine in larger, pole diameter, pole stub-length samples. This work is the continuation of two projects that began almost a decade ago. Previous reports indicated that certain morphological changes might occur in small labora...
H M Barnes, D P Kamdem, M H Freeman


Estimation of service life of durable timber species by accelerated decay test and fungal cellar test
2002 - IRG/WP 02-20249
Many kinds of durable wood species for outdoor uses has been imported from all over the world to Japan. However information on the natural durability of these species is not sufficient to estimate the service life of them in the climate of Japan. Highly durable species such as Jarrh, Teak, Ipe, Ekki, Selangan batu, Red wood, Western red cedar showed no significant percent mass losses by accelerate...
K Yamamoto, I Momohara


Checking of sodium pentachlorophenate fixation in wood
1990 - IRG/WP 3620
In order to estimate the volatilization of sodium pentachlorophenate from treated wood, wood samples treated with pentachlorophenate were analysed after various durations of an EN 73 weathering The results giving no clear evidence of volatilization, treated wood samples were put in a test chamber with precise climatic conditions, the air used in the experiment being analysed. The pentachlorophenat...
M Lamour, H Sageot


CCA fixation experiments. Part 2
1989 - IRG/WP 3505
CCA fixation in wood was measured by both squeezing solution from treated wood that had not been dried and analyzing the solution for copper, chromium and arsenic, as well as using a chromotropic acid test to detect the presence of chromium VI. Both methods provide useful information on the CCA fixation process and illustrate that chromium VI disappears as CCA becomes fixed within wood....
W S McNamara


Interaction mechanisms of F/Cr/As/B type preservative and wood
1981 - IRG/WP 3183
The paper reports results of investigations on the fixation of the components of a F/Cr/As/B preservative in wood and its lignin and cellulosic components....
N Ermush, I Andersone


The variation in electrical resistance in the CCA-treated wood during the fixation
1989 - IRG/WP 3554
The curve commonly used in Scandinavia for describing the fixation period at different temperatures for CCA-impregnated wood is based on investigation by Dahlgren on the pH-variations in a mixture of sawdust and preservative solution. As far as we know there is no such investigation on solid wood. We have therefore measured the electrical resistance in CCA-treated solid wood to see if this will di...
F G Evans, B Nossen


Field Test Results after Nine Years for CCA and ACQ Preservative-treated Wood Fixed in Different Climates
2003 - IRG/WP 03-30303
During assessment of the ground contact stakes in the Norwegian test field, we have frequently found that the first visual rot attack is in the zone of the stakes, where the stakes have been in contact with each other during the fixation. These parts are usually light green, caused by the lack of light during fixation, compared to the rest of the stake surface, which has a darker colour. To inves...
F G Evans


Effect of leaching temperature and water acidity on the loss of metal elements from CCA treated timber in aquatic conditions. Part 2: Semi-industrial investigation
1995 - IRG/WP 95-50040-13
In continuation of previous leaching research on the quantification and modelling of metal elements released from CCA treated timber, a series of experiments has been carried out dealing with the influence of temperature and pH of the relative aquatic environment. The leaching method used is the Dutch prestandard for building materials, a long term static leaching test simulating practical bank-sh...
G M F Van Eetvelde, W J Homan, H Militz, M Stevens


Copper binding capacity of modified wood flour
1992 - IRG/WP 92-3709
Wood flour was modified by reaction with oxidising agents and CCA preservative. The copper chromium and arsenic were removed from the CCA treated wood flour by an acid leaching procedure. The modified wood flours were allowed to react with copper acetate solution and the level of copper fixation achieved was determined. The modified wood flours had greater affinity for copper ions present in solut...
N C Milowych, W B Banks, J A Cornfield


Fixation of CCA in Pinus sylvestris after kiln-drying
1990 - IRG/WP 3594
Tanalith C Paste is 98% fixed and Tanalith Oxide C is 99% fixed irrespective of whether treated Pinus sylvestris is kiln or air dried. A schedule suitable for kiln drying of CCA treated Pinus sylvestris is described....
P Warburton, J A Cornfield, D A Lewis, D G Anderson


The use of zirconium as an inert fixative for borates in preservation
2001 - IRG/WP 01-30256
Stand-alone borates have been used in internal protected situations as wood preservatives for about 60 years. They have not been deemed acceptable for external situations because of their leaching characteristics. Work carried out to reduce the leachability of borates has been reviewed briefly here, and a specific fixation agent based on zirconium has been tested in standard leaching and decay tes...
J D Lloyd, J L Fogel, A Vizel


Patterns of long-term performance - How well are they predicted from accelerated tests and should evaluations consider parameters other than averages?
1998 - IRG/WP 98-20130
This paper is a discussion of whether different service-life distribution patterns of products treated with unlike preservatives can be predicted, modeled, characterized, or even anticipated from accelerated laboratory tests. Graphic displays of data from Forest Products Laboratory field plots with preservative-treated and fire-retardant-treated stakes demonstrate the importance of local environme...
R C De Groot, J W Evans


Questionnaire: Facility for accelerated stake tests in unsterile soil
1981 - IRG/WP 2166
An acceptable name for this type of test facility has not yet been devised, but it has previously been referred to as a FUNGUS CELLAR or as a TROPICAL DECAY HOUSE. The attached pamphlet (What's New in Forest Research No.65) describes in broad terms the facility used for this purpose at FRI in New Zealand. Over the last two or three years several laboratories and commercial firms have inst...
J A Butcher


Literature survey on the permanence and distribution of salt-type wood preservatives
1969 - IRG/WP III 1B
The objective of this survey is generally to review some of the more important published work dealing with the distribution and permanence of salt-type waterborne wood preservatives in treated timber. The survey is limited to the major chrome-containing formulations and the classification system proposed by Becker (1964) has been adopted throughout. CK - chromium, copper (copper, chrome); CKA - c...
Anonymous


Investigation of the fixation in wood of chromated zinc chloride and copperised chromated zinc chloride preservatives
1976 - IRG/WP 372
A biological method of evaluating the extent to which CZC and CCZC preparations are retained in wood in terms of the potential protection which they afford against destruction by Merulius lacrymans (dry rot) is given. CCZC is recommended for protection of wood under moderate leaching conditions, while the use of CZC under such conditions is not recommended....
V N Sozonova, D A Belenkov


Report on questionnaire: Facility for accelerated stake tests in unsterile soil
1983 - IRG/WP 2169
In October 1981 a questionnaire (IRG Doc. No. IRG/WP/2166) on the so-called fungus cellar tests in unsterile soil was prepared and despatched to 56 individuals representing various institutes, organisations, or companies. In addition a further 68 letters describing the purpose of the questionnaire were sent to additional IRG members who could request the full questionnaire if appropriate. This rep...
J A Butcher


Study on the treatment of construction timbers by diffusion methods
1983 - IRG/WP 3252
Several species of timber that could be used for constructional purposes have to be pressure impregnated before such use. Pressure impregnation requires expensive equipment, and needs specialized trained operators, etc, which is not possible in most parts of India. Some timbers cannot be pressure impregnated, but can be treated by diffusion. Diffusion treatments could protect these timbers with si...
V R Sonti, B Chatterjee


EPR investigations of interactions between ammoniacal Cu(II) octanoate and wood
1996 - IRG/WP 96-30110
Ammoniacal solutions of copper(II) octanoate [ C u . h l f . 2 . r h l f.(O2CC7H15)4], interactions of these solutions with wood and wood components, and leaching of copper(II) octanoate from impregnated wood samples, have been studied by electron paramagnetic resonance (EPR) method. It is still not clear if in the Cu(II) octanoate - water - ammonia system, Cu(II) remains in a (copper(II) octanoat...
F Dagarin, M Petric, F Pohleven, M Sentjurc


The influence of age on retention and fixation of CCA in pressure-treated Kenyan-grown Eycalyptus saligna: Summary of findings
2002 - IRG/WP 02-30296
The present study investigates the influence of age on retention and fixation of copper-chrome-arsenate (CCA) in Kenyan-grown Eucalyptus saligna. Samples for the study were obtained from sound trees aged 4, 8, 12, 16, 20 and 24 years. Test samples were radially cut from round material to represent total sapwood and heartwood for each age class, and measured 50mm in thickness, 100mm long, with wi...
R Venkatasamy


The potential for accelerated ageing to determine the persistence of active ingredients in timber
2006 - IRG/WP 06-20323
Fast screening methods for evaluating the persistence of active ingredients in timber are proposed. This is an outline proposal which is intended to provoke discussion and further development of the methods. Reliable and accurate analytical methods are key to these tests....
L D A Saunders, M R Powell


The Chemical and Biological Properties of Polymeric Betaine
2009 - IRG/WP 09-30512
Didecyl polyoxyethyl ammonium borate (DPAB), also known as Polymeric Betaine, was developed as a co-biocide for chromium-free copper based wood preservatives in Europe in the 1980’s. DPAB as a wood preservative has been reported previously. This paper summarizes the chemical, physical, and biological properties of DPAB. ...
H Härtner, S Schmitt, Futong Cui, H M Barnes


The effect of treatment temperature on the biological performance of CCA treated wood
1990 - IRG/WP 3624
Birch and Scots pine sapwood blocks were treated with several concentrations of CCA at three different temperatures: 5, 20 and 35°C. The treated wood was maintained at the appropriate temperature for the fixation period. Leached and unleached samples were then exposed in a soft rot monoculture test using Chaetomium globosum and a brown rot monoculture test using Coniophora puteana. The treatment ...
S M Gray


Preservative requirements for exterior particleboard as predicted from accelerated laboratory evaluations
1976 - IRG/WP 265
Arguments for and against preservative treatment of exterior particleboard were considered; it was concluded that preservative treatment is desirable. Laboratory decay tests were conducted to determine levels of sodium pentachlorophenoxide required to protect exterior particleboard from decay fungi. The decay resistance of treated board was compared with that of timber (both naturally durable and ...
M E Hedley


Natural durability of wood in ground contact - A correlation between field and laboratory tests
1985 - IRG/WP 2182
A field test is being carried out to evaluate the natural durability of 20 hardwoods. The resistance to decay and termite attack was evaluated in accelerated laboratory tests. The results of the field test after 6 years and 8 months indicate that there is not necessarily agreement between results from laboratory and field tests. It is pointed out that apart from the artificiality of the laboratory...
M S Cavalcante, G A C Lopez, R G Montagna, M E S Fosco Mucci


The course of fixation of Cu-Cr-As wood preservatives
1972 - IRG/WP 307
Copper-chrome-arsenic (CCA) preservatives in contact with wood result in an instant extensive increase of pH, because of ion-exchange and adsorption reactions with the wood. During precipitation of the active elements the pH continuously increases but reaches a maximum, when all chrome is consumed. Some of the early reaction products are unstable and slowly convert via dissolution into stable comp...
S-E Dahlgren


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